Method for decomposing organic compound contained in aqueous solution

Patent metadata

Field	Value
Publication number	US-9290394-B2
Application number	US-201314038690-A
Country	US
Kind code	B2
Filing date	Sep 26, 2013
Priority date	Jan 26, 2012
Publication date	Mar 22, 2016
Grant date	Mar 22, 2016

Abstract

Provided is a method for decomposing at least one of organic compound contained in an aqueous solution by using a titanium dioxide photocatalyst that is excellent in both photocatalytic activity and solid-liquid separation performance for water treatment. The method includes: a step of adding catalyst particles into the aqueous solution; a step of decomposing the organic compound by irradiating the aqueous solution with light having a wavelength of 200 nanometers or more and 400 nanometers or less while stirring the catalyst particles in the aqueous solution; and a step of stopping the stirring, and separating the catalyst particles from the aqueous solution by sedimentation. The catalyst particles are composed only of titanium dioxide particles and zeolite particles, the titanium dioxide particles are adsorbed on outer surfaces of the zeolite particles, the zeolite particles have a silica/alumina molar ratio of 10 or more, and the catalyst particles are contained in the aqueous solution at a concentration of 0.4 grams/liter or more and 16 grams/liter or less.

First claim

What is claimed is:

1. A method for decomposing at least one of organic compound contained in an aqueous solution, comprising:
a step a of adding catalyst particles into the aqueous solution;
a step b of decomposing the organic compound by irradiating the aqueous solution with light having a wavelength of 200 nanometers or more and 400 nanometers or less while stirring the catalyst particles in the aqueous solution; and
a step c of stopping the stirring in the step b, and separating the catalyst particles from the aqueous solution by sedimentation,
wherein the catalyst particles are composed only of titanium dioxide particles and zeolite particles, the titanium dioxide particles are adsorbed on outer surfaces of the zeolite particles, the zeolite particles have a silica/alumina molar ratio of 10 or more, and the catalyst particles are contained in the aqueous solution at a concentration of 0.4 grams/liter or more and 16 grams/liter or less.

2. The method according to claim 1 , comprising a step d of adding again the catalyst particles separated by sedimentation in the step c into the aqueous solution after the step c,
wherein the step b and the step c are performed again after the step d.

3. The method according to claim 1 ,
wherein the catalyst particles are separated by sedimentation in a solid-liquid separation vessel having a filtration membrane in the step c,
the method further comprises a step e of producing treated water from the aqueous solution using the filtration membrane, and
in the step e, the filtration membrane is a filtration membrane obtained by adhering a filter paper made of a resin to each of both sides of a plate-like frame, and the filtration membrane is arranged parallel to a direction in which the catalyst particles sediment.

4. The method according to claim 3 , comprising a step f of adding again the catalyst particles separated by sedimentation in the step c into the aqueous solution after the step c,
wherein the step b, the step c and the step e are performed again after the step f.

5. The method according to claim 1 , wherein the zeolite particles are zeolite particles treated with an acid aqueous solution to dissolve alumina portions thereof to introduce active sites for adsorbing the titanium dioxide particles directly on the zeolite particles, and then washed with water to remove the acid aqueous solution adhered to surfaces of the zeolite particles.

Assignees

• Panasonic Corp
• Panasonic Ip Man Co Ltd

Inventors

• Maruo Yuko
• Ino Daisuke

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J29/00

  Catalysts comprising molecular sieves {(molecular sieves per se C01B)} · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• C02F1/32 Primary

  with ultraviolet light · CPC title