Method for determining properties of superabsorbent polymer particles and of absorbent structures containing such particles

Patent metadata

Field	Value
Publication number	US-9285302-B2
Application number	US-201213524014-A
Country	US
Kind code	B2
Filing date	Jun 15, 2012
Priority date	Jun 17, 2011
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

A method for determining the time dependent effective permeability and the uptake kinetics of hydrogel-forming superabsorbent polymer particles under pressure.

First claim

What is claimed is:

1. A method for determining the time dependent effective permeability and the uptake kinetics under pressure of superabsorbent polymer particles or an absorbent structure comprising superabsorbent polymer particles, the method comprising the steps of:
a. providing dry, non-preswollen, non pre-wetted superabsorbent polymer particles on a screen to form a layer on the screen, wherein the bottom of the screen has pores, the pores having a dimension to allow liquid to pass through and to hinder the superabsorbent polymer particles from passing through;
b. applying a weight onto the surface of the superabsorbent polymer particles layer;
c. introducing a flow of hydrophilic liquid onto the surface of the superabsorbent polymer particles layer; and
d. measuring and recording the weight of liquid passing through the superabsorbent polymer particles layer and the caliper of the superabsorbent polymer particles layer.

2. The method according to claim 1 , wherein the weight applies a predetermined, constant and even pressure on the surface of the superabsorbent polymer particles layer or the surface of the absorbent structure.

3. The method according to claim 2 , wherein the pressure applied on the surface of the superabsorbent polymer particles layer or on the surface of the absorbent structure is 0.2 psi to 0.4 psi.

4. The method according to claim 1 , wherein the screen is attached to the bottom of a cylinder.

5. The method according to claim 1 , wherein the superabsorbent polymer particles are evenly dispersed on the screen to form a homogeneous layer.

6. The method according to claim 1 , wherein the hydrophilic liquid is a salt solution and is aqueous 0.9% by weight sodium chloride solution.

7. The method according to claim 6 , wherein the solution comprises 0.01% by weight of a non-ionic surfactant.

8. The method according to claim 7 , wherein the non-ionic surfactant is a linear C 12 -C 14 alcohol ethoxylate.

9. The method according to claim 1 , wherein the amount of the superabsorbent polymer particles provided on the screen or contained in the absorbent structure is predetermined and is about 2.0 g.

10. The method according to claim 1 , wherein the liquid is maintained at a constant level in the cylinder at about 5.0 cm.

11. The method according to claim 10 , wherein a reservoir is used to deliver the hydrophilic liquid to the cylinder and a digital fiber sensor connected to a controlled valve are used to temporarily block the flux of liquid flowing from the reservoir to the cylinder in order to maintain constant the level of hydrophilic liquid in the cylinder.

12. The method according to claim 1 , wherein weight is applied onto the surface of the superabsorbent polymer particles layer or the surface of the absorbent structure by using a piston, the piston comprising a piston body, a piston head and a piston guiding lid, the piston head being positioned onto the surface of the superabsorbent polymer particles layer or the surface of the absorbent structure.

13. The method according to claim 12 , wherein the caliper of the superabsorbent polymer particles layer or of the absorbent structure is measured by a digital laser sensor which is pointed at the top of the piston body.

14. The method according to claim 13 , wherein the piston guiding lid comprises an inlet, and wherein the hydrophilic liquid is introduced in the cylinder via the outlet of a liquid tube connected to the reservoir, the liquid tube being inserted into the cylinder via the inlet of the piston guiding lid.

15. The method according to claim 1 , wherein the amount of hydrophilic liquid passing through the superabsorbent polymer particles layer or the absorbent structure and the caliper of the superabsorbent polymer particles layer or the absorbent structure are recorded for a period of at least 21 minutes.

16. A method for determining the time dependent effective permeability and the uptake kinetics under pressure of an absorbent structure comprising superabsorbent polymer particles, the method comprising the steps of:
a. providing an absorbent structure comprising dry, non-preswollen, non pre-wetted superabsorbent polymer particles on a screen, wherein the bottom of the screen has pores, the pores having a dimension to allow liquid to pass through and to hinder the superabsorbent polymer particles from passing through;
b. applying a weight onto the surface of the absorbent structure;
c. introducing a flow of hydrophilic liquid onto the surface of the absorbent structure; and
d. measuring and recording the weight of liquid passing through the absorbent structure and the caliper of the absorbent structure.

17. The method according to claim 16 , wherein the weight applies a predetermined, constant and even pressure on the surface of the absorbent structure.

18. The method according to claim 17 , wherein the pressure applied on the surface of the absorbent structure is 0.2 psi to 0.4 psi.

19. The method according to claim 16 , wherein the screen is attached to the bottom of a cylinder.

20. The method according to claim 16 , wherein the amount of superabsorbent polymer particles contained in the absorbent structure is predetermined and is 2.0 g.

Assignees

• Ehrnsperger Bruno Johannes
• Jennewein Marc
• Michnacs Marion
• Peri Andrea
• Thomann Maike
• Procter & Gamble

Inventors

• Ehrnsperger Bruno Johannes
• Jennewein Marc
• Michnacs Marion
• Peri Andrea
• Thomann Maike

Classifications

• G01N15/0826 Primary

  and measuring fluid flow rate, i.e. permeation rate or pressure change · CPC title