Antistatic liquid crystalline polymer composition

Patent metadata

Field	Value
Publication number	US-9284435-B2
Application number	US-201314052789-A
Country	US
Kind code	B2
Filing date	Oct 14, 2013
Priority date	Oct 16, 2012
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

A liquid crystalline polymer composition having a reduced tendency to create a static electric charge during a molding operation is provided. More particularly, the composition contains an ionic liquid that is distributed within a liquid crystalline polymer matrix. In addition to being electrically conductive, the ionic liquid can exist in liquid form during melt processing, which allows it to be more uniformly blended within the liquid crystalline polymer matrix. This improves electrical connectivity and thereby enhances the ability of the composition to rapidly dissipate static electric charges from its surface.

First claim

What is claimed is:

1. A polymer composition that comprises an ionic liquid that is distributed within a liquid crystalline polymer matrix, wherein the ionic liquid has a melting temperature of about 400° C. or less and is a salt that contains a cationic species and counterion, wherein the liquid crystalline polymer matrix is formed from a polymer that contains aromatic dicarboxylic acid repeating units, aromatic hydroxycarboxylic acid repeating units, aromatic diol repeating units, aromatic amide units, aromatic amine units, or a combination thereof.

2. The polymer composition of claim 1 , wherein ionic liquids constitute from about 0.1 wt. % to about 10 wt. % of the composition.

3. The polymer composition of claim 1 , wherein liquid crystalline polymers constitute from about 25 wt. % to about 95 wt. % of the composition.

4. The polymer composition of claim 1 , wherein the cationic species is a quaternary onium.

5. The polymer composition of claim 4 , wherein the quaternary onium is an ammonium compound having the structure N + R 1 R 2 R 3 R 4 , wherein R 1 , R 2 , and/or R 3 are independently a C 1 -C 6 alkyl and R 4 is hydrogen or a C 1 -C 4 alkyl group.

6. The polymer composition of claim 5 , wherein the ammonium compound is tri-butylmethylammonium.

7. The polymer composition of claim 1 , wherein the counterion is a halogen, sulfate, sulfonate, sulfosuccinate, amide, imide, borate, phosphate, phosphinate, antimonate, aluminate, fatty acid carboxylate, cyanate, acetate, or a combination thereof.

8. The polymer composition of claim 7 , wherein the imide is bis(pentafluoroethylsulfonyl)imide, bis(trifluoromethylsulfonyl)imide, or bis(tri-fluoromethyl)imide.

9. The polymer composition of claim 1 , further comprising carbon fibers, graphite, carbon black, or a combination thereof.

10. The polymer composition of claim 1 , further comprising mineral fibers.

11. The polymer composition of claim 10 , wherein the mineral fibers include wollastonite fibers.

12. The polymer composition of claim 10 , wherein the mineral fibers have a volume average length of from about 1 to about 200 micrometers and a nominal diameter of from about 1 to about 35 micrometers.

13. The polymer composition of claim 1 , further comprising a functional aromatic compound having the general structure (II)

or a metal salt thereof, wherein,
ring B is a 6-membered aromatic ring, wherein ring B may be optionally fused or linked to a 5- or 6-membered aryl, heteroaryl, cycloalkyl, or heterocyclyl;
R 4 is OH or COOH;
R 5 is acyl, acyloxy, acylamino, alkoxy, alkenyl, alkyl, amino, aryl, aryloxy, carboxyl, carboxyl ester, cycloalkyl, cycloalkyloxy, hydroxyl, halo, haloalkyl, heteroaryl, heteroaryloxy, heterocyclyl, or heterocycloxy;
m is from 0 to 4; and
n is from 1 to 3.

14. The polymer composition of claim 1 , further comprising a hydrate.

15. The polymer composition of claim 1 , wherein the composition has a melt viscosity of from about 0.1 to about 80 Pa-s, as determined in accordance with ISO Test No. 11443 at a shear rate of 1000 seconds −1 and temperature that is 15° C. above the melting temperature of the composition.

16. A molded part that comprises a polymer composition, wherein the polymer composition comprises an ionic liquid distributed within a liquid crystalline polymer matrix, and wherein the part exhibits a surface resistivity of about 1×10 15 ohms or less as determined in accordance with IEC 60093.

17. The molded part of claim 16 , wherein the part exhibits a surface resistivity of from 1×10 11 to about 1×10 13 ohms and/or a volume resistivity of about 1×10 15 ohm-m or less as determined in accordance with IEC 60093.

18. A compact camera module that comprises a generally planar base on which is mounted a lens barrel, wherein the base, barrel, or both have a thickness of about 500 micrometers or less and are formed from a part that contains a polymer composition comprising a liquid crystalline polymer matrix, wherein the part exhibits a surface resistivity of about 1×10 15 ohms or less as determined in accordance with IEC 60093.

19. The compact camera module of claim 18 , wherein an ionic liquid is distributed within the liquid crystalline polymer matrix.

20. The polymer composition of claim 1 , wherein the aromatic dicarboxylic acid includes terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, or a combination thereof.

21. The polymer composition of claim 1 , wherein the aromatic hydroxycarboxylic acid includes 4-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, or a combination thereof.

22. The polymer composition of claim 1 , wherein the aromatic diol includes hydroquinone, 4,4′-biphenol, or a combination thereof.

23. The polymer composition of claim 1 , wherein the polymer contains repeating units derived from terephthalic acid, isophthalic acid, 4-hydroxybenzoic acid, and 4,4′-biphenol.

24. The polymer composition of claim 23 , wherein the polymer further contains repeating units derived from 6-hydroxy-2-naphthoic acid and acetaminophen.

25. The polymer composition of claim 1 , further comprising a sulfate.

26. The molded article of claim 16 , wherein the liquid crystalline polymer matrix is formed from a polymer that contains aromatic dicarboxylic acid repeating units, aromatic hydroxycarboxylic acid repeating units, aromatic diol repeating units, aromatic amide units, aromatic amine units, or a combination thereof.

27. The compact camera module of claim 18 , wherein the liquid crystalline polymer matrix is formed from a polymer that contains aromatic dicarboxylic acid repeating units, aromatic hydroxycarboxylic acid repeating units, aromatic diol repeating units, aromatic amide units, aromatic amine units, or a combination thereof.

Assignees

• Ticona Llc

Inventors

• Kim Young Shin

Classifications

• H04N23/55

  Optical parts specially adapted for electronic image sensors; Mounting thereof · CPC title

• C09K19/38 Primary

  Polymers · CPC title

• C08L67/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings · CPC title

• C08K5/43 Primary

  Compounds containing sulfur bound to nitrogen · CPC title

• C08K7/06

  Elements · CPC title