Tire prepared by using rubber composition containing modified polymer

Patent metadata

Field	Value
Publication number	US-9279045-B2
Application number	US-99038209-A
Country	US
Kind code	B2
Filing date	Apr 30, 2009
Priority date	Apr 30, 2008
Publication date	Mar 8, 2016
Grant date	Mar 8, 2016

Abstract

A tire prepared by using a rubber composition compounded with a modified conjugated diene base polymer obtained by reacting an active site of a conjugated diene base polymer with a hydrocarbyloxysilane compound which may have a functional group to introduce a functional group having high affinity with precipitated silica and precipitated silica in which a cetyltrimethylammonium bromide-adsorbing specific surface area (CTAB) (m 2 /g) and the mode A ac in diameters (nm) of primary aggregates determined by acoustic measurement of particle size distribution satisfy equation (A) shown below:

A ac ≧−0.76×(CTAB)+274  (A).

First claim

What is claimed is:

1. A tire prepared by using a rubber composition obtained by compounding a modified conjugated diene base polymer, into which at least one functional group selected from a hydroxysilyl group, an alkoxysilyl group, an amino group or a halogen atom is introduced, precipitated silica which is produced by a precipitation process in which an alkali silicate and a mineral acid are added to an alkali silicate aqueous solution prepared in advance, and at least one silane coupling agent selected from the group consisting of compounds represented by the following formulae (VI), (VII) and (VIII),
wherein in the precipitated silica, a cetyltrimethylammonium bromide-adsorbing specific surface area (CTAB) (m 2 /g) and the mode A ac in diameters (nm) of primary aggregates determined by acoustic measurement of particle size distribution satisfy equation (A) shown below, and an ignition loss, defined as mass reduction % when heated at 750° C. for 3 hours, and a heating loss, defined as mass reduction % when heated at 105° C. for 2 hours, satisfy equation (B) shown below:
A ac ≧−0.76×(CTAB)+274  (A)

2.1≦(ignition loss)−(heating loss)≦3  (B)

wherein the mode A ac is 1 μm or less and the CTAB is 50 to 250 m 2 /g,
compounds represented by the following formula (VI):
X m Y 3−m Si—(CH 2 ) p —S q —(CH 2 ) p —SiX m Y 3−m   (VI)

wherein X is C n H 2n+1 O wherein n is an integer of 1 to 3 or a chlorine atom; Y is an alkyl group having 1 to 3 carbon atoms; m is an integer of 1 to 3; p is an integer of 1 to 9; q is an integer of 1 or more and may have distribution; provided that when m is 1, two Y may be same or different and that when m is 2 or 3, two or three X may be same or different,
compounds represented by the following formula (VII)
X m Y 3−m Si—(CH 2 ) r —W  (VII)

wherein X is C n H 2n+1 O wherein n is an integer of 1 to 3 or a chlorine atom; Y is an alkyl group having 1 to 3 carbon atoms; W is a mercapto group, a vinyl group, an amino group, a glycidoxy group or an epoxy group; m is an integer of 1 to 3; r is an integer of 0 to 9; provided that when m is 1, two Y may be same or different and that when m is 2 or 3, two or three X may be same or different, and
compounds represented by the following formula (VIII)
X m Y 3−m Si—(CH 2 ) p —S q —Z  (VIII)

wherein X is C n H 2n+1 O wherein n is an integer of 1 to 3 or a chlorine atom; Y is an alkyl group having 1 to 3 carbon atoms; Z is a benzothiazolyl group, an N,N-dimethylthiocarbamoyl group or a methacryloyl group; m is an integer of 1 to 3; p is an integer of 1 to 9; q is an integer of 1 or more and may have distribution; provided that when m is 1, two Y may be same or different and that when m is 2 or 3, two or three X may be same or different.

2. The tire as described in claim 1 , prepared by using the rubber composition comprising the modified conjugated diene base polymer, wherein the modified conjugated diene base polymer is obtained by subjecting a diene base monomer used alone or in combination with other monomers to anionic polymerization in a hydrocarbon solvent using an alkali metal or alkali earth metal base initiator to obtain a conjugated diene base polymer having an active site of metal and reacting the active site of the conjugated diene base polymer with a hydrocarbyloxysilane compound.

3. The tire as described in claim 1 , prepared by using the rubber composition compounded with the modified conjugated diene base polymer, wherein the functional group introduced into the modified conjugated diene base polymer is introduced into a molecular end.

4. The tire as described in claim 3 , prepared by using the rubber composition compounded with the modified conjugated diene base polymer, wherein the functional group introduced into the modified conjugated diene base polymer is introduced into a molecular end at a polymerization termination side.

5. The tire as described in claim 1 , prepared by using the rubber composition compounded with the modified conjugated diene base polymer into which both of an alkoxysilyl group and an amino group are introduced as the functional group.

6. The tire as described in claim 1 , prepared by using the rubber composition compounded with the modified conjugated diene base polymer, wherein the amino group is a protic amino group or a protected amino group.

7. The tire as described in claim 1 , prepared by using the rubber composition compounded with the modified conjugated diene base polymer, wherein the amino group is a primary amino group or a protected primary amino group.

8. The tire as described in claim 1 , prepared by using the rubber composition comprising the modified conjugated diene base polymer, wherein the modified conjugated diene base polymer is obtained by being subjected to condensation reaction in the presence of a condensation accelerating agent comprising a compound of at least one of elements belonging to 4th group, 12th group, 13th group, 14th group and 15th group in the periodic table.

9. The tire as described in claim 1 , wherein at least one rubber selected from natural rubber and/or diene base synthetic rubber is further contained as the rubber component in the rubber composition, and 10 to 150 parts by mass of the precipitated silica based on 100 parts by mass of the whole rubber components is compounded in the rubber composition.

10. The tire as described in claim 1 , wherein 1 to 20% by mass of the silane coupling agent based on a compounding amount of the precipitated silica is compounded in the rubber composition.

11. The tire as described in claim 1 , wherein the rubber composition further contains 80 parts by mass or less of carbon black as a reinforcing filler based on 100 parts by mass of the rubber component, and a total compounding amount of the carbon black and the precipitated silica is 120 parts by mass or less.

Assignees

• Hoshino Yuuta
• Mori Noriko
• Tanaka Ken
• Bridgestone Corp

Inventors

• Hoshino Yuuta
• Mori Noriko
• Tanaka Ken

Classifications

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08L2666/08

  Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof · CPC title

• C08F4/482

  Metallic lithium, rubidium, caesium or francium · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title

• B60C1/0016

  Compositions of the tread · CPC title