Calcium oxide-based ceramic core and preparation method thereof

Patent metadata

Field	Value
Publication number	US-9308579-B2
Application number	US-201314374919-A
Country	US
Kind code	B2
Filing date	May 31, 2013
Priority date	Oct 25, 2012
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

This invention publishes a method to prepare CaO-based ceramic cores used in investment casting applications. This method claims to use the rare earth oxide to coat the CaO core surface; later the coated cores are shaped then sintered to get the final products. CaO based core was made by 5˜15 wt % plasticizer, 0.001˜20 wt % mineralizer and the rare earth-coated CaO powders to balance for total 100%. This preparation method can solve the CaO core water absorption problems during core manufacturing, shipping and storage process while improve the core chemical inertness and mechanical properties.

First claim

The invention claimed is:

1. A CaO-based ceramic core, consisting materials as follows: 5˜15 wt % plasticizer with rare earth oxides-coated CaO powders for balance.

2. The CaO-based ceramic core according to claim 1 , further consisting of 0.01˜20 wt % mineralizer in the raw material.

3. The CaO-based ceramic core according to claim 2 , characterized in that the mineralizers are made of zirconia, yttiria, or zirconia and yttiria mixed in any weight ratio.

4. The CaO-based ceramic core according to claim 1 , characterized in that the plasticizer consists of 50˜80 wt % paraffin wax, 10˜40 wt % beeswax and 5˜10 wt % oleic acid.

5. The CaO-based ceramic core according to claim 1 , characterized in that the rare earth oxides-coated CaO powders are CaO coated with yttiria, or zirconia mixed with yttiria.

6. A method of making the CaO-based ceramic core according to claim 1 , characterized in that the method includes the following steps:
Step 1: prepare rare earth oxides coated CaO powder;
Step 2: stirring while heating the rare earth oxides-coated CaO powders with plasticizer to 50˜130° C. to make rare earth oxides-coated CaO-based ceramic cores; stirring while heating rare earth oxides-coated CaO powders, plasticizer and mineralizer to 50˜130° C. to make rare earth oxides-coated CaO-based ceramic cores;
Step 3: shaping then sintering rare earth oxides-coated CaO-based ceramic cores with sintering temperature at 1100˜1600° C. for 0.5˜20 hrs.

7. The method according to claim 6 , characterized in that the Step 1 includes the following steps:
First, prepare the CaO suspension: add the non-ionic surfactant to ethanol to get the mixed solution, make sure every 10 L ethanol contain 0.1˜1 kg non-ionic surfactant, add the CaO powder into the solution to form a suspension;
Second, prepare the rare earth oxides precursor: mix the zirconium oxychloride and inorganic yttrium salt in any percentage to form the rare earth oxides precursor, weigh the zirconium oxychloride and inorganic yttrium salt, put them into the ethanol and heat the solution, then add hydrogen peroxide into the solution, sufficiently stir solution to form the rare earth oxides precursor No 1 solution;
Third, add the rare earth oxides precursor solution into the CaO suspension, and stir them to attain NO. 2 mixed solution;
Fourth, add the ammonia water solution into NO. 2 solution to adjust pH value to 8˜11, and attain NO. 3 mixed solution;
Fifth, dry the NO. 3 mixed solution to get the powders;
Sixth, sinter the powders to get the rare earth oxides-coated CaO powders.

8. The method according to claim 7 , characterized in that the non-ionic surfactant mentioned above is PEG, AEO, carbon-rich AEO, Polyoxyethylene fatty acid, Polyoxyethylene amine, or Polyoxyethylene amide.

9. The method according to claim 7 , characterized in that the inorganic yttrium salt is yttrium chloride or yttrium nitrate.

10. The method according to claim 7 , characterized in that the amount of added H 2 O 2 is 0.1˜0.5 kg per 10 L of the rare earth oxides precursor solution.

11. The method according to claim 7 , characterized in that the concentration of rare earth oxides precursor solution is 0.01˜22 mol/L.

12. The method according to claim 7 , characterized in that in the NO. 2 mixed solution, the mole ratio of rare earth oxides and CaO is 0.005˜9.5.

13. The method according to the claim 7 , characterized in that the sintering condition in the 6th step is 500˜1600° C., for 0.5˜20 hrs.

Assignees

• Univ Beihang

Inventors

• Wu Guoqing
• Zhou Pengpeng
• Zhao Jiaqi
• Nan Hai

Classifications

• B22D21/022

  Casting heavy metals, with exceedingly high melting points, i.e. more than 1600 degrees C, e.g. W 3380 degrees C, Ta 3000 degrees C, Mo 2620 degrees C, Zr 1860 degrees C, Cr 1765 degrees C, V 1715 degrees C · CPC title

• C04B2235/3244

  Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof · CPC title

• B22C1/22

  of resins or rosins · CPC title

• C04B35/057

  based on calcium oxide · CPC title

• C04B35/622

  Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products · CPC title