Process for synthesizing hydrocarbons from synthesis gas with control of the temperature of the external loop

Patent metadata

Field	Value
Publication number	US-9290699-B2
Application number	US-201314408621-A
Country	US
Kind code	B2
Filing date	Apr 10, 2013
Priority date	Jun 18, 2012
Publication date	Mar 22, 2016
Grant date	Mar 22, 2016

Abstract

The present invention concerns a process for the synthesis of hydrocarbons from a feed comprising synthesis gas, in which a solid catalyst comprising cobalt is used in a three-phase reaction section operated such that said catalyst is maintained in suspension in a liquid phase by movement of a gas phase from the bottom to the top of said reaction section, said process comprising an external loop for separating waxes, characterized in that:
1) the theoretical ratio P H2O :P H2 in the external loop for separating waxes is determined using the following calculation:

P H2O :P H2 theoretical= Cv /( R 1− Rft×Cv )
where Cv=(CO inlet −CO degas )/CO inlet R1=H 2 inlet /CO inlet Rft=(H 2 inlet −H 2 degas )/(CO inlet −CO degas )
2) if the theoretical ratio P H2O :P H2 determined in step 1) has a value of R threshold or higher, the temperature in the degassing means for the external loop for separating waxes is reduced, 3) steps 1) to 2) are repeated until the theoretical ratio P H2O :P H2 has a value strictly less than R threshold , where R threshold is in the range 0.1 to 1.1.

First claim

The invention claimed is:

1. A process for the synthesis of hydrocarbons from a feed comprising synthesis gas, in which a solid catalyst comprising cobalt is present in a three-phase reaction section operated such that said catalyst is maintained in suspension in a liquid phase by movement of a gas phase from the bottom to the top of said reaction section, said process comprising separating waxes in an external loop having a degassing means, wherein
1) a theoretical ratio P H20 :P H2 in the external loop for separating waxes is determined by the following calculation:
P H20 :P H2 theoretical= Cv /( R 1− Rft×Cv )

where Cv=(CO inlet −CO degas )/CO inlet
R1=H 2 inlet /CO inlet
Rft=(H 2 inlet −H 2 degas )/(CO inlet −CO degas )

wherein
CO inlet is a measurement of the molar flow rate of carbon monoxide entering the reaction section,
CO degas is a measurement of the molar flow rate of carbon monoxide leaving the degassing means,
H 2 inlet is a measurement of the molar flow rate of hydrogen entering the reaction section,
H 2 degas is a measurement of the molar flow rate of carbon monoxide leaving the degassing means,
2) if the theoretical ratio P H20 :P H2 determined in step 1) has a value of R threshold or higher, the temperature in the degassing means of the external loop for separating waxes is reduced,
3) steps 1) and 2) are repeated until the theoretical ratio P H20 :P H2 has a value strictly less than R threshold ,
where R threshold is a value in the range 0.1 to 1.1.

2. The process according to claim 1 , in which R threshold is equal to 1.1.

3. The process according to claim 1 , in which R threshold is equal to 0.9.

4. The process according to claim 1 , in which R threshold is equal to 0.7.

5. The process according to claim 1 , in which step 2) is carried out by reducing the temperature in said degassing means such that the difference in temperature between the reaction section and the degassing mean is in the range of 0° C. to +30° C.

6. The process according to claim 5 , in which the difference in temperature between the reaction section and said degassing means is in the range of +4° C. to +15° C.

7. The process according to claim 1 , in which the reduction in the temperature of step 2) is performed by a heat exchanger.

8. A process for the synthesis of hydrocarbons from a feed comprising synthesis gas, in which a solid catalyst comprising cobalt is present in a three-phase reaction section operated such that said catalyst is maintained in suspension in a liquid phase by movement of a gas phase from the bottom to the top of said reaction section, said process comprising separating waxes in an external loop having a degassing drum, wherein
1) a theoretical ratio P H20 :P H2 in the external loop for separating waxes is determined by the following calculation:
P H2O :P H2 theoretical= Cv /( R 1− Rft×Cv )

where Cv=(CO inlet −CO degas )/CO inlet
R1=H 2 inlet /CO inlet
Rft=(H 2 inlet −H 2 degas )/(CO inlet −CO degas )

wherein
CO inlet is a measurement of the molar flow rate of carbon monoxide entering the reaction section,
CO degas is a measurement of the molar flow rate of carbon monoxide leaving the degassing drum,
H 2 inlet is a measurement of the molar flow rate of hydrogen entering the reaction section,
H 2 degas is a measurement of the molar flow rate of carbon monoxide leaving the degassing drum,
2) if the theoretical ratio P H20 :P H2 determined in step 1) has a value of R threshold or higher, the temperature in the degassing drum of the external loop for separating waxes is reduced,
3) steps 1) and 2) are repeated until the theoretical ratio P H20 :P H2 has a value strictly less than R threshold ,
where R threshold is a value in the range 0.1 to 1.1.

9. The process according to claim 8 , in which R threshold is equal to 1.1.

10. The process according to claim 8 , in which R threshold is equal to 0.9.

11. The process according to claim 8 , in which R threshold is equal to 0.7.

12. The process according to claim 8 , in which step 2) is carried out by reducing the temperature in said degassing drum such that the difference in temperature between the reaction section and the degassing drum is in the range of 0° C. to +30° C.

13. The process according to claim 12 , in which the difference in temperature between the reaction section and said degassing drum is in the range of +4° C. to +15° C.

14. The process according to claim 8 , in which the reduction in the temperature of step 2) is performed by a heat exchanger.

Assignees

• IFP Energies Nouvelles
• Eni Spa

Inventors

• Heraud Jean Philippe
• Viguie Jean Christophe
• Boucher Sebastien
• Della Torre Chiara
• Mignone Elsa

Classifications

• B01J2219/00202

  at the reactor outlet · CPC title

• B01J2219/00213

  Fixed parameter value · CPC title

• B01D21/02

  Settling tanks {with single outlets for the separated liquid} · CPC title

• B01J2208/003

  involving reactant slurries · CPC title

• B01J8/228 Primary

  externally, i.e. the particles leaving the vessel and subsequently re-entering it · CPC title