Composition for wire coating member, insulated wire, and wiring harness

Patent metadata

Field	Value
Publication number	US-9305678-B2
Application number	US-201113636221-A
Country	US
Kind code	B2
Filing date	Apr 1, 2011
Priority date	Apr 5, 2010
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

To provide a composition for a wire coating member containing a non-crosslinked material at a low cost, which has superior flame retardancy, and is excellent in heat resistance, wear resistance and flexibility, and to provide an insulated wire and a wiring harness containing the composition. The composition contains (A) polypropylene, (B) a polyolefin elastomer, (C) a bromine flame retardant, (D) an antimony trioxide, (E) magnesium hydroxide, either one of (F) (F1) a zinc sulfide and (F2) a zinc oxide and (F3) mercaptobenzimidazole, and (G) a hindered phenolic antioxidant. The insulated wire includes a conductor and an insulation coat made from the composition, wherein the insulation coat has a thickness of 0.5 mm or less, and the insulated wire has an external diameter of 4 mm or less. The wiring harness includes the insulated wire.

First claim

The invention claimed is:

1. An insulated wire comprising a non-crosslinked insulation coat, wherein the non-crosslinked insulation coat is made from a composition comprising:
(A) a polypropylene;
(B) a polyolefin elastomer;
(C) a bromine flame retardant;
(D) an antimony trioxide;
(E) magnesium hydroxide;
(F) at least one of (i) and (ii):
(i) (F1) a zinc sulfide,
(ii) a combination of (F2) a zinc oxide and (F3) mercaptobenzimidazole; and

(G) a hindered phenolic antioxidant,
wherein:
each of (A) the polypropylene and (B) the polyolefin elastomer is not modified by a functional group or a silane coupling agent, and
a total content of (A) the polypropylene and (B) the polyolefin elastomer is 45 wt % or more of the composition.

2. The insulated wire according to claim 1 , wherein the compositon further any one of:
(H1) a functional-group modified styrene elastomer that is modified by a functional group;
(H2) a functional-group modified polyolefin that is modified by a functional group; and
(H1) the functional-group modified styrene elastomer and (H2) the functional-group modified polyolefin,
wherein each of the functional groups comprises one or a plurality of functional groups selected from the group consisting of a carboxylic acid group, an acid anhydride group, an amino group, and an epoxy group.

3. The insulated wire according to claim 2 , wherein (C) the bromine flame retardant comprises one or a plurality of bromine flame retardants selected from the group consisting of ethylenebis (pentabromobenzene), bis(tetrabromophthalimide)ethane, and tetrabromobisphenolA bis(dibromopropylether).

4. The insulated wire according to claim 3 , wherein:
(A) the polypropylene has a flexural modulus of 800 to 2000 MPa, and a melt flow rate at 230 degrees C. of 0.5 to 5 g/10 min, and
(B) the polyolefin elastomer has a flexural modulus less than 300 MPa, and a melt flow rate at 230 degrees C. of 1 g/10 min or more.

5. The insulated wire according to claim 4 having an external diameter of 4 mm or less.

6. A wiring harness comprising the insulated wire according to claim 5 .

7. The insulated wire according to claim 2 having an external diameter of 4 mm or less.

8. A wiring harness comprising the insulated wire according to claim 7 .

9. The insulated wire according to claim 1 having an external diameter of 4 mm or less.

10. A wiring harness comprising the insulated wire according to claim 9 .

11. The composition according to claim 1 , wherein (C) the bromine flame retardant comprises one or a plurality of bromine flame retardants selected from the group consisting of ethylenebis (pentabromobenzene), bis(tetrabromophthalimide)ethane, and tetrabromobisphenolA bis(dibromopropylether).

12. The insulated wire according to claim 11 having an external diameter of 4 mm or less.

13. A wiring harness comprising the insulated wire according to claim 12 .

14. The composition according to claim 1 , wherein:
(A) the polypropylene has a flexural modulus of 800 to 2000 MPa, and a melt flow rate at 230 degrees C. of 0.5 to 5 g/10 min, and
(B) the polyolefin elastomer has a flexural modulus less than 300 MPa, and a melt flow rate at 230 degrees C. of 1 g/10 min or more.

15. The insulated wire according to claim 14 having an external diameter of 4 mm or less.

16. A wiring harness comprising the insulated wire according to claims 15 .

17. The insulated wire according to claim 1 , wherein in the compostion:
the content of (A) the polypropylene is 50 to 90 parts by mass;
the content of (B) the polyolefin elastomer is 10 to 50 parts by mass;
the content of (C) the bromine flame retardant is 10 to 30 parts by mass with respect to 100 parts by mass of the total content of the (A) and (B) components;
the content of (D) the antimony trioxide is 1 to 20 parts by mass with respect to 100 parts by mass of the total content of the (A) and (B) components;
the content of (E) the magnesium hydroxide is 10 to 90 parts by mass with respect to 100 parts by mass of the total content of the (A) and (B) components;
the content of (F2) the zinc oxide is 1 to 15 parts by mass, and the content of (F3) the mercaptobenzimidazole is 2 to 15 parts by mass with respect to 100 parts by mass of the total content of the (A) and (B) components; and
the content of (G) the hindered phenolic antioxidant is 1 to 10 parts by mass with respect to 100 parts by mass of the total content of the (A) and (B) components.

Assignees

• Shimada Tatsuya
• Sakamoto Yukihiro
• Sato Masashi
• Autonetworks Technologies Ltd
• Sumitomo Wiring Systems
• Sumitomo Electric Industries

Inventors

• Shimada Tatsuya
• Sakamoto Yukihiro
• Sato Masashi

Classifications

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• H01B3/28 Primary

  natural or synthetic rubbers · CPC title

• H01B7/295

  using material resistant to flame · CPC title

• C08K5/0066

  Flame-proofing or flame-retarding additives · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title