Topical protective polymerized nanoparticles in an active or bioactive array, methods for preparing same and uses thereof
US-2015374610-A1 · Dec 31, 2015 · US
US9290585B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9290585-B2 |
| Application number | US-201314370911-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 1, 2013 |
| Priority date | Aug 1, 2013 |
| Publication date | Mar 22, 2016 |
| Grant date | Mar 22, 2016 |
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Disclosed are a modified conjugated diene polymer and a method for preparing the same. Provided are advantageously a modified conjugated diene polymer and a method for preparing the same which provide superior compatibility with an inorganic filler, heat generation, tensile strength and abrasion resistance, low fuel consumption and excellent resistance on wet roads.
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What is claimed is: 1. A method for preparing a modified conjugated diene polymer comprising: (a) polymerizing a conjugated diene monomer, or a conjugated diene monomer and an aromatic vinyl monomer in the presence of a solvent using an organometallic compound to prepare an active polymer having a metal end group; and (b) adding a compound represented by the following Formula 2 to the active polymer to modify the active polymer: wherein R 1 is an alkyl group or an alkylsilyl group, R 2 and R 3 are an alkyl group, a is an integer of 1 to 3, and n is an integer of 0 to 2, wherein two R 1 bonded to nitrogen are identical or different when n is 2, and corresponding groups are identical or different when 3-n is 2 or more. 2. The method according to claim 1 , wherein the organometallic compound is used in an amount of 0.01 to 10 mmol, based on 100 g in total of the monomer. 3. The method according to claim 1 , wherein a molar ratio of the organometallic compound to the compound represented by Formula 2 is 1:0.1 to 1:10. 4. The method according to claim 1 , wherein the polymerization (a) further comprises adding a polar additive. 5. The method according to claim 4 , wherein the polar additive is added in an amount of 0.001 to 10 g, based on 1 mmol in total of the organometallic compound.
Silicon-containing compounds {(C08K5/0091 takes precedence)} · CPC title
Silica · CPC title
Compositions of rubber derivatives (C08L11/00, C08L13/00 take precedence) · CPC title
Carbon · CPC title
Introducing metal atoms or metal-containing groups · CPC title
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