Metal powderdous catalyst comprising a CoCrMo-alloy

Patent metadata

Field	Value
Publication number	US-9283549-B2
Application number	US-201314380195-A
Country	US
Kind code	B2
Filing date	Feb 22, 2013
Priority date	Feb 24, 2012
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

The present invention is related to a new metal powder catalytic system (catalyst) comprising a cobalt/chrome-alloy as a carrier, its production and its use in hydrogenation processes.

First claim

The invention claimed is:

1. A powderous catalytic system comprising powder particles formed of a metal alloy carrier which is coated by a metal oxide layer impregnated with Pd particles, wherein the metal alloy carrier comprises:
(i) 55 wt-%-80 wt-%, based on the total weight of the metal alloy, of Co, and
(ii) 20 wt-%-40 wt-%, based on the total weight of the metal alloy, of Cr, and
(iii) 2 wt-%-10 wt-%, based on the total weight of the metal alloy, of Mo.

2. The powderous catalytic system according to claim 1 , wherein the metal alloy carrier further comprises metals other than Co, Cr and Mo.

3. The powderous catalytic system according to claim 1 , wherein the metal alloy carrier further comprises carbon.

4. The powderous catalytic system according to claim 1 , wherein the metal alloy carrier comprises Co in an amount of 55 wt-%-70 wt-%, based on the total weight of the metal alloy carrier.

5. The powderous catalytic system according to claim 1 , wherein the metal alloy comprises Cr in an amount of 20 wt-%-35 wt-%, based on the total weight of the metal alloy carrier.

6. Catalyst according to claim 1 , wherein the metal alloy comprises 4 wt-%-10 wt-%, based on the total weight of the metal alloy, of Mo.

7. The powderous catalytic system according to claim 1 , wherein the metal oxide layer is basic or amphoteric.

8. The powderous catalytic system according to claim 1 , wherein the metal oxide layer comprises Zn, Cr, Mn, Cu and/or Al.

9. The powderous catalytic system according to claim 1 , wherein the metal oxide layer comprises ZnO and optionally at least one further metal oxide selected from the group consisting of Cr, Mn, Mg, Cu and Al.

10. The powderous catalytic system according to claim 1 , wherein the metal oxide layer comprises ZnO and Al 2 O 3 .

11. The powderous catalytic system according to claim 1 , wherein the metal oxide layer is non-acidic, and wherein the non-acidic metal oxide layer is present in an amount between 0.1 wt-% and 50 wt-%, based on the total weight of the catalytic system.

12. The powderous catalytic system according to claim 1 , wherein the metal oxide layer is a mixture of ZnO and Al 2 O 3 in a ratio of ZnO to Al 2 O 3 of from 2:1 to 1:2.

13. The powderous catalytic system according to claim 1 , wherein the Pd particles are nanoparticles having an average particle size of between 0.5 and 20 nm.

14. The powderous catalytic system according to claim 13 , wherein the Pd nanoparticles are present in an amount between 0.001 wt-% and 5 wt-%, based on the total weight of the catalytic system.

15. The powderous catalytic system according to claim 12 , wherein the ratio of ZnO to Al 2 O 3 in the metal oxide layer is 1:1.

16. A method for the selective hydrogenation of an organic starting material which comprises bringing the organic starting material into contact with the powderous catalytic system according to claim 1 under selective hydrogenation conditions.

17. The method according to claim 16 , wherein the organic starting material is a compound of formula (I)

wherein
R 1 is linear or branched C 5 -C 35 alkyl or linear or branched C 5 -C 35 alkenyl moiety, wherein the C chain can be substituted, and
R 2 is linear or branched C 1 -C 4 alkyl, wherein the C chain can be substituted.

Assignees

• Dsm Ip Assets Bv

Inventors

• Bonrath Werner
• Buss Axel

Classifications

• C07C29/17

  by hydrogenation of carbon-to-carbon double or triple bonds · CPC title

• B01J37/0207

  Pretreatment of the support · CPC title

• B01J23/60 Primary

  with zinc, cadmium or mercury · CPC title

• B01J37/0226

  Oxidation of the substrate, e.g. anodisation · CPC title

• B01J23/8993 Primary

  with chromium, molybdenum or tungsten · CPC title