Apparatus and process for the continuous reaction of liquids with gases

Patent metadata

Field	Value
Publication number	US-9302237-B2
Application number	US-201414147823-A
Country	US
Kind code	B2
Filing date	Jan 6, 2014
Priority date	Jan 11, 2013
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

The present invention relates to an apparatus of the loop Venturi reactor type for the continuous reaction of liquids with gases, in particular for hydrogenations, oxidations or acetylations, e.g. for the preparation of toluenediamine by hydrogenation of dinitrotoluene, and a process for the continuous reaction of liquid reactants with gaseous reactants in the apparatus. In the apparatus of the invention, the diversion of an internal circulatory flow in the reactor is effected by means of a diversion pan which is arranged underneath a heat exchanger.

First claim

The invention claimed is:

1. An apparatus, comprising:
a vertically elongated reactor in which there is a reaction space,
at least one heat exchanger which is arranged within the reactor,
at least one cooling inlet for introducing the cooling medium into the heat exchanger,
at least one cooling outlet for taking the cooling medium off from the heat exchanger,
at least one gaseous reactant inlet for introducing the gaseous reactant into the reaction space,
at least one liquid reactant inlet for introducing the liquid reactant into the reaction space,
at least one mixing chamber,
at least one downward-directed driving jet nozzle for introducing the reaction medium, the outlet of which is arranged above the at least one mixing chamber and which is in fluid connection with the reaction space,
at least one reaction medium outlet for taking the reaction medium off from the reactor, and
at least one diverter arranged below the heat exchanger and below the mixing chamber for diverting the reaction medium flowing downward through the mixing chamber in such a way that the reaction medium once again flows upward through the heat exchanger,
wherein the diverter is a diversion pan having a surface oriented in the transverse direction of the reactor and a lateral border extending in the longitudinal direction of the reactor.

2. The apparatus as claimed in claim 1 , wherein the heat exchanger comprises heat exchanger tubes.

3. The apparatus as claimed in claim 1 , wherein the heat exchanger comprises heat exchanger tubes and a region surrounding the heat exchanger tubes is in fluid connection with the cooling inlet for introducing the cooling medium and the cooling outlet for taking off the cooling medium and an inner region of the heat exchanger tubes forms part of the reaction space and is in fluid connection with the at least one driving jet nozzle and the reaction medium outlet for taking off the reaction medium.

4. The apparatus of claim 1 , wherein a horizontal cross-sectional area of the diversion pan occupies from 60 to 98% of the area taken up by the lower end of the heat exchanger in the cross section of the reactor.

5. The apparatus of claim 1 , wherein the gaseous reactant inlet for introduction of the gaseous reactant into the reaction space is installed below the heat exchanger and at the same time above the diverter for diverting the reaction medium flowing downward through the mixing chamber.

6. The apparatus as claimed in claim 5 , wherein a further gaseous reactant inlet for introducing the gaseous reactant into the reaction space is additionally provided above the heat exchanger.

7. The apparatus of claim 1 , wherein the at least one mixing chamber is connected, at its lower end, to a diffuser.

8. The apparatus of claim 1 , wherein each ejector, which is arranged from the top downward in the longitudinal direction of the reactor, comprises a driving jet nozzle, a mixing chamber, optionally a diffuser and optionally at least one further cylindrical section comprising at least three sections underneath the driving jet nozzle: an upper section which has an essentially round cross section having the diameter d1, a cylindrical section diffuser as a middle section whose cross section widens compared to the upper section from the top downward and a lower section which has an essentially round cross section having the diameter d2, where d2>d1.

9. The apparatus as claimed in claim 8 , wherein the apparatus comprises a plurality of ejectors.

10. The apparatus of claim 1 , wherein the driving jet nozzles are multiorifice nozzles.

11. The apparatus of claim 1 , wherein at least one liquid reactant inlet for introducing the liquid reactant into the reaction space is provided for each driving jet nozzle.

12. The apparatus of claim 1 , wherein the diversion pan has emptying openings.

13. The apparatus of claim 1 , wherein an external circuit produces a fluid connection between the reaction medium outlet for taking the reaction medium off from the reactor and the at least one driving jet nozzle for introducing the reaction medium into the reactor.

14. The apparatus as claimed in claim 13 , wherein a pump is arranged in the external circuit.

15. A process, comprising continuous reaction of liquid reactants with gaseous reactants in the apparatus of claim 1 .

16. The process as claimed in claim 15 , wherein the heat exchanger is a shell-and-tube heat exchanger and the reaction medium flows through heat exchanger tubes and the cooling medium surrounds the heat exchanger tubes.

17. The process of claim 15 , wherein the reaction is occurs in the presence of a suspended or dissolved catalyst.

18. The process of claim 15 , wherein the liquid reactant is a nitroaromatic and the gaseous reactant is hydrogen.

19. The process of claim 15 , wherein the reaction product is taken off from the external circuit.

Assignees

• Basf Se

Inventors

• Bey Oliver
• Kunkelmann Christian
• Bauer Roland
• Raichle Andreas
• Riechers Hartmut
• Zehner Peter

Classifications

• B01J2219/00081

  Tubes · CPC title

• B01J19/2465

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title

• B01J8/228

  externally, i.e. the particles leaving the vessel and subsequently re-entering it · CPC title

• B01J8/226

  internally, i.e. the particles rotate within the vessel · CPC title

• B01J19/246

  internally, i.e. the mixture circulating inside the vessel such that the upward stream is separated physically from the downward stream(s) · CPC title