Multilayer ceramic electronic device

Patent metadata

Field	Value
Publication number	US-9305708-B2
Application number	US-201414445894-A
Country	US
Kind code	B2
Filing date	Jul 29, 2014
Priority date	Jul 30, 2013
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

A multilayer ceramic electronic device comprising a lamination in which an internal electrode layer 3 and a dielectric layer 2 are laminated alternatively, wherein the dielectric layer 2 is comprised of a dielectric ceramic composition including a main component represented by a general formula of ABO 3 and a rare-earth component R, and segregation phases 5 including the rare-earth component R are present in the dielectric layer 2 . When the dielectric layer 2 is separated to six areas by dividing the dielectric layer 2 sandwiched by a pair of the internal dielectric layers 3 in the thickness direction, there are the R segregation phases present in two neighboring areas 2 a respectively adjacent to the pair of the internal electrode layers 3 in the dielectric layer 3 at a ratio of double or more compared with the R segregation phases present in two central areas 2 b located at a substantially center in the dielectric layer 2.

First claim

The invention claimed is:

1. A multilayer ceramic electronic device comprising a lamination in which an internal electrode layer and a dielectric layer are laminated alternatively, wherein
the dielectric layer is comprised of a dielectric ceramic composition including a main component represented by a general formula of ABO 3 (A is at least one selected from Ba, Sr and Ca, and B is at least one selected from Ti, Zr and Hf) and a rare-earth component R (R is at least one selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu),
R segregation phases including the rare-earth component R are present in the dielectric layer, and
when the dielectric layer is separated to six areas by dividing the dielectric layer sandwiched by a pair of the internal dielectric layers in the thickness direction, there are the R segregation phases present in two neighboring areas respectively adjacent to the pair of the internal electrode layers in the dielectric layer at a ratio of double or more compared with the R segregation phases present in two central areas located at a substantially center in the dielectric layer.

2. The multilayer ceramic electronic device as set forth in claim 1 , wherein
the dielectric layer additionally comprises a sub-component including Si,
at least a part of a Si segregation phase including Si is coexistently present at the R segregation phases in the dielectric layer, and
a Si.R copresence ratio showing a ratio of an area of a copresence region where the R segregation phases and the Si segregation phase are copresent is 35% or more with respect to an area of a region where the R segregation phases and/or the Si segregation phase are present.

3. The multilayer ceramic electronic device as set forth in claim 1 , wherein
a dielectric particle in which the rare-earth component R is at least dissolved in solid on a surface of the main component of ABO 3 is present in the dielectric layer.

4. The multilayer ceramic electronic device as set forth in claim 1 , wherein
the dielectric particle in which the rare-earth component R is dissolved in solid from a particle surface of the main component of ABO 3 in a range of 15% or more along a grain diameter is present in the dielectric layer and
a ratio of the dielectric particle dissolved in solid in the range of 15% or more is 70% or more with respect to the whole number of the dielectric particles in a predetermined observation visual field.

5. The multilayer ceramic electronic device as set forth in claim 1 , wherein
there is a discontinuous part in the internal dielectric layer and the R segregation phases including the rare-earth component R are present at the discontinuous part.

Assignees

• Tdk Corp

Inventors

• Kai Nobutaka
• Okui Yasuhiro
• Kindaichi Satoru
• Kaneko Hideki
• Kojima Tatsuya
• Yoshii Akitoshi

Classifications

• H01G4/1209 Primary

  characterised by the ceramic dielectric material (H01G4/1272, H01G4/1281 take precedence) · CPC title

• H01G4/30

  Stacked capacitors (H01G4/33 takes precedence) · CPC title

• H01G4/1236

  based on zirconium oxides or zirconates (H01G4/1263 takes precedence) · CPC title

• H01G4/1218

  based on titanium oxides or titanates (H01G4/1245 takes precedence) · CPC title