Method and system for analyzing a liquid sample containing particles of solid matter and the use of such a method and system

Patent metadata

Field	Value
Publication number	US-9304120-B2
Application number	US-201314088403-A
Country	US
Kind code	B2
Filing date	Nov 24, 2013
Priority date	Nov 24, 2013
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

The invention relates to a method and system for monitoring of particles properties in a stream and the use of such method and system. In particular, the invention concerns sampling of liquids like aqueous suspensions or filtrates that contain solid matter in forest industry, oil and mining industry, as well as in and water treatment, desalination or water reuse processes, and in subsequent measurement of the samples. A sample from a stream of liquid is dyed to stain particles contained in the sample, which is conducted to a first flow chamber having means for causing said sample to be divided into particle populations according to their size or mass. A liquid flow is applied through the first flow chamber to cause at least one particle population to flow into a second flow chamber. The particle populations are measured to produce at least one measurement signal representative of the amount and/or properties of the particles, and processing extract key variables of each particle population and presenting them as an analysis of particle populations or the whole sample in terms of a count and size of particles and/or their hydrophobicity.

First claim

The invention claimed is:

1. A method of analyzing a liquid sample containing particles of solid matter, the method including the steps of:
providing a sample from a stream of liquid;
adding a dye to said sample to stain the particles contained therein;
conducting the sample to a first flow chamber which includes a disintegration channel having one or more depressions;
applying a liquid flow having a non-constant temporal velocity profile through said first flow chamber causing said sample to be divided into particle populations according to their size or mass;
causing at least one particle population to flow into a second flow chamber;
measuring by optical measurement at least one of said particle populations to produce at least one measurement signal representative of the amount and/or properties of the particles;
processing said measurement signal for each measured particle population to extract key variables of each particle population; and
presenting said key variables as an analysis of particle populations or the whole sample in terms of a count and size of particles and/or their hydrophobicity.

2. A method according to claim 1 , wherein the dye is a hydrophobic dye.

3. The method according to claim 1 , wherein the first flow chamber is a fractionator.

4. A method according to claim 1 , wherein the flow velocity in the first flow chamber disintegration channel is increased step by step according to said velocity profile, allowing smaller or lighter particle populations entering said second flow chamber having an essentially laminar flow first, and other particle populations later in an ascending order of size and weight, until all particle populations have entered said second flow chamber.

5. A method according to claim 1 , wherein the first flow chamber is a fractionator where particle separation into particle populations is based on particle settling, centrifugal separation and/or filtering.

6. A method according to claim 1 , wherein the amount and/or size of the particles in said sample is measured by light scattering of the particles in the sample.

7. A method according to claim 1 , wherein the hydrophobicity of the particles in said sample is measured by measuring the fluorescence emitted by the particles in the sample.

8. A method according to claim 1 , wherein the chemical or physical properties of said sample to be measured are one or more of the following: concentration of particles, volume of particles, surface area of particles, particle size, turbidity, concentration of suspended solid, light absorbance, fluorescence, light scattering, and hydrophobicity.

9. A method according to claim 8 , wherein the processing of said measurement signals includes filtering, averaging and baseline correction of said signals.

10. A method according to claim 1 , wherein the processing of said measurement signals for the key variables includes statistical operations on the data including one or more of the following: integration of signal(s), derivation of signal(s), cumulative sum of signal(s), mean value, maximum and minimum values.

11. A system for analyzing a liquid sample containing particles of solid matter, the system including:
means for providing a sample from a stream of liquid;
means or adding a dye to said sample;
a first flow chamber including a disintegration channel having one or more depressions for causing said sample to be divided into at particle populations determined by their size or mass;
means for applying a liquid flow having a non-constant temporal velocity profile through said first flow chamber;
a second flow chamber arranged to receive liquid containing at least one particle population from said first flow chamber;
optical measuring means for producing at least one measurement signal representative of the amount and/or character of the particles in said second flow chamber;
processing means for processing said measurement signal for each measured particle population to extract key variables of each particle population;
processing means for presenting said key variables as an analysis of particle populations or the whole sample in terms of a count and size of particles and/or their hydrophobicity.

12. A system according to claim 11 , wherein the means for applying a liquid flow through said first flow chamber is arranged to increasing the liquid flow velocity in said first flow chamber stepwise according to a predetermined flow velocity profile.

13. A system according to claim 11 , wherein the first flow chamber is a fractionator where particle separation into particle populations is based on particle settling, centrifugal separation or filtering.

14. A system according to claim 11 , wherein the optical measuring means comprises means at said second flow chamber for measuring of light scattering of the particles in the sample.

15. A system according to claim 11 , wherein the optical measuring means comprises means at said second flow chamber for measuring of fluorescence emitted by the particles in the sample.

16. A system according to claim 11 , including processing unit having adapted for automatic operation of the sample taking, fractionating and data collection.

17. A system according to claim 11 , including processing means for performing filtering, averaging and baseline correction of said measurement signals.

18. A system according to claim 11 , including processing means for performing statistical operations on the key variables includes including one or more of the following: integration of signal(s), derivation of signal(s), cumulative sum of signal(s), mean value, maximum and minimum values.

Assignees

• Kemira
• Kemira Oyj

Inventors

• Joensuu Iiris
• Piironen Marjatta

Classifications

• G01N15/0255

  with mechanical, e.g. inertial, classification, and investigation of sorted collections (with centrifuges G01N15/042) · CPC title

• G01N21/85 Primary

  Investigating moving fluids or granular solids · CPC title

• G01N15/0272

  with screening; with classification by filtering (B01D takes precedence) · CPC title

• G01N33/343 Primary

  Paper pulp · CPC title

• G01N2015/0053

  in liquids, e.g. trouble · CPC title