Blowing agent compositions of hydrochlorofluoroolefins
US-9206297-B2 · Dec 8, 2015 · US
US9279039B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9279039-B2 |
| Application number | US-53220208-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 28, 2008 |
| Priority date | Mar 29, 2007 |
| Publication date | Mar 8, 2016 |
| Grant date | Mar 8, 2016 |
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A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234yf in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
Opening claim text (preview).
The invention claimed is: 1. A polymer blowing agent composition for thermosetting foams comprising (a) from 20 to 50 weight % HFO-1234yf in combination with (b) from 50 to 80 weight % of the hydrochlorofluoroolefin HCFO-1233zd. 2. The polymer blowing agent composition of claim 1 , further comprising a non-HFO and non-HCFO hydrofluorocarbon. 3. The polymer blowing agent composition of claim 2 wherein said non-HFO and non-HCFO hydrofluorocarbon is selected from the group consisting of difluoromethane (HFC32); 1,1,1,2,2-pentafluoroethane (HFC125); 1,1,1-trifluoroethane (143a); 1,1,2,2-tetrafluoroethane (HFC134); 1,1,1,2-tetrafluoroethane (HFC134a); 1,1-difluoroethane (HFC152a); 1,1,1,2,3,3,3-heptafluoropropane (HFC227ea); 1,1,1,3,3-pentafluoropropane (HFC245fa); 1,1,1,3,3-pentafluorobutane (HFC365mfc) and 1,1,1,2,2,3,4,5,5,5-decafluoropentane (HFC4310mee). 4. The polymer blowing agent composition of claim 1 , further comprising a second hydrofluoroolefin selected from the group consisting of tetrafluoropropenes; trifluoropropenes; tetrafluorobutene isomers; pentafluorobutene isomers; hexafluorobutene isomers; heptafluorobutene isomers; heptafluoropentene isomers; octafluoropentene isomers and nonafluoropentene isomers. 5. The polymer blowing agent composition of claim 1 further comprising a component selected from the group consisting of a second hydrofluoroolefin (HFO), a hydrofluorocarbon, a hydrocarbon, an alcohol, an ester, an aldehyde, a ketone ether/diether, carbon dioxide and mixtures thereof. 6. The polymer blowing agent composition of claim 1 , further comprising a second hydrofluoroolefin selected from the group consisting of HFO-1234ze; HFO-1243zf, HFO-1354; HFO-1345; HFO-1336; HFO-1327; HFO-1447; HFO-1438 and HFO-1429.
containing carbon, halogen and hydrogen only · CPC title
of physical blowing agents, e.g. acetone and butane · CPC title
Halogenated saturated hydrocarbons, e.g. H3C-CF3 · CPC title
with compounds having active hydrogen · CPC title
Halogenated unsaturated hydrocarbons, e.g. H2C=CF2 · CPC title
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