Graphene gas sensor for measuring the concentration of carbon dioxide in gas environments
US-2015377824-A1 · Dec 31, 2015 · US
US9285332B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9285332-B2 |
| Application number | US-201414250821-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 11, 2014 |
| Priority date | Dec 12, 2011 |
| Publication date | Mar 15, 2016 |
| Grant date | Mar 15, 2016 |
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The present disclosure provides a gas sensor including: a substrate; an electrode formed on the substrate; and a gas-sensing layer formed on the electrode, wherein the gas-sensing layer is a self-heating nanocolumnar structure having nanocolumns formed on the electrode and inclined with respect to the electrode with an angle of 60-89° and gas diffusion pores formed between the nanocolumns. The gas sensor according to the present disclosure requires no additional heater since it self-heats owing to the nanocolumnar structure and exhibits superior gas sensitivity even when no heat is applied from outside. Also, it can be mounted on mobile devices such as mobile phones because it consumes less power.
Opening claim text (preview).
What is claimed is: 1. A gas sensor comprising: a substrate; an electrode formed on the substrate; and a gas-sensing layer formed on the electrode, wherein the gas-sensing layer is a self-heating nanocolumnar structure having nanocolumns formed on the electrode and inclined with respect to the electrode with an angle of 60-89° and gas diffusion pores formed between the nanocolumns. 2. The gas sensor according to claim 1 , wherein the nanocolumns are arranged on an x-y plane on the electrode such that the gas diffusion pores are formed between the nanocolumns arranged in one of the x and y directions and the nanocolumns arranged in the other direction are connected with each other. 3. The gas sensor according to claim 1 , wherein the nanocolumns are formed by glancing angle deposition and the gas diffusion pores are formed in the self-shadowed region between the nanocolumns. 4. The gas sensor according to claim 1 , wherein the gas-sensing layer comprises a metal oxide having a band gap of at least 2.7 eV. 5. The gas sensor according to claim 1 , wherein the gas-sensing layer comprises at least one metal oxide selected from tungsten oxide (WO 3 ), tin oxide (SnO 2 ), niobium oxide (Nb 2 O 5 ), zinc oxide (ZnO), indium oxide (In 2 O 3 ), iron oxide (Fe 2 O 3 ), titanium oxide (TiO 2 ), cobalt oxide (Co 2 O 3 ) and gallium oxide (Ga 2 O 3 ). 6. The gas sensor according to claim 1 , wherein the substrate is a glass, sapphire, quartz or MgO substrate. 7. The gas sensor according to claim 1 , wherein the electrode is a metal film, a metal oxide film or a carbon film. 8. The gas sensor according to claim 7 , wherein the electrode is a metal film and the metal film comprises at least one selected from copper (Cu), gold (Au), silver (Ag) and platinum (Pt). 9. The gas sensor according to claim 7 , wherein the electrode is a metal oxide film and the metal oxide film is an oxide film comprising at least one metal selected from indium (In), tin (Sn), zinc (Zn), aluminum (AD, niobium (Nb), titanium (Ti) and gallium (Ga). 10. The gas sensor according to claim 7 , wherein the electrode is a metal oxide film and the metal oxide film is an oxide film selected from indium-doped tin oxide (ITO), fluorine-doped tin oxide (FTC)), aluminum-doped zinc oxide (AZO), gallium-doped zinc oxide (GZO), indium-doped zinc oxide (IZO) and niobium-doped titanium oxide (NTO). 11. The gas sensor according to claim 7 , wherein the electrode is a carbon film and the carbon film comprises graphene. 12. The gas sensor according to claim 1 , wherein the electrode is a metal oxide film or a carbon film and the gas sensor has a light transmittance of at least 90% in the visible region.
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