Membrane compositions and methods for making and using them

Patent metadata

Field	Value
Publication number	US-9278319-B2
Application number	US-200913139263-A
Country	US
Kind code	B2
Filing date	Dec 11, 2009
Priority date	Dec 11, 2008
Publication date	Mar 8, 2016
Grant date	Mar 8, 2016

Abstract

By modifying existing methods for synthesizing polyaniline, a polyaniline polymer having a new constellation of material properties has been produced. The material properties of the polymeric compositions disclosed herein enhance the use of polyanilines in a wide variety of processes that use such materials, for example processes used in the formation of filtration membranes.

First claim

The invention claimed is:

1. A filtration membrane comprising from about 25% to 100% by weight of a high defect density polyaniline polymer
having an average molecular weight between 1,000 and 1×10 6 Daltons,
capable of forming a dispersion at a concentration of at least 11 weight % in a solvent consisting essentially of N-methyl-2-pyrrolidone,
and having a higher proportion of covalent bonds at the meta and/or ortho position on the aniline rings than (i) a polyaniline polymer formed in an oxidative polymerization reaction in the absence of mechanical force sufficient to disrupt nucleation during the reaction, and (ii) a polyaniline polymer formed in an oxidative polymerization reaction at a temperature below 15° C.

2. The filtration membrane of claim 1 , wherein the membrane is formed using a phase inversion process.

3. The filtration membrane of claim 2 , wherein the phase inversion process is a thermal phase inversion process.

4. The filtration membrane of claim 2 , wherein the phase inversion process is an immersion phase inversion process.

5. A method of making the filtration membrane of claim 1 , the method comprising:
combining aniline monomers and an aniline polymer initiator together in a single step so as to form an oxidative polymerization reaction; and
subjecting the oxidative polymerization reaction to a mechanical force during the oxidative polymerization reaction, wherein the mechanical force is sufficient to disrupt a nucleation process of a polyaniline polymer formed by the oxidative polymerization reaction.

6. The method of claim 5 , wherein the oxidative polymerization reaction is conducted at room temperature.

7. The method of claim 6 , wherein the oxidative polymerization reaction forms polyaniline polymers having a decreased ability to form interchain hydrogen bonding interactions in a solvent.

8. The method of claim 5 , wherein the aniline polymer initiator is a polyaniline oxidizing agent.

9. The method of claim 5 , wherein subjecting the oxidative polymerization reaction to the mechanical force comprises stirring the oxidative polymerization reaction for at least one hour after the oxidative polymerization reaction is initiated.

10. The method of claim 5 , wherein the oxidative polymerization reaction is conducted at a temperature between 20 and 25 degrees centigrade.

11. The filtration membrane of claim 1 , wherein the filtration membrane further comprises a polysulfone polymer in an amount from about 25% to about 75% by weight.

12. The filtration membrane of claim 11 , wherein the polysulfone polymer has an average molecular weight of between 1,000 and 1×10 6 Daltons.

13. The filtration membrane of claim 1 , wherein the filtration membrane further comprises:
a hydrophilic agent; or
a doping agent.

14. The filtration membrane of claim 1 , wherein the high defect density polyaniline polymer forms a dispersion at a concentration up to 18 weight % in a solvent consisting essentially of N-methyl-2-pyrrolidone.

15. The filtration membrane of claim 1 , wherein the high defect density polyaniline polymer forms a dispersion that is stable for over a week.

16. A filtration membrane comprising from about 25% to 100% by weight of a high defect density polyaniline polymer, wherein the high defect density polyaniline polymer is produced by a process comprising the steps of:
combining aniline monomers and an aniline polymer initiator together in a single step so as to form an oxidative polymerization reaction; and
subjecting the oxidative polymerization reaction to a mechanical force during the oxidative polymerization reaction, wherein the mechanical force is sufficient to disrupt a nucleation process of a polyaniline polymer formed by the oxidative polymerization reaction,
wherein
the high defect density polyaniline polymer has an average molecular weight between 1,000 and 1×10 6 Daltons;
the high defect density polyaniline polymer is capable of forming a dispersion at a concentration of at least 11 weight % in a solvent consisting essentially of N-methyl-2-pyrrolidone; and
the high defect density polyaniline polymer has a higher proportion of covalent bonds at the meta and/or ortho position on the aniline rings than (i) a polyaniline polymer formed in an oxidative polymerization reaction in the absence of mechanical force sufficient to disrupt nucleation during the reaction, and (ii) a polyaniline polymer formed in an oxidative polymerization reaction at a temperature below 15° C.

17. The filtration membrane of claim 16 , wherein the oxidative polymerization reaction is conducted at room temperature.

18. The filtration membrane of claim 16 , wherein the high defect density polyaniline polymer forms a dispersion at a concentration up to 18 weight % in a solvent consisting essentially of N-methyl-2-pyrrolidone.

19. The filtration membrane of claim 16 , wherein the filtration membrane further comprises a polysulfone polymer in an amount from about 25% to about 75% by weight.

20. The filtration membrane of claim 19 , wherein the polysulfone polymer has an average molecular weight of between 1,000 and 1×10 6 Daltons.

Assignees

• Hoek Eric M V
• Guillen Gregory R
• Kaner Richard B
• Farrell Thomas P
• Univ California

Inventors

• Hoek Eric M V
• Guillen Gregory R
• Kaner Richard B
• Farrell Thomas P

Classifications

• C08L81/06

  Polysulfones; Polyethersulfones · CPC title

• C08G73/0266

  Polyanilines or derivatives thereof · CPC title

• B01D2323/02

  Hydrophilization · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• B01D2325/26

  Electrical properties · CPC title