Method for preparing flexible polyurethane foam with hydrolysable silane compounds

Patent metadata

Field	Value
Publication number	US-9290605-B2
Application number	US-201214236615-A
Country	US
Kind code	B2
Filing date	Aug 16, 2012
Priority date	Aug 31, 2011
Publication date	Mar 22, 2016
Grant date	Mar 22, 2016

Abstract

Flexible polyurethane foams are made using certain hydrolysable silane compounds in the foam formulation. The hydrolysable silane compounds contain at least one isocyanate-reactive group and at least one hydrolysable silane group. The presence of the hydrolysable silane compound in the foam formulation leads to improved tensile, tear and elongation properties without an adverse effect on other important foam properties such as resiliency and hysteresis loss.

First claim

What is claimed is:

1. A process for making a flexible polyurethane foam comprising curing in one or more steps ingredients that include:
a) one or more isocyanate-reactive compounds that contain an average of at least 2 isocyanate-reactive groups per molecule, contain no hydrolysable silane groups and have an equivalent weight per isocyanate-reactive group of at least 200;
b) from 1 to 100 parts by weight, per 100 parts by weight of component a), of a polyether monol or polyol having one hydrolysable silane group per molecule and a molecular weight of from 500 to 5000;
c) a blowing agent that includes water; and
d) at least one organic polyisocyanate compound,
wherein 1) some or all of component a), component b) or both can be pre-reacted with the organic polyisocyanate compound(s) to form an isocyanate terminated prepolymer or quasi-prepolymer; and 2) the isocyanate index is from 70 to 150.

2. The process of claim 1 wherein component b) is a polyether monol.

3. The process of claim 1 wherein water is the sole blowing agent.

4. The process of claim 3 wherein the ingredients include from 2 to 3.5 parts by weight of water per 100 parts by weight of component a).

5. The process of claim 1 wherein the ingredients include from 5 to 100 parts by weight of component b) per 100 parts by weight component a).

6. The process of claim 1 wherein the ingredients include at least one catalyst for the reaction of water or an alcohol with an isocyanate group and at least one catalyst for the reaction of a hydrolysable silane group with water or a silanol.

7. The process of claim 6 wherein the ingredients include no more than 2 parts by weight of a crosslinker per 100 parts by weight of component a) and no more than 3 parts by weight of a chain extender per 100 parts by weight of component a).

8. A process for making a flexible polyurethane foam comprising curing ingredients that include:
a) one or more isocyanate-reactive compounds that contain an average of at least 2 isocyanate-reactive groups per molecule, contain no hydrolysable silane groups and have an equivalent weight per isocyanate-reactive group of at least 200;
b) from 1 to 100 parts by weight, per 100 parts by weight of component a), of a polyether monol or polyol having at least one hydrolysable silane group per molecule and a molecular weight of from 500 to 5000;
c) a blowing agent that includes water; and
d) at least one organic polyisocyanate compound, wherein all or a portion of component b) is pre-reacted with the polyisocyanate (component d)) in the absence of water, to form an isocyanate-terminated prepolymer or quasi-prepolymer, and the prepolymer or quasi-prepolymer is then further cured by reaction with a mixture of water and component a) or a mixture of water and component a) and (1) any remaining portion of b), (2) a crosslinker and/or chain extender, or both (1) and (2) at an isocyanate index of from 70 to 150 to produce the foam.

9. The process of claim 1 , wherein the organic polyisocyanate is prereacted with a chain extender or crosslinker to form a prepolymer or quasi-prepolymer which is then reacted with components a) and b) in the presence of component c) to form the foam.

10. A process for making a flexible polyurethane foam comprising curing ingredients that include:
a) one or more isocyanate-reactive compounds that contain an average of at least 2 isocyanate-reactive groups per molecule, contain no hydrolysable silane groups and have an equivalent weight per isocyanate-reactive group of at least 200;
b) from 1 to 100 parts by weight, per 100 parts by weight of component a), of a polyether monol or polyol having at least one hydrolysable silane group per molecule and a molecular weight of from 500 to 5000;
c) a blowing agent that includes water; and
d) at least one organic polyisocyanate compound, wherein the ingredients are reacted in a one step reaction at an isocyanate index of from 70 to 150 to produce the foam.

11. A flexible polyurethane foam made in accordance with claim 1 .

Assignees

• Walia Parvinder S
• Obi Bernard E
• Minnikanti Venkat S
• Koonce William A
• Vyakaranam Kamesh R
• Zhang Ling
• Fregni Sabrina
• Dow Global Technologies Llc

Inventors

• Walia Parvinder S
• Obi Bernard E
• Minnikanti Venkat S
• Koonce William A
• Vyakaranam Kamesh R
• Zhang Ling
• Fregni Sabrina

Classifications

• C08G18/4841

  containing oxyethylene end groups · CPC title

• C08G18/1833

  having ether, acetal, or orthoester groups · CPC title

• C08G18/3275

  containing two hydroxy groups · CPC title

• C08G18/289 Primary

  containing silicon · CPC title

• C08G18/1841

  having carbonyl groups which may be linked to one or more nitrogen or oxygen atoms · CPC title