Blends of polyarylene ethers and polyarylene sulfides
US-9212281-B2 · Dec 15, 2015 · US
US9284452B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9284452-B2 |
| Application number | US-200913125675-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 22, 2009 |
| Priority date | Oct 24, 2008 |
| Publication date | Mar 15, 2016 |
| Grant date | Mar 15, 2016 |
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To provide a connection structure for a photovoltaic power generation module which is excellent in long-term heat resistance and which is excellent in low-temperature impact resistance even if the structure is reduced in wall thickness and size. There is provided a connection structure ( 1 ) for a photovoltaic power generation module which at least joins a photovoltaic power generation module to a cable for connecting to the photovoltaic power generation module, the connection structure for the photovoltaic power generation module comprising a thermoplastic resin composition having, as an index of long-term heat resistance, a relative thermal index (RTI) of tensile impact strength at a thickness of 1.5 mm of 115° C. or higher, and a Charpy impact strength at −40° C. of 6.5 kJ/m 2 or more.
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What is claimed is: 1. A junction box for a photovoltaic power generation module, which at least joins a photovoltaic power generation module to a cable for connecting to the photovoltaic power generation module, the connection structure for the photovoltaic power generation module comprising a thermoplastic resin composition having, as an index of long-term heat resistance, a relative thermal index (RTI) of tensile impact strength at a thickness of 1.5 mm of 115 degree C. or higher, and a Charpy impact strength at −40 degree C. of 6.5 kJ/m 2 or more and 15kJ/m 2 or less, wherein the thermoplastic resin composition comprises a (A) polyphenyiene ether, a (B) styrenic-based resin and a (C) hydrogenated block copolymer, and the junction box has an average wall thickness of 3mm or less. 2. The junction box for a photovoltaic power generation module according to claim 1 , wherein the thermoplastic resin composition comprises a (A) polyphenylene ether, a (B) styrenic-based resin, and a (C) hydrogenated block copolymer, and based on 100 parts by mass of a total of the (A), the (B), and the (C), a content of the (A) is from 65 to 98 parts by mass; a content of the (B) is from 1 to 25 parts by mass; and a content of the (C) is from 1 to 20 parts by mass. 3. The junction box for a photovoltaic power generation module according to claim 1 or 2 , wherein the thermoplastic resin composition has a relative thermal index of 120 degree C. or higher. 4. The junction box for a photovoltaic power generation module according to claim 1 or 2 , wherein the thermoplastic resin composition has a Charpy impact strength at −40 degree C. of 7.5 kJ/m 2 or more. 5. The junction box for a photovoltaic power generation module according to claim 1 or 2 , wherein the thermoplastic resin composition has a Dart impact strength at −40 degree C. of 3.0 J or more. 6. The junction box for a photovoltaic power generation module according to claim 1 or 2 , wherein the thermoplastic resin composition has a retention of 70% or more, wherein the retention is defined as a ratio, in percentage, of the Dart impact strength at −40 degree C. after being left standing in a 90 degree C./saturated water vapor environment for 500 hours to the Dart impact strength at −40 degree C. before the standing. 7. The junction box for a photovoltaic power generation module according to claim 1 , wherein the junction box has an average wall thickness of 1 mm or more and 2.5 mm or less. 8. The junction box for a photovoltaic power generation module according to claim 1 or 2 , wherein the junction box for a photovoltaic power generation module comprises a male connector and a female connector. 9. The junction box for a photovoltaic power generation module according to claim 8 , wherein the junction box has an average wall thickness of 0.5 mm or more and 2.5 mm or less. 10. The junction box for a photovoltaic power generation module according to claim 1 , wherein the thermoplastic resin composition comprises at least one member selected from the group consisting of polyphenylene ether, polycarbonate, a polymer alloy containing polycarbonate and ABS, polybutylene terephthalate, polyethylene terephthalate, and polyphenylene sulfide. 11. The junction box for a photovoltaic power generation module according to claim 1 , wherein the thermoplastic resin composition comprises at least one member selected from the group consisting of polyphenylene ether, polycarbonate, and polyphenylene sulfide.
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