System and method of a catalytic reactor having multiple sacrificial coatings

Patent metadata

Field	Value
Publication number	US-9291082-B2
Application number	US-201213627973-A
Country	US
Kind code	B2
Filing date	Sep 26, 2012
Priority date	Sep 26, 2012
Publication date	Mar 22, 2016
Grant date	Mar 22, 2016

Abstract

A system includes a catalytic reactor configured to mount to a combustor. The catalytic reactor includes a catalyst configured to reduce emissions associated with combustion in the combustor. The catalytic reactor also includes a first and a second sacrificial coating disposed over the catalyst prior to mounting of the catalytic reactor into the combustor, wherein the first and second sacrificial coatings are removable while the catalytic reactor is mounted to the combustor without damaging the catalyst.

First claim

The invention claimed is:

1. A system, comprising:
a catalytic reactor configured to mount to a combustor, wherein the catalytic reactor comprises:
a catalyst configured to reduce emissions associated with combustion in the combustor; and
a first sacrificial coating disposed over the catalyst prior to mounting of the catalytic reactor into the combustor;
a second sacrificial coating disposed over the first sacrificial coating prior to mounting of the catalytic reactor to the combustor, wherein the second sacrificial coating has a greater temperature resistance than the first sacrificial coating;

wherein the first and second sacrificial coatings are removable while the catalytic reactor is mounted to the combustor without damaging the catalyst.

2. The system of claim 1 , comprising a third sacrificial coating disposed over the second sacrificial coating prior to mounting of the catalytic reactor to the combustor, wherein the second and third sacrificial coatings are different from one another, and the third sacrificial coating is configured to allow combustion to take place in a catalytic environment when the first sacrificial coating, the second sacrificial coating, and the third sacrificial coating are disposed over the catalyst, wherein the first, second, and third sacrificial coatings are removable while the catalytic reactor is mounted to the combustor without damaging the catalyst.

3. The system of claim 1 , comprising a third sacrificial coating disposed over the second sacrificial coating, wherein at least one of the first, second, and third sacrificial coating is water soluble, wherein at least one of the first, second, and third sacrificial coatings comprises a catalytic material.

4. The system of claim 1 , wherein the first sacrificial coating comprises at least one of a silicate, an inorganic halide, a metal nitrate, a metal chlorate, a metal acetate, a metal sulfate, an organometallic compound, a mixed organic-inorganic oxide composition, a halogenated carbon compound, or a combination thereof.

5. The system of claim 1 , wherein the first sacrificial coating comprises a ceramic.

6. The system of claim 1 , wherein the second sacrificial coating degrades with temperature over time, and the first sacrificial coating is water soluble.

7. The system of claim 6 , comprising a third sacrificial coating disposed over the second sacrificial coating prior to mounting of the catalytic reactor to the combustor, wherein the first, second, and third sacrificial coatings are removable while the catalytic reactor is mounted to the combustor without damaging the catalyst, wherein the third sacrificial coating comprises a catalytic material.

8. The system of claim 1 , comprising the combustor having the catalytic reactor.

9. The system of claim 8 , comprising a gas turbine engine having the combustor with the catalytic reactor.

10. The system of claim 1 , wherein the first sacrificial coating comprises at least one of a silicate, an inorganic halide, a metal nitrate, a metal chlorate, a metal sulfate, or a combination thereof.

11. A method, comprising:
applying a first sacrificial coating over a catalyst of a catalytic reactor;
applying a second sacrificial coating over the first sacrificial coating, wherein the second sacrificial coating has a greater temperature resistance than the first sacrificial coating; and
mounting the catalytic reactor to a combustor after applying the first sacrificial coating over the catalyst, wherein the sacrificial coating is removable while the catalytic reactor is mounted to the combustor without damaging the catalyst.

12. The method of claim 11 , wherein applying the first sacrificial coating comprises applying a green slurry or a sol gel to form the first sacrificial coating over the catalyst.

13. The method of claim 11 , wherein the first sacrificial coating comprises at least one of a silicate, an inorganic halide, a metal nitrate, a metal chlorate, a metal acetate, a metal sulfate, an organometallic compound, a mixed organic-inorganic oxide composition, or a combination thereof.

14. The method of claim 11 , comprising operating a gas turbine engine having the combustor with the catalytic reactor, wherein the first sacrificial coating protects the catalyst during a first period of combustion in the combustor to inhibit fouling of the catalyst.

15. The method of claim 11 , wherein the first sacrificial coating comprises at least one of a silicate, an inorganic halide, a metal nitrate, a metal chlorate, a metal sulfate, or a combination thereof.

16. The method of claim 11 , comprising removing the second sacrificial coating by a first removal process, and subsequently removing the first sacrificial coating by a second removal process.

17. The method of claim 16 , wherein the first removal process comprises thermally degrading the second sacrificial coating with temperature over time to remove the second sacrificial coating, and the second removal process comprises water washing the first sacrificial coating to remove the first sacrificial coating after removal of the second sacrificial coating.

18. The method of claim 11 , comprising removing the first sacrificial coating and the second sacrificial coating to reveal the catalyst after mounting the catalytic reactor to the combustor.

19. The method of claim 18 , wherein removing the first sacrificial coating comprises applying a water wash, applying vibration, applying pressure waves, thermally degrading, ablating, or using a frangible process, or a combination thereof, to remove the first sacrificial coating.

20. A method, comprising:
protecting a catalyst of a catalytic reactor mounted to a combustor with at least a first and a second sacrificial coating during a first period of combustion in the combustor, wherein the second sacrificial coating has a greater temperature resistance than the first sacrificial coating; and
reducing emissions with the catalyst during a second period of combustion after the first period of combustion in the combustor, wherein the at least one sacrificial coating is removed from the catalyst after the first period and before the second period while the catalytic reactor remains mounted to the combustor.

Assignees

• Gen Electric

Inventors

• Everhart Richard Todd
• Hefner Rebecca Evelyn
• Kraemer Cristina Colindres
• Kraemer Gilbert Otto
• Pabla Surinder Singh
• Pope Stephen Gerard

Classifications

• B01D53/8643

  Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides · CPC title

• F23C13/02

  characterised by arrangements for starting the operation, e.g. for heating the catalytic material to operating temperature · CPC title

• Y10T29/49885

  with coating before or during assembling · CPC title

• Y10T29/49345

  Catalytic device making · CPC title

• B01D2257/702

  Hydrocarbons · CPC title