Post-synthetic functionalization of porous materials
US-2024299905-A1 · Sep 12, 2024 · US
US9283543B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9283543-B2 |
| Application number | US-201213526410-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 18, 2012 |
| Priority date | Sep 10, 2008 |
| Publication date | Mar 15, 2016 |
| Grant date | Mar 15, 2016 |
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Modified diamond particles for use in chromatography with a desired functional group at the diamond surface, formed from reaction of hydroxyl groups at diamond surfaces with a reactive molecule.
Opening claim text (preview).
What is claimed is: 1. A diamond particle with a modified surface comprising: a plurality of bonding sites; and a plurality of straight chain alkyl molecules tethered to the diamond surface through urethane linkages at the plurality of bonding sites, wherein the plurality of straight chain alkyl molecules provide hindrance from further bonding reactions near the bonding sites. 2. The diamond particle of claim 1 wherein each of the plurality of straight chain alkyl molecules contains an electrophilic site. 3. The diamond particle of claim 1 wherein the plurality of straight chain alkyl molecules are a reaction product of an alkyl isocyanate. 4. The diamond particle of claim 1 wherein the plurality of straight chain alkyl molecules comprise an alkyl group with the formula —(CH2)nCH3, where n=0-25. 5. The diamond particle of claim 1 wherein the plurality of straight chain alkyl molecules are partially or fully fluorinated. 6. The modified diamond particle of claim 1 , wherein the hindered bonding sites include hydroxide molecules on the diamond surface. 7. The modified diamond particle of claim 1 , wherein the plurality of straight chain alkyl molecules include the reaction product of octadecyl isocyanate and a hydroxide terminated bonding site on the diamond surface. 8. A diamond particle with a modified surface comprising: a plurality of bonding sites; and a plurality of octadecyl isocyanate molecules tethered to the diamond surface through urethane linkages at a plurality of bonding sites, wherein the octadecyl isocyanate molecules provide hindrance from further bonding reactions near the bonding sites. 9. The modified diamond particle of claim 8 , wherein the hindered bonding sites include hydroxide molecules on the diamond surface.
the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such · CPC title
comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur · CPC title
Packing or coating · CPC title
by adsorption or absorption · CPC title
Non-polar phases; Reversed phases · CPC title
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