Method and apparatus for producing large, single-crystals of aluminum nitride
US-2015079329-A1 · Mar 19, 2015 · US
US9299880B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9299880-B2 |
| Application number | US-201414208379-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 13, 2014 |
| Priority date | Mar 15, 2013 |
| Publication date | Mar 29, 2016 |
| Grant date | Mar 29, 2016 |
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In various embodiments, light-emitting devices incorporate smooth contact layers and polarization doping (i.e., underlying layers substantially free of dopant impurities) and exhibit high photon extraction efficiencies.
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What is claimed is: 1. An ultraviolet (UV) light-emitting device comprising: a substrate having an Al y Ga 1-y N top surface, wherein y≧0.4; a light-emitting device structure disposed over the substrate, the device structure comprising a plurality of layers each comprising Al x Ga 1-x N; an undoped graded Al 1-z Ga z N layer disposed over the device structure, a composition of the graded layer being graded in Ga concentration z such that the Ga concentration z increases in a direction away from the light-emitting device structure; a p-doped Al 1-w Ga w N cap layer disposed over the graded layer, the p-doped Al 1-w Ga w N cap layer having (i) a thickness between approximately 2 nm and approximately 30 nm, (ii) a surface roughness of less than approximately 6 nm over a sample size of approximately 200 μm×300 μm, and (iii) a Ga concentration w≧0.8; and a metallic contact disposed over the Al 1-w Ga w N cap layer and comprising at least one metal, the metallic contact having a contact resistivity to the Al 1-w Ga w N cap layer of less than approximately 1.0 mΩ-cm 2 . 2. The light-emitting device of claim 1 , wherein the Al 1-w Ga w N cap layer is doped with Mg. 3. The light-emitting device of claim 1 , wherein the Al 1-w Ga w N cap layer is at least partially relaxed. 4. The light-emitting device of claim 1 , wherein the light-emitting device has a photon extraction efficiency of greater than 25%. 5. The light-emitting device of claim 1 , wherein the graded layer and Al 1-w Ga w N cap layer collectively absorb less than 80% of UV photons generated by the light-emitting device structure and having a wavelength less than 340 nm. 6. The light-emitting device of claim 1 , wherein the at least one metal of the metallic contact comprises Ni/Au or Pd. 7. The light-emitting device of claim 1 , wherein the metallic contact has a reflectivity to light generated by the light-emitting device structure of approximately 60% or less. 8. The light-emitting device of claim 1 , wherein the metallic contact has a reflectivity to light generated by the light-emitting device structure of approximately 30% or less. 9. The light-emitting device of claim 1 , wherein the metallic contact has the form of a plurality of discrete lines and/or pixels of the at least one metal, portions of the Al 1-w Ga w N cap layer not being covered by the metallic contact. 10. The light-emitting device of claim 9 , further comprising a reflector disposed over the metallic contact and the uncovered portions of the Al 1-w Ga w N cap layer. 11. The light-emitting device of claim 10 , wherein the reflector comprises a metal having greater than 90% reflectivity to UV light and a work function less than approximately 4.5 eV. 12. The light-emitting device of claim 10 , wherein the reflector has a contact resistivity to the Al 1-w Ga w N cap layer of greater than approximately 5 mΩ-cm 2 . 13. The light-emitting device of claim 10 , wherein the reflector has a contact resistivity to the Al 1-w Ga w N cap layer of greater than approximately 10 mΩ-cm 2 . 14. The light-emitting device of claim 10 , wherein the reflector comprises Al. 15. The light-emitting device of claim 1 , wherein the light-emitting device comprises a light-emitting diode. 16. The light-emitting device of claim 1 , wherein (i) a bottom portion of the graded layer proximate the active device structure has a Ga concentration z substantially equal to a Ga concentration of a layer directly thereunder and (ii) a top portion of the graded layer opposite the bottom portion of the graded layer has a Ga concentration z of approximately 1. 17. The light-emitting device of claim 1 , wherein the substrate consists essentially of doped or undoped AlN.
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