Process for increasing the yield of an isomerization zone

Patent metadata

Field	Value
Publication number	US-9302959-B2
Application number	US-201414267838-A
Country	US
Kind code	B2
Filing date	May 1, 2014
Priority date	May 1, 2014
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

A process for increasing a yield of an isomerization zone by removing at least a portion of the C 6 cyclic hydrocarbons from a stream having iC 4 hydrocarbons, iC 5 hydrocarbons, and iC 6 hydrocarbons prior to the stream being passed into the same isomerization zone. Suppression of the iC 4 hydrocarbons does not occur, allowing the iC 4 hydrocarbons to be isomerized in the same isomerization zone as the iC 5 hydrocarbons and iC 6 hydrocarbons.

First claim

What is claimed is:

1. A process for the isomerization of isoparaffins to normal paraffins, the process comprising:
separating a portion of C6 cyclic hydrocarbons from a naphtha stream comprising C4+ hydrocarbons to provide a C6 cyclic hydrocarbons lean stream;
separating iC4 paraffinic hydrocarbons, iC5 paraffinic hydrocarbons, and iC6 paraffinic hydrocarbons from the C6 cyclic hydrocarbons lean stream; and,
passing in iC4 paraffinic hydrocarbons, iC5 paraffinic hydrocarbons, and iC6 paraffinic hydrocarbons to an isomerization zone containing a chlorided alumina catalyst to isomerize isoparaffins to normal paraffins, disproportionate at least some isoparaffins, and crack at least some isoparaffins; and
controlling an amount of C6 cyclic hydrocarbons passed into the isomerization zone by at least one of the following:
selectively adding a stream of C6 cyclic hydrocarbons to the isomerization zone; and,
controlling an operating parameter of a separation zone used to separate the C6 cyclic hydrocarbons from the naphtha stream.

2. The process of claim 1 further comprising:
separating an effluent from the isomerization zone into an overhead stream comprising C3− hydrocarbons and a bottoms stream comprising C4+ hydrocarbons.

3. The process of claim 2 further comprising:
combining the bottoms stream comprising C4+ hydrocarbons with at least a portion of the naphtha stream.

4. The process of claim 1 further comprising:
passing the naphtha stream to a first separation zone; and,
separating the naphtha stream in the first separation zone into an overhead stream and a bottoms stream, the overhead stream being the C6 cyclic hydrocarbons lean stream and the bottoms stream being rich in n-hexane and C6 cyclic hydrocarbons.

5. The process of claim 4 further comprising:
passing the overhead stream from the first separation zone to a second separation zone; and,
separating the overhead stream from the first separation zone in the second separation zone into the at least one stream being rich in iC4 paraffinic hydrocarbons, iC5 paraffinic hydrocarbons, iC6 paraffinic hydrocarbons, or a combination thereof.

6. The process of claim 5 wherein the second separation zone comprises:
at least three separator columns.

7. The process of claim 6 further comprising:
separating the overhead stream from the first separation zone in a first separator column of the second separation zone into an overhead stream, an intermediate stream, a bottoms stream,
the overhead stream from the first separator column of the second separation zone being rich in C4+ hydrocarbons, and,
the intermediate stream of the first separator column of the second separation zone being rich in iC6 paraffinic hydrocarbons.

8. The process of claim 7 further comprising:
recycling the bottoms stream from the isomerization zone to the first column from the second separation zone.

9. The process of claim 7 further comprising:
combining the bottoms stream from the first separator column and the second separator column.

10. The process of claim 5 wherein the second separation zone comprises:
at least one adsorption zone.

11. The process of claim 10 further comprising:
separating the overhead stream from the first separation zone in the at least one absorption zone into a first stream and a second stream,
the first stream being rich in iC4 paraffinic hydrocarbons, iC5 paraffinic hydrocarbons, iC6 paraffinic hydrocarbons, or a combination thereof, and,
the second stream being rich in n-butane, n-pentane, and n-hexane.

12. The method of claim 11 further comprising:
recycling the bottoms stream from the isomerization zone to the first separation zone.

13. The method of claim 11 further comprising:
recycling the bottoms stream from the isomerization zone to the second separation zone.

14. The process of claim 1 further comprising:
separating n-butane, n-pentane, and n-hexane from the C6 cyclic hydrocarbons lean stream prior to passing the C6 cyclic hydrocarbons lean stream into the isomerization zone.

15. The process of claim 14 wherein the C6 cyclic hydrocarbons are separated in a first separation zone.

16. The process of claim 15 wherein n-butane, n-pentane, and n-hexane are separated in a second separation zone having at least three separation columns.

17. The process of claim 15 wherein n-butane, n-pentane, and n-hexane are separated in a second separation zone having an adsorption zone.

Assignees

• Uop Llc

Inventors

• Lapinski Mark P
• Lippmann Matthew
• Funk Gregory

Classifications

• C07C7/005 Primary

  Processes comprising at least two steps in series · CPC title

• C07C5/27 Primary

  Rearrangement of carbon atoms in the hydrocarbon skeleton · CPC title

• C07C7/04

  by distillation · CPC title

• C10G35/02

  Thermal reforming · CPC title

• C07C5/2772

  with metal oxides · CPC title