Use of an aqueous preparation for the coating of wood surfaces to achieve a natural-touch effect

Patent metadata

Field	Value
Publication number	US-9273210-B2
Application number	US-201214008005-A
Country	US
Kind code	B2
Filing date	Mar 23, 2012
Priority date	Mar 29, 2011
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

The present invention relates to the use of an aqueous preparation for the coating of wood surfaces, characterized in that the aqueous preparation comprises: a hydroxyl-functional polyurethane-polyacrylate dispersion, apolyurethane dispersion, an at least partially hydrophilicized polyisocyanate and ≧0 weight-% to ≦10 weight-% of a matting agent, wherein the combined hydroxyl content of the hydroxyl-functional polyacrylate dispersion and the polyurethane dispersion is ≧1% to ≦12%. The invention further relates to a method of producing a coated wood surface, comprising the step of coating a wood surface with such an aqueous preparation and to a coated wood surface comprising an aqueous preparation whose use has been recited in the context of the use according to the invention.

First claim

The invention claimed is:

1. A method for coating a wood surface, comprising applying an aqueous preparation to the wood surface; wherein the aqueous preparation comprises:
≧20 weight-% to ≦50 weight-% of a hydroxyl-functional polyurethane-polyacrylate dispersion,
≧20 weight-% to ≦50 weight-% of a polyurethane dispersion comprising a hydroxyl-functional polyurethane,
≧5 weight-% to ≦20 weight-% of an at least partially hydrophilicized polyisocyanate and
≧0 weight-% to ≦10 weight-% of a matting agent,
wherein the combined hydroxyl content of the hydroxyl-functional polyurethane-polyacrylate dispersion and the polyurethane dispersion is ≧1% to ≦12%, and
wherein the hydroxyl-functional polyurethane-polyacrylate dispersion is a polyurethane-polyacrylate hybrid secondary dispersion prepared by a process comprising:
preparing a polyurethane solution (A) having an average molecular weight M n of ≧1100 g/mol to ≦10000 g/mol, which contains no polymerizable double bond, in a non-aqueous solution, optionally in the presence of an vinylically unsaturated monomer which carries no group that is reactive towards an isocyanate group,
adding to the polyurethane solution (A), one or more vinylically unsaturated monomers (B) at least one selected from the group consisting of (B1) acid-functional monomers, (B2) hydroxyl- and/or amino-functional monomers, and (B3) other monomers different from (B1) and (B2), to form a mixture,
subjecting the mixture to free-radical polymerization in a homogeneous, non-aqueous phase to provide a hybrid polymer,
neutralizing at least one neutralizable group, and
dispersing the hybrid polymer into the aqueous phase, wherein the neutralization can take place before or after the vinyl polymerization or during the dispersing step.

2. The method of claim 1 , wherein the combined hydroxyl content of the hydroxyl-functional polyurethane-polyacrylate dispersion and the polyurethane dispersion is ≧1% to ≦10%.

3. The method of claim 1 , wherein in the free-radical polymerization the fraction of the acid-functional monomers in the monomer mixture is higher at the end than at the beginning of the reaction.

4. The method of claim 1 , wherein the polyurethane-polyacrylate hybrid polymer contains a hydroxyl group both in the polyurethane fraction (A) and in the vinylically unsaturated monomer fraction (B).

5. The method of claim 1 , wherein the polyurethane dispersion comprises:
I) a hydroxyl-free polyurethane and/or polyurethane-urea and/or
II) an ionically modified, hydroxyl- and/or amino-containing polyurethane and/or polyurethane-urea, and
III) at least one crosslinker, identical or different from the at least partially hydrophilicized polyisocyanate,
wherein the components (I) and (II), comprise a polycarbonate polyol which has at least 25% by weight of 1,4-butanediol as a synthesis component.

6. The method of claim 5 , wherein the polycarbonate polyol contains ≧60% to ≦100% by weight of 1,4-butanediol and ≧0% to ≦40% by weight of 1,6-hexandiol as synthesis components, the sum of 1,4-butanediol and 1,6-hexanediol adding up to ≦100% by weight.

7. The method of claim 5 , wherein the polycarbonate polyol has an average hydroxyl functionality of ≧1.6 to ≦4.

8. The method of claim 1 , wherein the at least partially hydrophilicized polyisocyanate is an aliphatic polyisocyanate.

9. The method of claim 8 , wherein the at least partially hydrophilicized polyisocyanate is based on 1,6-hexamethylene diisocyanate.

10. A coated wood surface produced by the method of claim 1 .

Assignees

• Schrinner Marc Claudius
• Irle Christoph
• Melchiors Martin
• Almato Guiteras Maria
• Tejada Eva
• Covestro Deutschland Ag

Inventors

• Schrinner Marc Claudius
• Irle Christoph
• Melchiors Martin
• Almato Guiteras Maria
• Tejada Eva

Classifications

• C09D5/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• C08G18/6229 Primary

  Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols · CPC title

• C08G18/44

  Polycarbonates · CPC title

• C08G18/0823 Primary

  containing carboxylate salt groups or groups forming them · CPC title

• C08L75/04

  Polyurethanes · CPC title