Pressure-sensitive adhesive film

Patent metadata

Field	Value
Publication number	US-9302344-B2
Application number	US-201313924991-A
Country	US
Kind code	B2
Filing date	Jun 24, 2013
Priority date	Jun 25, 2012
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

The pressure-sensitive adhesive film according to the present invention comprises a resin film as a substrate and a pressure-sensitive adhesive layer provided at least on a face of the resin film. The resin film has a multi-layer constitution consisting of at least two layers. The resin film has a laser beam reflectance of 5% or higher, but 40% or lower in a wavelength range of 1000 nm to 1100 nm, and has a laser beam transmittance of 5% or lower in the said wavelength range.

First claim

What is claimed is:

1. A pressure-sensitive adhesive film comprising a resin film as a substrate and a pressure-sensitive adhesive layer provided at least on a face of the resin film, wherein:
the resin film has a multi-layer constitution consisting of at least two layers, has a laser beam reflectance of 5% or higher, but 40% or lower in a wavelength range of 1000 nm to 1100 nm, and has a laser beam transmittance of 5% or lower in the said wavelength range,
the resin film has a front face positioned on the pressure-sensitive adhesive layer side and a back face positioned opposite to the front face, the front face having a lightness L* of 50or lower, the back face having a lightness L* of 40 or higher, the front face and the back face differing in the lightness L* by 20 or larger, wherein the lightness L* is defined by the L*a*b* color space,
the resin film comprises a first layer, a second layer, and an intermediate layer placed between the first layer and the second layer, the first layer being placed on a pressure-sensitive adhesive side,
the first layer contains a black-based laser beam-absorbing agent,
the second layer contains a white-based laser beam-absorbing agent, and
the intermediate layer contains at least one of a black-based laser beam-absorbing agent and a white-based laser beam-absorbing agent.

2. The pressure-sensitive adhesive film according to claim 1 , wherein the resin film comprises a first layer forming a front face of the resin film, and the first layer comprises a carbon black as a laser beam-absorbing agent.

3. The pressure-sensitive adhesive film according to claim 1 , wherein the pressure-sensitive adhesive layer is provided on a front face of the resin film, the front face has a lightness L* of 25 or lower and a back face has a lightness L* of 65 or higher.

4. The pressure-sensitive adhesive film according to claim 1 , wherein each layer constituting the resin film comprises a resin component, with the resin component being a polyolefin resin or a polyester resin.

5. The pressure-sensitive adhesive film according to claim 1 used in an application involving cutting with a laser beam having a center wavelength of 1000 nm to 1100 nm.

6. The pressure-sensitive adhesive film according to claim 1 , wherein the first layer contains, as the black-based laser beam-absorbing agent, a carbon black having an average particle diameter of 10 nm to 500 nm.

7. The pressure-sensitive adhesive film according to claim 1 , wherein the second layer contains at least one white-based laser beam-absorbing agent selected from the group consisting of calcium carbonate, silica, alumina, titanium oxide, talc, clay, aluminum silicate, basic lead carbonate, zinc oxide, strontium titanate, barium sulfate, and calcium sulfate.

8. The pressure-sensitive adhesive film according to claim 1 , wherein the second layer contains at least one white-based laser beam-absorbing agent selected from the group consisting of calcium carbonate, silica, and titanium oxide.

9. The pressure-sensitive adhesive film according to claim 1 , wherein the second layer contains a white-based laser beam-absorbing agent having an average particle diameter of 0.01 μm to 5 μm.

10. The pressure-sensitive adhesive film according to claim 1 , wherein the second layer contains a white-based laser beam-absorbing agent having an average particle diameter of 0.01 μm to 5 μm, the white-based laser beam-absorbing agent being at least one selected from the group consisting of calcium carbonate, silica, and titanium oxide.

11. The pressure-sensitive adhesive film according to claim 1 , wherein the first layer contains as the black-based laser beam-absorbing agent a carbon black having an average particle diameter of 10 nm to 500 nm, and the second layer contains a white-based laser beam-absorbing agent having an average particle diameter of 0.01μm to 5 μm, the white-based laser beam-absorbing agent being at least one selected from the group consisting of calcium carbonate, silica, and titanium oxide.

12. The pressure-sensitive adhesive film according to claim 1 , wherein the second layer further contains an organic compound which is a laser beam-absorbing agent different from the black-based laser beam-absorbing agent and the white-based laser beam-absorbing agent, and the organic compound is at least one selected from the group consisting of a quaterrylene-based compound, a perylene-based compound, a phthalocyanine-based compound, a cyanine-based compound, an aminium-based compound, a naphthalocyanine-based compound, a naphthoquinone-based compound, a diimonium-based compound, an anthraquinone-based compound, and an aromatic dithiol-based metal complex.

13. The pressure-sensitive adhesive film according to claim 1 , wherein the second layer further contains an organic compound which is a laser beam-absorbing agent different from the black-based laser beam-absorbing agent and the white-based laser beam-absorbing agent, and the organic compound is an organic quaterrylene bisimide.

14. The pressure-sensitive adhesive film according to claim 1 , wherein the first layer is thicker than the second layer, and the thickness of the second layer is 25 μm or smaller.

15. The pressure-sensitive adhesive film according to claim 1 , wherein the intermediate layer has a thickness accounting for 10% to 50% of the thickness of the entire resin film.

16. The pressure-sensitive adhesive film according to claim 1 , wherein the pressure-sensitive adhesive layer comprises at least one polymer selected from the group consisting of natural rubber, polybutadiene, polyisoprene, butyl rubber, styrene-butadiene-styrene block copolymer, styrene-ethylene/butylene-styrene block copolymer, styrene-ethylene/butylene random copolymer, ethylene propylene rubber, propylene butene rubber, and ethylene propylene butene rubber.

17. A pressure-sensitive adhesive film capable of being cut with a laser beam having a center wavelength of 1000 nm to 1100 nm, the pressure-sensitive adhesive film comprising:
a resin film as a substrate, the resin film having a front face and a back face positioned opposite to the front face, the resin film having a tri-layer constitution consisting of a first layer constituting the front face, a second layer constituting the back face, and an intermediate layer placed between the first layer and the second layer; and
a pressure-sensitive adhesive layer provided above the front face of the resin film, wherein
the resin film has a laser beam reflectance of 5% or higher, but 40% or lower in a wavelength range of 1000 nm to 1100 nm, and has a laser beam transmittance of 5% or lower in the wavelength range,
the front face of the resin film has a lightness L* of 25 or lower, the back face of the resin film has a lightness L* of 65 or higher, and the front face and the back face of the resin film differ in the lightness L* by 20 or larger, wherein the lightness L* is defined by the L*a*b* color space,
each layer constituting the resin film comprises a resin component, with the resin component being a polyolefin resin or a polyester resin,
the first layer contains as a black-based laser beam-absorbing agent a carbon black having an average particle diameter of 10 nm to 500 nm,
the second layer contains at least one white-based laser beam-absorbing agent selected from the group consisting of calcium carbonate, silica, and titanium oxide, the white-based laser beam-absorbing agent having an average particle diameter of 0.01 μm to 5 μm,
the second layer further contains an organic compound which is a laser beam-absorbing agent different from th

Assignees

• Nitto Denko Corp
• Nitto Europe Nv

Inventors

• Yamashita Kenta
• Yamamoto Mitsushi
• Pinxten Donald
• Cryns Bert

Classifications

• B32B27/36

  comprising polyesters · CPC title

• B32B27/20

  using fillers, pigments, thixotroping agents · CPC title

• B23K26/18

  using absorbing layers on the workpiece, e.g. for marking or protecting purposes · CPC title

• B23K26/36

  Removing material (B23K26/55, B23K26/57 take precedence) · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title