Production of vinyl chloride from a methane conversion process

Patent metadata

Field	Value
Publication number	US-9308513-B2
Application number	US-201313915143-A
Country	US
Kind code	B2
Filing date	Jun 11, 2013
Priority date	Aug 21, 2012
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

Methods and systems are provided for converting methane in a feed stream to acetylene. The method includes processing the acetylene to form a hydrocarbon stream having vinyl chloride. The hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream is be treated to convert acetylene to other hydrocarbon processes. The method according to certain aspects includes controlling the level of carbon monoxide in the hydrocarbon stream to limit downstream side reactions in the downstream processing units.

First claim

The invention claimed is:

1. A method for producing vinyl chloride comprising:
introducing a hydrocarbon feed stream comprising methane into a supersonic reactor;
pyrolyzing the methane in the supersonic shock wave reactor to form a reactor effluent stream comprising acetylene wherein pyrolyzing the methane includes heating the methane to a temperature of between about 1200° C. and about 3500° C. for a residence time of between about 0.5 ms and 100 ms;
treating the reactor effluent stream to remove CO to a level below about 100 wt-ppm of the reactor effluent stream to generate a treated reactor effluent stream;
passing the treated reactor effluent stream to a hydrogenation reactor to form a second effluent stream comprising ethylene; and
passing the second effluent stream to a vinyl chloride reactor to generate a vinyl chloride effluent stream.

2. The method of claim 1 , wherein pyrolyzing the methane includes accelerating the hydrocarbon stream to a velocity of between about mach 1.0 and about mach 4.0 and slowing down the hydrocarbon stream to increase the temperature of the hydrocarbon process stream.

3. The method of claim 1 , wherein the hydrocarbon stream includes a methane feed stream portion upstream of the supersonic reactor comprising natural gas.

4. The method of claim 1 , further comprising passing the hydrogenation reactor effluent stream through a light olefins recovery unit to generate an enriched ethylene stream; and
passing the enriched ethylene stream to a vinyl chloride reactor to generate a vinyl chloride effluent stream.

5. The process of claim 1 , wherein the vinyl chloride reactor comprises a chlorination zone and a heating zone, further comprising:
passing the enriched ethylene stream and a chlorine stream to the chlorination zone to generate a chlorinated hydrocarbon stream comprising dichloroethane; and
passing the chlorinated hydrocarbon stream to the heating zone to decompose the dichloroethane to an effluent stream comprising vinyl chloride and hydrochloric acid.

6. The process of claim 5 further comprising passing the effluent stream to a separation unit to generate a vinyl chloride product stream and a hydrochloric acid stream.

7. The process of claim 1 wherein the vinyl chloride reactor comprises a chlorination zone and a heating zone, further comprising:
passing the enriched ethylene stream to the vinyl chloride reactor;
passing hydrochloric acid to the vinyl chloride reactor;
passing an oxidizing stream comprising oxygen to the vinyl chloride reactor;
reacting the ethylene, hydrochloric acid and oxygen in the chlorination zone to generate a chlorinated hydrocarbon stream comprising dichloroethane; and
passing the chlorinated hydrocarbon stream to the heating zone to generate an effluent stream comprising vinyl chloride.

8. The process of claim 7 further comprising passing the effluent stream to a separation unit to generate a vinyl chloride product stream and a hydrochloric acid stream.

9. The method of claim 1 , further comprising a methane enrichment zone positioned upstream of the supersonic reactor to remove at least some of the non-methane compounds from the feed stream prior to introducing the feed stream into the supersonic reactor.

10. A method for producing vinyl chloride comprising:
introducing a hydrocarbon feed stream comprising methane into a supersonic reactor;
pyrolyzing the methane in the supersonic shock wave reactor to form a first reactor effluent stream comprising acetylene; wherein pyrolyzing the methane includes heating the methane to a temperature of between about 1200° C. and about 3500° C. for a residence time of between about 0.5 ms and 100 ms;
treating the first reactor effluent stream to remove CO to a level below about 100 wt-ppm of the reactor effluent stream to generate a treated first reactor effluent stream;
passing the treated first reactor effluent stream to a acetylene enrichment zone to form a second effluent stream comprising enriched acetylene; and
passing the second effluent stream and a hydrogen chloride stream to a hydrochlorination reactor to generate a vinyl chloride effluent stream.

11. The method of claim 10 further comprising passing the vinyl chloride effluent stream to a product recovery unit to generate a vinyl chloride product stream.

12. A method for producing vinyl chloride comprising:
introducing a hydrocarbon feed stream comprising methane into a supersonic reactor;
pyrolyzing the methane in the supersonic shock wave reactor to form a first reactor effluent stream comprising acetylene; wherein pyrolyzing the methane includes heating the methane to a temperature of between about 1200° C. and about 3500° C. for a residence time of between about 0.5 ms and 100 ms;
treating the first reactor effluent stream to remove CO to a level below about 100 wt-ppm of the reactor effluent stream to generate a treated first reactor effluent stream;
passing the treated first reactor effluent stream to a hydrogenation reactor to form a second effluent stream comprising ethylene; and
passing the second effluent stream to a chlorination reactor;
passing a stream comprising chlorine to the chlorination reactor, wherein the chlorination reactor generates a process stream comprising dichloroethane;
passing the dichloroethane process stream to a decomposition reactor to generate a decomposition effluent stream comprising vinyl chloride and hydrogen chloride;
passing the decomposition effluent stream to a product recovery unit to generate a product stream comprising vinyl chloride.

13. The method of claim 12 wherein the stream comprising chlorine is chlorine gas (Cl2).

14. The method of claim 12 further comprising passing the first reactor effluent stream to a carbon oxide removal unit to generate an enriched acetylene stream; and
passing the enriched acetylene stream to the hydrogenation reactor.

Assignees

• Uop Llc

Inventors

• Bricker Jeffery C
• Chen John Q
• Coughlin Peter K

Classifications

• B01J3/08 Primary

  Application of shock waves for chemical reactions or for modifying the crystal structure of substances · CPC title

• C07C5/09

  to carbon-to-carbon double bonds · CPC title

• B01J2219/00006

  Large-scale industrial plants · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J2219/00123

  adding a temperature modifying medium to the reactants · CPC title