Lithium secondary battery positive electrode material for improving output characteristics and lithium secondary battery including the same

Patent metadata

Field	Value
Publication number	US-9287564-B2
Application number	US-201213566360-A
Country	US
Kind code	B2
Filing date	Aug 3, 2012
Priority date	Apr 4, 2011
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

Provided are a positive electrode active material for improving an output and a lithium secondary battery including the same. Particularly, graphite and conductive carbon which have shapes and sizes different from each other, may be simultaneously coated on a mixed positive electrode material of a 3-component system lithium-containing metal oxide having a layered structure and expressed as following Chemical Formula 1 and LiFePO 4 having an olivine structure as an conductive material to improve high resistance occurrence and conductivity reduction phenomenon of a 3-component system lithium metal oxide due to a difference between particle sizes and surface areas of the 3-component system lithium-containing metal oxide and LiFePO 4 olivine.

Li 1+a Ni x Co y Mn 1-x-y O 2 , 0≦ a <0.5, 0< x <1, 0< y <0.5  [Chemical formula 1]

First claim

What is claimed is:

1. A lithium secondary battery positive electrode material consisting essentially of:
a mixed positive electrode active material comprising a 3-component system lithium-containing metal oxide having a layered structure expressed as following Chemical Formula 1 and a metal oxide having an olivine structure expressed as following Chemical Formula 2; and
two conductive materials having particle shapes and sizes different from each other:
Li 1+a Ni x Co y Mn 1-x-y O 2 , 0≦ a< 0.5, 0< x< 1, 0< y< 0.5  Chemical Formula 1

A x M y M′ z XO 4   Chemical Formula 2

where, A is at least one selected from alkali metals, M and M′ are at least one selected from transition metal elements, X is any one selected from the group consisting of P, Si, S, As, Sb, and combinations thereof, and x+y+z=2,
wherein the metal oxide having the olivine structure, which is expressed as Chemical Formula 2, is contained in a ratio of about 10 wt % to about 40 wt % with respect to the 3-component system lithium-containing metal oxide, which is expressed as Chemical Formula 1, on the basis of the total weight of the mixed positive electrode active material, and
wherein the two conductive materials having the particle shapes and sizes different from each other are graphite and acetylene black,
wherein the two conductive materials having the particle shapes and sizes different from each other, which are formed of graphite and acetylene black, have a content of about 0.5 wt % to about 15 wt % with respect to the total weight of the lithium secondary battery positive electrode material,
wherein the acetylene black has a content of about 3 wt % to about 10 wt % with respect to the total weight of the lithium secondary battery positive electrode material,
wherein a content ratio of acetylene black to graphite is 2:1, and
wherein a particle size of the 3-component system lithium-containing metal oxide of the Chemical Formula 1 is larger than that of the metal oxide of the Chemical Formula 2, so that a surface area of the 3-component system lithium-containing metal oxide of the Chemical formula 1 is 0.3 to 1 m 2 /g and a surface area of the metal oxide of the Chemical Formula 2 is 10 to 40 m 2 /g.

2. The lithium secondary battery positive electrode material of claim 1 , wherein the mixed positive electrode active material further comprises at least one lithium-containing metal oxide selected from the group consisting of lithium manganese spinel and an oxide in which other elements(s) is(are) replaced or doped with/into the lithium manganese spinel.

3. The lithium secondary battery positive electrode material of claim 2 , wherein the other element(s) is(are) any one element or two or more elements selected from the group consisting of Al, Mg, Mn, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, and Bi.

4. The lithium secondary battery positive electrode material of claim 2 , wherein the lithium-containing metal oxide is contained in about 50 wt % or less on the basis of the total weight of the mixed positive electrode active material.

5. A positive electrode for secondary battery comprising the lithium secondary battery positive electrode material according to claim 1 .

6. A lithium secondary battery comprising the positive electrode for secondary battery according to claim 5 .

7. The lithium secondary battery of claim 6 , wherein the lithium secondary battery is used as a unit battery of a battery module that is a power source for a device,
wherein the device comprises: a power tool; a vehicle selected from the group consisting of an electric vehicle (EV), a hybrid electric vehicle (HEV), and a plug-in hybrid electric vehicle (PHEV); an electric two-wheeled vehicle including an E-bike and an E-scooter; an electric golf cart; an electric truck; or an electric commercial vehicle or a power storage system.

8. The lithium secondary battery positive electrode material of claim 1 , wherein the lithium-containing metal oxide expressed by Chemical Formula 1 is Li[Ni 1/3 Mn 1/3 Co 1/3 ]O 2 , and wherein the metal oxide expressed by Chemical Formula 2 is LiFePO 4 .

Assignees

• Oh Song Taek
• Chang Sung Kyun
• Park Sin Young
• Hwang Sun Jung
• Lim Jin Hyung
• Chung Geun Chang
• Kim Sin Kyu
• Choi Jung Seok
• An Keunwan
• Lg Chemical Ltd

Inventors

• Oh Song Taek
• Chang Sung Kyun
• Park Sin Young
• Hwang Sun Jung
• Lim Jin Hyung
• Chung Geun Chang
• Kim Sin Kyu
• Choi Jung Seok
• An Keunwan

Classifications

• H01M4/5825 Primary

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• C01G45/1228

  of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2 · CPC title

• Y10S903/907

  Electricity storage, e.g. battery, capacitor · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• C01P2004/80

  Particles consisting of a mixture of two or more inorganic phases · CPC title