Recovering performance of degraded solar cells with electrical pulses

Patent metadata

Field	Value
Publication number	US-9299503-B2
Application number	US-201313785538-A
Country	US
Kind code	B2
Filing date	Mar 5, 2013
Priority date	Mar 5, 2013
Publication date	Mar 29, 2016
Grant date	Mar 29, 2016

Abstract

A system and method for recovering performance of a degraded solar cell are provided. The system includes a solar cell having electrodes arranged on opposing sides of an electrolyte and defining a solar cell polarity therebetween and a power source connected to the electrodes. A controller controls the power source for applying a voltage pulse(s) across the solar cell. The voltage pulse may be applied at the solar cell polarity so as to define a forward electrical bias of the solar cell.

First claim

We claim:

1. A method of recovering performance of a degraded solar cell having first and second electrodes defining a solar cell polarity therebetween, the degraded solar cell having ions accumulated in an electrolyte of the solar cell so as to block ion transport channels of the electrolyte, comprising:
connecting a power source to the first and second electrodes; and
sequentially applying a series of voltage pulses with the power source across the solar cell at the solar cell polarity providing a forward electrical bias of the solar cell, each voltage pulse:
spaced from an adjacent voltage pulse by a time period, the time period being in a range of 1 second to 3 seconds: and
defined by a pulse height of between about 2 V and 3 V and a pulse width of between about 150 ms and 200 ms.

2. The method of claim 1 further comprising the step of injecting electrons into the electrolyte so as to improve a flow characteristic through the ion transport channels.

3. The method of claim 1 further comprising injecting a number of electrons into the electrolyte that is no more than a number of ions in the electrolyte.

4. A method of recovering performance of a degraded solar cell having first and second electrodes, the degraded solar cell having ions accumulated in an electrolyte of the solar cell so as to block ion transport channels of the electrolyte, the method comprising:
connecting a power source to first and second electrodes;
sequentially applying a series of voltage pulses with the power source across the solar cell for forward electrical biasing of the solar cell, each voltage pulse:
spaced from an adjacent voltage pulse by a time period, the time period being in a range of 1 second to 3 seconds; and
defined by a pulse height of between about 2 V and 3 V and a pulse width of between about 150 ms and 200 ms;
injecting electrons into the electrolyte during application of each voltage pulse; and
redistributing the ions by moving at least some of the ions so as to improve a flow characteristic through the ion transport channels.

5. The method of claim 4 wherein redistributing the ions includes changing a concentration of ions in the electrolyte.

6. The method of claim 4 further comprising injecting a number of electrons into the electrolyte that is no more than a number of ions in the electrolyte.

Assignees

• Wisconsin Alumni Res Found

Inventors

• Jiang Hongrui
• Zhang Xi
• Huang Xuezhen

Classifications

• H10F71/10

  the devices comprising amorphous semiconductor material · CPC title

• H01M10/4242

  Regeneration of electrolyte or reactants · CPC title

• H01L2251/568

  Electricity · mapped topic

• H01G9/2031

  comprising titanium oxide, e.g. TiO2 (H01G9/2036 takes precedence) · CPC title

• Y02E10/542

  Dye sensitized solar cells · CPC title