Optical glass and use thereof

Patent metadata

Field	Value
Publication number	US-9302930-B2
Application number	US-201314381771-A
Country	US
Kind code	B2
Filing date	Feb 25, 2013
Priority date	Feb 28, 2012
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

An aspect of the present invention relates to optical glass, which is oxide glass, having a refractive index nd ranging from 1.95 to 2.50 and an Abbé number νd ranging from 18 to 40, including essential components in the form of Si 4+ , B 3+ , La 3+ , Ti 4+ , Nb 5+ , and at least one from among Gd 3+ , Y 3+ , and Yb 3+ , including, denoted as cation %, 1 to 30% of Si 4+ , 1 to 50% of B 3+ , wherein a total of Si 4+ and B 3+ ranges from 5 to 55%, a total of 11 to 70% of La 3+ , Gd 3+ , Y 3+ , and Yb 3+ , with 10 to 50% of La 3+ , a total of 23 to 70% of Ti 4+ , Nb 5+ , Ta 5+ , and W 6+ , with equal to or greater than 1% of Nb 5+ and greater than 22% of Ti 4+ .

First claim

The invention claimed is:

1. Optical glass, which is oxide glass, having a refractive index nd ranging from 1.95 to 2.50 and an Abbé number νd ranging from 18 to 40;
comprising essential components in the form of Si 4+ , B 3+ , La 3+ , Ti 4+ , Nb 5+ , and at least one from among Gd 3+ , Y 3+ , and Yb 3+ ;
comprising, denoted as cation %,
1 to 30% of Si 4+ ;
and 1 to 50% of B 3+ , wherein a total of Si 4+ and B 3+ ranges from 5 to 55%;
a total of 21 to 70% of La 3+ , Gd 3+ , Y 3+ , and Yb 3+ , with 20 to 50% of La + ;
total of Ti 4+ , Nb 5+ , Ta 5+ , and W 6+ ranges from greater than 23% to 70% with equal to or greater than 1% of Nb 5+ and greater than 22% of Ti 4+ ; and
0 to 6% of Ba 2+ ;
wherein
the refractive index nd and Abbé number νd satisfy the following expression: nd≧2.54−(0.02×ν);
a cation ratio of a content of Ti 4+ to a content of B 3+ , Ti 4+ /B 3+ , is equal to or greater than 0.85;
a cation ratio of a content of Y 3+ to a total content of Gd 3+ , Y 3+ , and Yb 3+ , Y 3+ /(Gd 3+ +Y 3+ +Yb 3+ ), is equal to or less than 0.60; and

a cation ratio of a content of W 6+ to a total content of Ti 4+ , Nb 5+ , Ta 5+ , and W 6+ , W 6+ /(Ti 4+ +Nb 5+ +Ta 5+ +W 6+ ), is less than 0.10.

2. The optical glass according to claim 1 , which comprises equal to or greater than 1 cation % of Zr 4+ .

3. The optical glass according to claim 1 , wherein a relation between a liquidus temperature LT and a refractive index nd satisfies the following expression (1):
LT /( nd− 1)≦1250° C.  (1).

4. The optical glass according to claim 1 , wherein a content of Ge 4+ ranges from 0 to 6 cation %.

5. The optical glass according to claim 1 , wherein a content of Bi 3+ ranges from 0 to 10 cation %.

6. The optical glass according to claim 1 , which comprises essentially no Pb.

7. The optical glass according to claim 1 , wherein the content of Ba 2+ falls within a range of 0% to 4%, denoted as cation %.

8. The optical glass according to claim 1 , wherein the content of La 3+ , Gd 3+ , Y 3+ , and Yb 3+ , with 20 to 50% of La 3+ , is in a range of from 23 to 70%, denoted as cation %.

9. A press-molding glass gob, which is comprised of the optical glass according to claim 1 .

10. A method of manufacturing an optical element blank that is to be finished into an optical element by grinding and polishing, which comprises:
softening by heating and then press molding the press-molding glass gob according to claim 9 .

11. A method of manufacturing an optical element, which comprises:
preparing an optical element blank by the method according to claim 10 and processing the optical element blank that has been prepared to obtain an optical element.

12. An optical element blank, which is comprised of the optical glass according to claim 1 .

13. A method of manufacturing an optical element blank that is to be finished into an optical element by grinding and polishing, which comprises:
melting glass starting materials by heating and press molding the glass melt that has been obtained to prepare the optical element blank according to claim 12 .

14. A method of manufacturing an optical element, which comprises obtaining an optical element by processing the optical element blank according to claim 12 .

15. An optical element, which is comprised of the optical glass according to claim 1 .

16. A method of manufacturing optical glass, which comprises melting glass starting materials by heating, and molding the glass melt that has been obtained; and further comprises:
blending the glass starting materials to obtain the optical glass according to claim 1 ; and
conducting the melting in a glass melting vessel made of platinum or a platinum alloy.

Assignees

• Negishi Tomoaki
• Nishikawa Toshiyuki
• Hoya Corp

Inventors

• Negishi Tomoaki
• Nishikawa Toshiyuki

Classifications

• C03B17/061

  by lateral drawing or extrusion · CPC title

• C03B40/02

  by lubrication; Use of materials as release or lubricating compositions · CPC title

• C03B2215/46

  Lenses, e.g. bi-convex · CPC title

• C03C3/068 Primary

  containing rare earths · CPC title

• C03B17/04

  Forming tubes or rods by drawing from stationary or rotating tools or from forming nozzles · CPC title