Process for preparing an oxyhalogenide and/or oxide of actinide(s) and/or of lanthanide(s) from a medium comprising at least one molten salt

Patent metadata

Field	Value
Publication number	US-9302918-B2
Application number	US-201214345855-A
Country	US
Kind code	B2
Filing date	Sep 25, 2012
Priority date	Sep 26, 2011
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

The invention relates to a process for manufacturing an oxychloride or oxide of actinide(s) and/or of lanthanide(s) from a chloride of actinide(s) and/or of lanthanide(s) present in a medium comprising at least one molten salt of chloride type comprising a step of bringing said chloride of actinide(s) and/or lanthanide(s) present in said medium comprising at least one molten salt of chloride type into contact with a wet inert gas.

First claim

The invention claimed is:

1. A process of manufacturing an oxychloride and/or oxide of actinide(s) and/or of lanthanide(s), the process comprising:
contacting at least one selected from the group consisting of an actinide chloride and a lanthanide chloride present in a medium comprising a molten chloride salt with a wet inert gas,
wherein the contacting does not modify the molten chloride salt by ionic exchange.

2. The process according to claim 1 , wherein the molten chloride salt is selected from the group consisting of an alkali metal chloride, an alkaline earth metal chloride, and any mixture thereof.

3. The process according to claim 1 , wherein the medium comprises a mixture of molten lithium chloride and calcium chloride.

4. The process according to claim 1 , wherein the inert gas is a noble gas.

5. The process according to claim 1 , wherein the inert gas is argon.

6. The process according to claim 1 , wherein the inert gas is nitrogen.

7. The process according to claim 1 , wherein the actinide is at least one selected from the group consisting of uranium, plutonium, thorium, and a minor actinide.

8. The process according to claim 1 , wherein said contacting is carried out by bubbling the wet inert gas in the medium.

9. The process according to claim 1 , further comprising,
before said contacting, preparing the medium, in which the chloride of the at least one of an actinide and a lanthanide is present.

10. The process according to claim 1 , further comprising,
before said contacting, preparing the wet inert gas.

11. The process according to claim 1 , further comprising,
isolating the oxychloride and/or oxide formed by said process.

12. The process according to claim 1 , comprising contacting at least one actinide chloride present in the medium comprising a molten chloride salt with the wet inert gas.

13. The process according to claim 12 , wherein the actinide is at least one selected from the group consisting of uranium, plutonium, thorium, and a minor actinide.

14. The process according to claim 1 , comprising contacting at least one lanthanide chloride present in the medium comprising a molten chloride salt with the wet inert gas.

15. The process according to claim 14 , where in the lanthanide is cerium or neodymium.

16. The process according to claim 1 , further comprising recycling the molten chloride salt.

17. The process according to claim 1 , wherein the yield of the oxychloride and/or oxide of actinide(s) and/or of lanthanide(s) is more than 99%.

18. The process according to claim 1 , which is a process for manufacturing an oxychloride of an actinide or a lanthanide.

19. The process according to claim 1 , which is a process for manufacturing an oxide of an actinide or a lanthanide.

Assignees

• Commissariat Energie Atomique
• Commissariat Energie Atomique

Inventors

• Laplace Annabelle
• Vigier Jean-Francois
• Plet Thierry
• Renard Catherine
• Abraham Francis
• Slim Cyrine
• Delpech Sylvie
• Picard Gerard

Classifications

• C01F17/271

  Chlorides · CPC title

• C01G43/01

  Oxides; Hydroxides · CPC title

• C01G43/00 Primary

  Compounds of uranium · CPC title

• G21C19/48

  Non-aqueous processes · CPC title

• C01G56/00

  Compounds of transuranic elements · CPC title