Bimodal resins having good film processability

Patent metadata

Field	Value
Publication number	US-9284389-B2
Application number	US-201414445793-A
Country	US
Kind code	B2
Filing date	Jul 29, 2014
Priority date	Jul 29, 2014
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

A bimodal polyethylene copolymer comprising a lower molecular weight (LMW) component and a higher molecular weight (HMW) component, the copolymer having a z-average molecular weight (M z ) of from about 1,000 kg/mol to about 2,500 kg/mol, a weight fraction of the LMW component (LMW fr.) of from about 0.60 to 0.85, a ratio of a weight average molecular weight (M w ) of the HMW component (HMW M w ) to a M w of the LMW component (LMW M w ) of from about 14 to about 25, a zero shear viscosity (η 0 ) of from about 5×10 5 Pa-s to about 1×10 7 Pa-s and a HMW M w of from about 800 kg/mol to about 1,500 kg/mol.

First claim

What is claimed is:

1. A bimodal polyethylene copolymer comprising a lower molecular weight (LMW) component and a higher molecular weight (HMW) component, the copolymer having a z-average molecular weight (M z ) of from about 1,000 kg/mol to about 2,500 kg/mol, a weight fraction of the LMW component (LMW fr.) of from about 0.60 to 0.85, a ratio of a weight average molecular weight (M w ) of the HMW component (HMW M w ) to a M w of the LMW component (LMW M w ) of from about 14 to about 25, a zero shear viscosity (η 0 ) of from about 5×10 5 Pa-s to about 1×10 7 Pa-s and a HMW M w of from about 800 kg/mol to about 1,500 kg/mol, wherein the copolymer is prepared using a residence time in a polymerization reactor of equal to or greater than about 30 minutes.

2. The copolymer of claim 1 having a processability characterized by a pressure index of greater than about (1.1×η 100 +50) and a bubble stability index of less than about (0.96×(η 0 /10000)−15), wherein η 100 is the viscosity of the copolymer expressed in Pas and measured at 190° C. and a shear rate of 100 rad/s.

3. The copolymer of claim 2 wherein the pressure index is defined by following equation: pressure index=5737−563*(HMW M w /LMW M w )−209*(HMW fr./LMW fr.)+7*M z −1234*M z /M w +404*(HMW M w /LMW M w *HMW fr./LMW fr.)−0.22*(HMW M w /LMW M w *M z )+139*(HMW M w /LMW M w *M z /M w )+2*(HMW fr./LMW fr.*M z )−1591*(HMW fr./LMW fr.*M z /M w )−0.64*(M z *M z /M w ), wherein HMW fr. is a weight fraction of the HMW component.

4. The copolymer of claim 2 wherein the bubble stability index is defined by following equation: bubble stability index=1.31×10 4 −2.76×10 3 *(HMW M w /LMW M w )−1.46×10 5 *(HMW fr./LMW fr.)+4.16×10 2 *M z −2.43×10 4 *M z /M w .

5. The copolymer of claim 1 comprising an alpha olefin comonomer.

6. The copolymer of claim 5 wherein the alpha olefin comonomer comprises 1-hexene.

7. The copolymer of claim 1 having a M w from about 200 kg/mol to 600 kg/mol.

8. The copolymer of claim 1 having a M z /M w ratio from about 4 to about 8.

9. The copolymer of claim 1 having a M w /M n ratio of from about 10 to about 25.

10. The copolymer of claim 1 wherein the LMW component has a weight average molecular weight of from about 40 kg/mol to about 80 kg/mol.

11. The copolymer of claim 1 wherein the HMW component has a weight average molecular weight of from about 1,000 kg/mol to about 1,450 kg/mol.

12. The copolymer of claim 1 which when tested in accordance with ASTM D1238 has a high load melt index (I 21.6 ) of from about 8 g/10 min to about 30 g/10 min.

13. The copolymer of claim 1 which when tested in accordance with ASTM D1505 has a density of from about 0.930 glee to about 0,950 g/cc.

14. The copolymer of claim 1 having a moo of from about 1,000 Pa-s to about 2,500 Pa-s.

15. The copolymer of claim 1 having a number average molecular weight (M n ) of from about 15 kg/mol to about 30 kg/mol.

16. The copolymer of claim 1 having a HMW fr./LMW fr. ratio of from about 0.20 to about 0.50, wherein HMW fr. is a weight fraction of the HMW component.

17. The copolymer of claim 1 which when tested in accordance with ASTM D1709 has a dart drop strength ranging from about 100 g to about 450 g.

18. The copolymer of claim 1 which when tested in accordance with ASTM D1922 has an Elmendorf tear strength in the machine direction ranging from about 25 g to about 75 g.

19. The copolymer of claim 1 which when tested in accordance with ASTM D1922 has an Elmendorf tear strength in the transverse direction ranging from about 300 g to about 500 g.

20. A film made from the copolymer of claim 1 .

21. A food packaging comprising the film of claim 20 .

Assignees

• Chevron Phillips Chemical Co

Inventors

• St Jean Guylaine
• Yang Qing
• Lanier J Todd

Classifications

• C08L23/0815 Primary

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08F10/14 Primary

  Monomers containing five or more carbon atoms · CPC title

• C08F4/65925

  two cyclopentadienyl rings being mutually non-bridged · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C08L2314/06

  Metallocene or single site catalysts · CPC title