Polymer film, retardation film, polarizing plate, liquid crystal display, and compound

Patent metadata

Field	Value
Publication number	US-9296877-B2
Application number	US-201414470249-A
Country	US
Kind code	B2
Filing date	Aug 27, 2014
Priority date	Dec 1, 2010
Publication date	Mar 29, 2016
Grant date	Mar 29, 2016

Abstract

Provided is a polymer film containing at least one of a compound represented by formula (1) of hydrates, solvates, or salts thereof. Y is a methine group or nitrogen atom. Q a , Q b , and Q c are a single bond or a divalent linking group. R a , R b , and R c , are hydrogen atom, alkyl group, alkenyl group, alkynyl group, aryl group, cyano group, halogen group, or heterocyclic group. X 2 is a single bond or a divalent linking group. X 1 is a single bond or a predetermined divalent linking group. R 1 and R 2 are a hydrogen atom, alkyl group, alkenyl group, alkynyl group, aryl group, or heterocyclic group

First claim

What is claimed is:

1. A polymer film comprising:
at least one kind of compounds represented by Formula (I), hydrates of the compounds, solvates of the compounds, and salts of the compounds:

wherein in Formula (I), Y represents —N— or —C(-Q d -R d )—; Q a , Q b , Q c , and Q d each independently represent a single bond or a divalent linking group; R a , R b , R c , and R d each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a cyano group, a halogen group, or a heterocyclic group, wherein R a and R b are optionally bonded to each other to form a ring, or R a and R d are optionally bonded to each other to form a ring; X 2 represents a single bond or a divalent linking group; X 1 represents a single bond or a divalent group selected from a divalent linking group G 1 :

in each formula of said divalent linking group G 1 , the side indicated by symbol * is a bonding site to the nitrogen atom introduced into the pyrimidine ring or pyridine ring in the compound represented by the formula; and R g represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group; and R 1 and R 2 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group, wherein R 1 and R 2 are optionally bonded to each other to form a ring, provided that one of -Q c -R c and N(X 1 R 1 )X 2 R 2 is —NH 2 and both are not simultaneously —NH 2 and that when Y is a nitrogen atom and when N(X 1 R 1 )X 2 R 2 is —NH 2 , -Q a -R a is not —NH 2 ,
wherein the compound represented by Formula (1) has a molecular weight of 200 to 2000,
wherein Formula (I) is Formula (II):

wherein symbols in Formula (II) are each synonymous with those in Formula (I); Y represents —N— or —C(-Q d -R d )—, and Z represents —C(-Q b -R b )—; X 1 represents a single bond or a linking group selected from the group consisting of divalent linking groups represented by a divalent linking group G 2 ; X 2 represents a single bond or a divalent linking group; R 1 and R 2 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocycle, and at least one of —X 1 —R 1 and —X 2 —R 2 is a substituent other than a hydrogen atom; Q a , Q b , and Q d each independently represent a single bond or —O—, —S—, or —NR′—, wherein R′ represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocycle, and Q a and R a , Q d and R d , or Q b and R b are optionally bonded to each other to form a ring, or -Q a -R a —R d -Q d - or -Q a -R a —R b -Q b - optionally forms a ring; and R a represents a hydrogen atom, a halogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocycle; and

wherein symbols in the divalent linking group G 2 are each synonymous with those in the divalent linking group G 1 .

2. The polymer film according to claim 1 , wherein Formula (II) is Formula (III) or Formula (V):

wherein symbols in Formula (III) are each synonymous with those in Formula (II);

wherein symbols in Formula (V) are each synonymous with those in Formula (II).

3. The polymer film according to claim 1 , wherein Formula (II) is Formula (IIIa) or (Va):

wherein symbols in Formula (IIIa) are each synonymous with those in Formula (II);

wherein symbols in Formula (Va) are each synonymous with those in Formula (II).

4. The polymer film according to claim 1 , wherein Formula (II) is Formula (IIIb) or Formula (Vb):

wherein symbols in Formula (Mb) are each synonymous with those in Formula (II);

wherein symbols in Formula (Vb) are each synonymous with those in Formula (II).

5. The polymer film according to claim 1 , wherein Formula (II) is Formula (IIIc) or Formula (Vc):

wherein symbols in Formula (IIIc) are each synonymous with those in Formula (II); and R 9 represents —O—Ar, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group, wherein Ar represents an aryl group;

wherein symbols in Formula (Vc) are each synonymous with those in Formula (II); and R 9 represents —O—Ar, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group, and Ar represents an aryl group.

6. The polymer film according to claim 1 , wherein Formula (II) is Formula (IIId) or Formula (Vd):

wherein symbols in Formula (IIId) are each synonymous with those in Formula (II);

wherein symbols in Formula (Vd) are each synonymous with those in Formula (II).

7. The polymer film according to claim 1 , wherein Formula (II) is Formula (IIIe) or (Ve):

wherein symbols in Formula (Me) are each synonymous with those in Formula (II); and Ar represents an aryl group;

wherein symbols in Formula (Ve) are each synonymous with those in Formula (II); and Ar represents an aryl group.

8. The polymer film according to claim 1 , wherein Q a represents a single bond or —O—, —NH—, or —N(R)—, wherein R is an alkyl group having 1 to 8 carbon atoms; and R a represents a hydrogen atom, a halogen atom, or an alkyl group having 1 to 8 carbon atoms.

9. The polymer film according to claim 1 , wherein Formula (II) is Formula (IIIf), (IIIg), (IIIh) or (Vf):

wherein in Formula (IIIf), R a7 represents an alkyl group having 1 to 8 carbon atoms; and R 6 , R 7 and R 8 each independently represent a hydrogen atom, a halogen atom, a nitro group, a cyano group, a carbamoyl group, an N-alkylcarbamoyl group having 1 to 8 carbon atoms, an N,N-dialkylcarbamoyl group having 1 to 16 carbon atoms, a sulfamoyl group, an N-alkylsulfamoyl group having 1 to 8 carbon atoms, an N,N-dialkylsulfamoyl group having 1 to 16 carbon atoms, an alkyl group having 1 to 16 carbon atoms, an alkoxy group having 1 to 16 carbon atoms, an alkylamino group having 1 to 16 carbon atoms, a dialkylamino gr

Assignees

• Fujifilm Corp

Inventors

• Yamamoto Aiko
• Tanaka Satoshi
• Niori Teruki
• Nagura Masato
• Noro Masaki
• Yoshida Aiko
• Fukagawa Nobutaka
• Kuwayama Yasukazu

Classifications

• C08L1/08

  Cellulose derivatives · CPC title

• G02B5/305

  including organic materials, e.g. polymeric layers · CPC title

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• Y10T428/1041

  Cross-Sectional Technologies · mapped topic

• C07D213/75

  Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates · CPC title