Method for recycling floor coverings

Patent metadata

Field	Value
Publication number	US-9284431-B2
Application number	US-201314377131-A
Country	US
Kind code	B2
Filing date	Jan 24, 2012
Priority date	Feb 14, 2012
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

The invention relates to a solvent-based separation method for the total material recycling of materials used in nonwoven, woven, and tufted wares into the individual material components thereof sorted by type. At least one of the materials contains a polyolefin wax. As a solvent and/or swelling agent, halogen-free, aliphatic hydrocarbons or aromatic hydrocarbons or a mixture of one or several of said solvents are used.

First claim

What is claimed is:

1. A method of recovering individual varietally pure component materials used combined with each other in tufteds, wovens and nonwovens comprising the step of selective dissolution, selective swelling or both, wherein at least one of the component materials contains a polyolefin wax and the solvent and/or the swellant used comprises halogen-free aliphatic hydrocarbons aromatic hydrocarbons or both.

2. The method as claimed in claim 1 wherein the polyolefin wax comprises homo- or copolymers manufactured from ethylene, propylene, higher α-olefins of 4 to 20 carbon atoms or a combination thereof by polymerizing in the presence of metallocene catalysts and wherein the polyolefin wax has a dropping or softening point, ring/ball, between 70 and 160° C. and a melt viscosity, as measured at a temperature of 170° C., of not more than 40,000 mPa·s.

3. The method as claimed in claim 1 , wherein the polyolefin wax has a weight-average molar mass M w between 1000 and 40,000 g/mol and a number-average molar mass M n between 500 and 25,000 g/mol.

4. The method as claimed in claim 1 , wherein the polyolefin wax is a homopolymer based on ethylene or propylene or a copolymer consisting of propylene and 0.1 to 30 wt % of ethylene 0.1 to 50 wt % of at least one branched or unbranched C 4 -C 20 α-olefin or a mixture thereof and wherein the polyolefin wax has a melt viscosity, as measured at 170° C., of not more than 30,000 mPa·s.

5. The method as claimed in claim 1 , wherein the polyolefin wax and its recyclate have a dropping or softening point (ring/ball) between 70° C. and 165° C. and the recyclate has a melt viscosity measured at 170° C. of not more than 30,000 mPa·s.

6. The method as claimed in claim 1 , wherein the polyolefin wax and its recyclate have a weight-average molar mass M w between 1000 and 40,000 g/mol and a number-average molar mass M n between 500 and 25,000 g/mol and an M w /M n <5.

7. The method as claimed in claim 1 , wherein the component materials used in combination with one another in tufteds, wovens and nonwovens respond to admixing with a swellant by at least one component undergoing swelling and forming a polymer gel as a first phase which contains not more than 80 wt % of swellant, a second phase is formed concurrently or after a temperature- or pressure-induced separation and comprises at least one other component material in a dissolved state, and optionally an insoluble contrary present neither in the first phase nor in the second phase is removed from the polymer gel by filtration or sedimentation.

8. The method as claimed in claim 1 , wherein component materials still containing solvent after having been separated off are desolventized and isolated by drying at temperatures in the range from 30 to 120° C., optionally in the presence of negative pressure.

9. The method as claimed in claim 1 , wherein the component materials used combined with one another in tufteds, wovens and nonwovens comprise one or more, polymers that are soluble in a certain organic solvent and not more than one insoluble component material.

10. The method as claimed in claim 1 , wherein the material for the filaments comprises natural fibers, wool, or manufactured fibers of LLDPE, LDPE, PP, polyester or polyamide and the material for the backing comprises polyethylene or polypropylene.

11. The method as claimed in claim 1 , wherein the material for the bonding comprises a polyolefin wax used as hot-melt adhesive and composed of amorphous poly-alpha-olefins (APAO), metallocene-based homo- and copolymers or a combination thereof.

12. The method as claimed in claim 1 , wherein the component materials optionally contain filler materials, wherein the filler material is calcium carbonate or auxiliary materials selected from the group consisting of flame retardants, antistats, waxes, resins, plasticizers, pigments and antioxidants.

13. The method as claimed in claim 1 , wherein the recovered, varietally pure component materials are reused in their respective previous function in tufteds, wovens and nonwovens.

14. The method as claimed in claim 1 , wherein the recovered, varietally pure component materials differ by not more than 20% in their tensile strength, their modulus of elasticity and their elongation at break, from the component materials in the original state.

15. The method as claimed in claim 4 , wherein the polyolefin was has a melt viscosity, as measured at 170° C. of not more than 20,000 mPa·s.

16. The method as claimed in claim 5 , wherein the recyclate has a melt viscosity measured at 170° C. of not more than 20,000 mPa·s.

17. The method as claimed in claim 6 , wherein the polyolefin wax and its recyclate have an M w /M n <2.5.

18. The method as claimed in claim 6 , wherein the polyolefin wax and its recyclate have an M w /M n <1.8.

19. The method as claimed in claim 1 , wherein the component materials used combined with one another in tufteds, wovens and nonwovens comprise two or more polymers that are soluble in a certain organic solvent and not more than one insoluble component material.

20. The method as claimed in claim 1 , wherein the recovered, varietally pure component materials are reused in their respective previous function in synthetic turf.

Assignees

• Hohner Gerd
• Steib Christian
• Herrlich Timo
• Clariant Int Ltd

Inventors

• Hohner Gerd
• Steib Christian
• Herrlich Timo

Classifications

• Y02W30/62

  Plastics recycling; Rubber recycling · CPC title

• C08J2391/06

  Waxes · CPC title

• C08J2423/12

  Polypropene · CPC title

• C08J2423/02

  not modified by chemical after treatment · CPC title

• C08J2323/06

  Polyethene · CPC title