Functionalized block composite and crystalline block composite compositions as compatibilizers

Patent metadata

Field	Value
Publication number	US-9303156-B2
Application number	US-201214364352-A
Country	US
Kind code	B2
Filing date	Dec 12, 2012
Priority date	Dec 14, 2011
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

The invention provides functionalized block composites and crystalline block composites as compatibilizers. In particular, the invention provides compositions of at least three polymers and a compatibilizer. The compatibilizer comprises a functionalized olefin-based polymer formed from at least (A) and (B): (A) a crystalline block composite comprising: a block copolymer comprising a propylene-based crystalline block and crystalline ethylene-based block; a propylene-based crystalline polymer; and, a crystalline ethylene-based polymer; and (B) at least one functionalization agent or a functionalized olefin-based polymer formed from at least (A) and (B): (A) a crystalline block composite comprising: a block copolymer comprising a propylene-based crystalline block and crystalline ethylene-based block; a propylene-based crystalline polymer; and, a crystalline ethylene-based polymer; and (B) at least one functionalization agent.

First claim

The invention claimed is:

1. A composition comprising:
a) a first polymer;
b) a second polymer;
c) a third polymer; and,
d) a compatibilizer, wherein the compatibilizer is
i) a functionalized olefin-based polymer formed from at least (A) and (B):
(A) a block composite comprising:
a. a block copolymer comprising a propylene-based crystalline block and an ethylene/α-olefin block;
b. a propylene-based crystalline polymer; and,
c. an ethylene/α-olefin polymer; and

(B) at least one functionalization agent; and/or

(ii) a functionalized olefin-based polymer formed from at least (A) and (B):
(A) a crystalline block composite comprising:
a. a block copolymer comprising a propylene-based crystalline block and crystalline ethylene-based block;
b. a propylene-based crystalline polymer; and,
c. a crystalline ethylene-based polymer; and

(B) at least one functionalization agent,

wherein the first, second and third polymers are different, and
wherein the compatibilizer is present in an amount of from 2 wt % to 20 wt %, the first polymer is present in an amount of from 5 wt % to 85 wt %, the second polymer is present in an amount of from 5 wt % to 40 wt %, and the third polymer is present in an amount of from 5 wt % to 50 wt %, by the total weight of the polymers.

2. The composition of claim 1 wherein the first polymer is a polyethylene, the second polymer is a polypropylene and the third polymer is selected from the group of polyamide, polyurethane, polyester, polyethers, polyetherimides, polyvinylalcohols, polycarbonates, polylactic acids, polyamide esters and combinations thereof.

3. The composition of claim 1 wherein the compatibilizer comprises a block composite and the functionalization agent is selected from maleic anhydride, peroxide, and amine.

4. The composition of claim 1 wherein the compatibilizer includes the crystalline block composite and the functionalization agent is selected from maleic anhydride, peroxide, and amine.

5. The composition of claim 1 wherein the compatibilizer is (i) and the propylene-based crystalline block comprises 90 mol % to 100 mol % propylene.

6. The composition of claim 1 wherein the compatibilizer is (ii) and the crystalline propylene-based block comprises 90 mol % to 100 mol % propylene and the crystalline ethylene based block has a comonomer content between 0 mol % and 7 mol %.

7. The composition of claim 1 wherein the compatibilizer is (i) and the functionalization agent is maleic anhydride in a grafting level of from 0.10 wt % to 1.8 wt %.

8. The composition of claim 1 wherein the compatibilizer is (ii) and the functionalization agent is maleic anhydride in a grafting level of from 0.10 wt % to 1.8 wt %.

9. The composition of claim 1 wherein the first polymer is polyethylene, the second polymer is a polypropylene, and the third polymer is a polyurethane.

10. The composition of claim 1 wherein the first polymer is a low density polyethylene, the second polymer is a polypropylene, and the third polymer is a polyurethane.

Assignees

• Weeks Ronald J
• Hu Yushan
• Walton Kim L
• Marchand Gary R
• Read Michael D
• Silvis H C
• Dow Global Technologies Llc

Inventors

• Weeks Ronald J
• Hu Yushan
• Walton Kim L
• Marchand Gary R
• Read Michael D
• Silvis H C

Classifications

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L23/12

  Polypropene · CPC title

• C08L23/10

  Homopolymers or copolymers of propene · CPC title

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title