Thermal methods for treating a metathesis feedstock

Patent metadata

Field	Value
Publication number	US-9284515-B2
Application number	US-201414182527-A
Country	US
Kind code	B2
Filing date	Feb 18, 2014
Priority date	Aug 9, 2007
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

Various methods are provided for metathesizing a feedstock. In one aspect, a method includes providing a feedstock comprising a natural oil, heating the feedstock to a temperature greater than 100° C. in the absence of oxygen, holding the feedstock at the temperature for a time sufficient to diminish catalyst poisons in the feedstock, and, following the heating and holding, combining a metathesis catalyst with the feedstock under conditions sufficient to metathesize the feedstock.

First claim

What is claimed is:

1. A method of metathesizing a feedstock, comprising:
providing a feedstock comprising a natural oil;
treating the feedstock; and
introducing a metathesis catalyst to the treated feedstock under conditions sufficient to metathesize the natural oil;
wherein the treating comprises heating the feedstock to a temperature greater than 100° C. and holding the temperature of the feedstock at a temperature greater than 100° C. for a period of time so as to reduce the concentration of peroxides in the feedstock.

2. The method of claim 1 , wherein the treating comprises heating the feedstock to a temperature greater than 100° C. but no more than 300° C.

3. The method of claim 1 , wherein the treating comprises, after the heating, cooling the feedstock to a temperature below 80° C.

4. The method of claim 1 , wherein the treating comprises, after the heating, cooling the feedstock to a temperature below 60° C.

5. The method of claim 1 , wherein the treating comprising contacting the feedstock with an adsorbent material.

6. The method of claim 5 , wherein the absorbent material comprises a molecular sieve, activated carbon, a zeolite, silica gel, Fuller's earth, neutral alumina, basic alumina, diatomaceous earth, acid-activated clay, aluminum sulfate, calcium carbonate, Kaolin, magnesium sulfate, potassium chloride, potassium magnesium sulfate, potassium sulfate, soda ash, sodium carbonate, sodium sulfate, or magnesium silicate.

7. The method of claim 6 , wherein the adsorbent material comprises magnesium silicate.

8. The method of claim 1 , wherein the metathesis catalyst is a carbene complex of ruthenium, molybdenum, osmium, chromium, rhenium, or tungsten.

9. The method of claim 1 , wherein the metathesis catalyst is a carbene complex of ruthenium or osmium.

10. The method of claim 1 , wherein the treating comprises partially hydrogenating the natural oil or natural oil derivative.

11. The method of claim 1 , wherein the natural oil is a vegetable oil, an algae oil, an animal oil, a tall oil, a natural oil derivative, or any combinations thereof.

12. The method of claim 11 , wherein the vegetable oil is canola oil, rapeseed oil, coconut oil, corn oil, cottonseed oil, olive oil, palm oil, peanut oil, safflower oil, sesame oil, sunflower oil, linseed oil, palm kernel oil, tung oil, jatropha oil, or any combinations thereof.

13. The method of claim 11 , wherein the natural oil derivative is a fatty acid alkyl ester.

14. The method of claim 13 , wherein the fatty acid is oleic acid, linoleic acid, or linolenic acid.

15. The method of claim 13 , wherein the fatty acid is oleic acid.

16. The method of claim 11 , wherein the natural oil derivative is a fatty acid methyl ester.

17. The method of claim 16 , wherein the fatty acid is oleic acid, linoleic acid, or linolenic acid.

18. The method of claim 16 , wherein the fatty acid is oleic acid.

Assignees

• Elevance Renewable Sciences

Inventors

• Uptain Kevin D
• Tanger Charles
• Kaido Hiroki

Classifications

• C11C3/14

  by isomerisation {(isomerisation induced by hydrogenation C11C3/12)} · CPC title

• C11C3/00 Primary

  Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom (sulfonated fats or oils C07C309/62; factice C08H; drying oils C09F) · CPC title