Polyimide blend membranes for gas separations

Patent metadata

Field	Value
Publication number	US-9308487-B1
Application number	US-201414496754-A
Country	US
Kind code	B1
Filing date	Sep 25, 2014
Priority date	Sep 25, 2014
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

The polyimide blend membrane in the present invention was prepared by blending a first aromatic polyimide with high permeability and a second aromatic polyimide with high selectivity for gas separation. The polyimide blend membrane in the present invention showed improved permeability compared to membranes made from the second aromatic polyimide and improved selectivity compared to membranes made from the first aromatic polyimide.

First claim

The invention claimed is:

1. A process for separating at least one gas from a mixture of gases, the process comprising
(a) providing a polyimide blend membrane comprising a miscible blend of a first aromatic polyimide that comprises a plurality of repeating units of formula (I) and a second aromatic polyimide that comprises a plurality of repeating units of formula (II), wherein formula (I) is represented by:

 wherein n, m, o, and p are independent integers from 20 to 500; and wherein formula (II) is represented by:

 wherein q and r are independent integers from 20 to 500; and wherein the weight ratio of said first aromatic polyimide to said second aromatic polyimide is in a range from about 10:1 to 1:10 wherein said polyimide blend membrane is permeable to said at least one gas;
(b) contacting a mixture of gases to one side of the polyimide blend membrane to cause said at least one gas to permeate the polyimide blend membrane; and
(c) removing from an opposite side of the polyimide blend membrane a permeate gas composition comprising a portion of said at least one gas which permeated said membrane.

2. The process of claim 1 wherein said mixture of gases comprises a mixture of carbon dioxide and methane.

3. The process of claim 1 wherein said mixture of gases comprises a mixture of hydrogen and methane.

4. The process of claim 1 wherein said mixture of gases comprises a mixture of helium and methane.

5. The process of claim 1 wherein said mixture of gases comprises a mixture of at least one volatile organic compound and at least one atmospheric gas.

6. The process of claim 1 wherein said mixture of gases comprises nitrogen and hydrogen.

7. The process of claim 1 wherein said mixture of gases comprises a mixture of at least two gases selected from the group consisting of carbon dioxide, oxygen, nitrogen, water vapor, hydrogen sulfide, helium and methane.

8. The process of claim 1 wherein said mixture of gases comprises a mixture of volatile organic compounds and at least one atmospheric gas.

9. The process of claim 8 wherein said volatile organic compounds are selected from the group consisting of toluene, xylene and acetone.

10. The process of claim 1 wherein said mixture of gases comprises a mixture of olefins and paraffins.

11. The process of claim 1 wherein said mixture of gases comprises a mixture of hydrocarbons and hydrogen.

12. The process of claim 1 wherein said polyimide blend membrane is cross-linked via UV radiation.

13. The process of claim 1 wherein said process is at a temperature from about 20° to about 100° C.

14. The process of claim 1 wherein said mixture of gases comprises a mixture of isoparaffin and normal paraffin.

15. The process of claim 1 wherein said polyimide blend membrane is used in either a single stage membrane system or in either stages of a two stage membrane system.

Assignees

• Uop Llc

Inventors

• Liu Chunqing
• Tran Howie Q

Classifications

• B01D53/228 Primary

  characterised by specific membranes · CPC title

• B01D69/125

  In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction · CPC title

• B01D71/64

  Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors · CPC title

• Y02C20/40

  of CO2 · CPC title

• B01D2325/20

  Specific permeability or cut-off range · CPC title