Laundry detergent particles

Patent metadata

Field	Value
Publication number	US-9290724-B2
Application number	US-201113878447-A
Country	US
Kind code	B2
Filing date	Sep 1, 2011
Priority date	Oct 14, 2010
Publication date	Mar 22, 2016
Grant date	Mar 22, 2016

Abstract

The present invention provides a coated lenticular or disc detergent particle having perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm and z is from 2 to 8 mm, wherein the particle comprises: (i) from 40 to 90 wt % surfactant selected from anionic surfactant and non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; and (iii) from 0.0001 to 0.1 wt % dye, wherein the dye is covalently bound to from 1 to 4 sulphonate groups, wherein the inorganic salts and the dye are present on the detergent particle as a coating and the surfactant is present as a core.

First claim

We claim:

1. A coated detergent particle having perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm, and z is from 2 to 8 mm, wherein x is not equal to y and z, and wherein the particle consists of:
a core consisting of surfactant, and optionally, at least one of soap, water, fluorescent agent, perfume, pigment, carboxymethylcellulose, polyethylene glycol, polyvinyl alcohol, polyethylene imine, ethoxylated polyethylene imine, water soluble polyester polymer, polycarboxylate, polyacrylate, maleic/acrylic acid copolymer, lauryl methacrylate/acrylic acid copolymer, enzyme, or enzyme stabilizer; and
a coating consisting of water soluble inorganic salts, dye and optionally, at least one of water, fluorescent agent, perfume, pigment, carboxymethylcellulose, polyethylene glycol, polyvinyl alcohol, polyethylene imine, ethoxylated polyethylene imine, water soluble polyester polymer, polycarboxylate, polyacrylate, maleic/acrylic acid copolymer, lauryl methacrylate/acrylic acid copolymer, enzyme, or enzyme stabilizer; and
wherein from 40 to 90 wt % of the coated detergent particle is the surfactant;
wherein the surfactant is selected from anionic surfactant, non-ionic surfactant, and combinations thereof;
wherein from 1 to 40 wt % of the coated detergent particle is the water soluble inorganic salts;
wherein from 0.001 to 0.01 wt % of the coated detergent particle is the dye; and
wherein the dye is covalently bound to from 1 to 4 sulphonate groups.

2. A coated detergent particle according to claim 1 , wherein the dye is an acid dye.

3. A coated detergent particle according to claim 1 , wherein the dye is selected from those having: anthraquinone; mono-azo; bis-azo; xanthene; phthalocyanine; and phenazine chromophores.

4. A coated detergent particle according to claim 3 , wherein the dye is selected from those having: anthraquinone; mono-azo; and phenazine chromophores.

5. A coated detergent particle according to claim 1 , wherein the dye is selected from: acid blue 80, acid blue 62, acid violet 43, acid green 25, direct blue 86, acid blue 59, acid blue 98, direct violet 9, direct violet 99, direct violet 35, direct violet 51, acid violet 50, acid yellow 3, acid red 94, acid red 51, acid red 95, acid red 92, acid red 98, acid red 87, acid yellow 73, acid red 50, acid violet 9, acid red 52, food black 1, food black 2, acid red 163, acid black 1, acid orange 24, acid yellow 23, acid yellow 40, acid yellow 11, acid red 180, acid red 155, acid red 1, acid red 33, acid red 41, acid red 19, acid orange 10, acid red 27, acid red 26, acid orange 20, acid orange 6, sulphonated Al and Zn phthalocyanines.

6. A coated detergent particle according to claim 1 , wherein the water soluble inorganic salts are configured to act as builders.

7. A coated detergent particle according to claim 6 , wherein the water soluble inorganic salt is sodium carbonate.

8. A coated detergent particle according to claim 1 , wherein the surfactant consists of: from 15 to 85 wt % on total surfactant of the anionic surfactant and from 5 to 75 wt % on total surfactant of the non-ionic surfactant.

9. A coated detergent particle according to claim 1 , wherein the anionic surfactant is selected from alkyl benzene sulphonates; alkyl ether sulphates; alkyl sulphates.

10. A coated detergent particle according to claim 9 , wherein the anionic surfactant is selected from sodium lauryl ether sulfate with 1 to 3 ethoxy groups, sodium C 10 to C 15 alkyl benzene sulphonates and sodium C 12 to C 18 alkyl sulphates.

11. A coated detergent particle according to claim 1 , wherein the non-ionic surfactant is a 10 to 50 EO non-ionic surfactant.

12. A coated detergent particle according to claim 11 , wherein the non-ionic surfactant is the condensation products of aliphatic C 8 to C 18 primary or secondary linear or branched alcohols with 20 to 35 ethylene oxide groups.

13. A coated detergent particle according to claim 1 , wherein from 20 to 40 wt % of the coated detergent particle is the water soluble inorganic salts.

14. A coated detergent particle according to claim 13 , wherein from 25 to 35 wt % of the coated detergent particle is the water soluble inorganic salts.

15. A coated detergent particle according to claim 1 , wherein the water is present in the coated detergent particle in an amount from 1 to 15 wt %.

16. A coated detergent particle according to claim 15 , wherein the water is present in the coated detergent particle in an amount from 1 to 5 wt %.

17. A coated detergent particle according to claim 1 , wherein the coated detergent particle is present in a detergent formulation in an amount from 80 to 100 wt %, and wherein the detergent formulation is enclosed in a package.

18. A coated detergent particle according to claim 1 , wherein the coated detergent particle is present in a detergent formulation in an amount from 90 to 100 wt %, and wherein the detergent formulation is enclosed in a package.

19. A plurality of coated detergent particles according to claim 1 , wherein at least 90 to 100% of the coated detergent particles in the x, y and z dimensions are within a 20% variable from the largest to the smallest coated detergent particle.

Assignees

• Batchelor Stephen Norman
• Chapple Andrew Paul
• Keningley Stephen Thomas
• Conopco Inc

Inventors

• Batchelor Stephen Norman
• Chapple Andrew Paul
• Keningley Stephen Thomas

Classifications

• C11D17/0039

  Coated compositions or coated components in the compositions, (micro)capsules · CPC title

• C11D3/08

  Silicates · CPC title

• C11D3/046

  Salts · CPC title

• C11D3/40 Primary

  Dyes {; Pigments} · CPC title

• C11D3/10

  Carbonates {; Bicarbonates} · CPC title