Adhesive composition and adhesive containing the same

Patent metadata

Field	Value
Publication number	US-9273202-B2
Application number	US-200913119508-A
Country	US
Kind code	B2
Filing date	Aug 28, 2009
Priority date	Sep 18, 2008
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

It is an object of the present invention to provide adhesive compositions having excellent flexibility, rubber elasticity, mechanical properties, heat resistance and low-temperature properties.
An adhesive composition of the invention includes 10 to 70 parts by weight of a soft polypropylene resin composition (X) which includes 40 to 98 wt % of a propylene copolymer (A) satisfying the following requirements (A 1 ) to (A 8 ) and 2 to 60 wt % of a crystalline isotactic polypropylene (B) satisfying the following requirements (B 1 ) to (B 3 ), and 30 to 90 parts by weight of a tackifier (C) (wherein the total of the component (X) and the component (C) is 100 parts by weight), wherein (A 1 ) Shore A hardness: 20 to 90; (A 2 ) the copolymer comprises a copolymer with C 3 units at 51 to 90 mol %, C 2 units at 7 to 24 mol % and C 4-20 α-olefin units at 3 to 25 mol %; (A 3 ) Mw/Mn: 1.2 to 3.5; (A 4 ) mm: 85 to 99.9%; (A 5 ) value B: 0.8 to 1.3; (A 6 ) 2,1-insertion ratio: less than 1%; (A 7 ) Tg: −10° C. to −50° C.; (A 8 ) MFR (230° C.): 0.5 to 500 g/10 min; (B 1 ) Tm: 100 to 175° C.; (B 2 ) mmmm: 90 to 99.8%; (B 3 ) MFR (230° C.): 0.1 to 100 g/10 min.

First claim

The invention claimed is:

1. A hot melt adhesive consisting of:
10 to 70 parts of a polypropylene resin composition (X);
30 to 90 parts of at least one tackifier (C) selected from the group consisting of natural rosins, modified rosins, polyterpene resins, synthetic petroleum resins, coumarone resins, phenolic resins, xylene resins, styrene resins, and isoprene resins, wherein the total of the component (X) and the component (C) is 100 parts by weight; and
optionally at least one first additive selected from the group consisting of a flow modifier, an inorganic filler, an antioxidant and a weathering stabilizer, wherein the polypropylene resin composition (X) consists of:
40 to 98 wt. % of a propylene copolymer (A) satisfying the following requirements (A 1 ) to (A 8 ):
(Al) the Shore A hardness is in the range of 20 to 90;
(A 2 ) the propylene copolymer is a propylene/ethylene/C 4-20 α-olefin copolymer comprising: 51 to 90 mol. % of structural units derived from propylene, 7 to 24 mol. % of structural units derived from ethylene and 3 to 25 mol. % of structural units derived from an α-olefin having 4 to 20 carbon atoms, wherein the total of the structural units from propylene, the structural units from ethylene and the structural units from an α-olefin having 4 to 20 carbon atoms is 100 mol. %;
(A 3 ) the ratio, of the weight average molecular weight, Mw, to the number average molecular weight, Mn, according to gel permeation chromatography, GPC, is 1.2 to 3.5;
(A 4 ) the isotactic triad fraction, ram, calculated by 13 C-NMR is 85 to 99.9%:
(A 5 ) the value B defined by Formula below is 0.8 to 1.3:

B
=

M
OE

2
⁢

⁢

M
O

·

M
E

(
1
)

wherein M oe is a molar fraction of the total of propylene-ethylene sequences and C 4 or higher α-olefin-ethylene sequences to all the dyad sequences, M o is a total of molar fractions of propylene and the C 4 or higher α-olefin, and M E , is a molar fraction of ethylene;
(A 6 ) the ratio of 2,1-insertions of propylene monomers in all propylene insertions is less than 1% according to 13 C-NMR; (A 7 ) the glass transition temperature, Tg, is observed in the range of −10° C. to −50° C.; (A 8 ) MFR, as measured in accordance with ASTM D 1238 at 230° C. under a load of 2.16 kg, is 0.5 to 500 g/10 min; 2 to 60 wt. % of a crystalline isotactic polypropylene (B) satisfying the following requirements (B 1 ) to (B 3 ):
(B 1 ) the melting point, Tm, is in the range of 100 to 175° C. as measured by DSC wherein the polymer is held at 200° C. for 10 minutes in a differential scanning calorimeter, DSC, cooled to −20° C. at a temperature decreasing rate of 10° C./min, held at −20° C. for 1 minute, and heated at a temperature increasing rate of 10° C./min;
(B 2 ) the isotactic pentad fraction, mmmm, is 90 to 99.8%; and
(B 3 ) the melt flow rate, MFR, as measured in accordance with ASTM D 1238 at 230° C. under a load of 2.16 kg, is 0.1 to 100 g/10 min; and

optionally at least one second additive selected from the group consisting of weathering stabilizer, heat stabilizer, antistatic agent, anti-slip agent, antiblocking agent, antifogging agent, nucleating agent, lubricant, pigment, dye, plasticizer, anti-aging agent, hydrochloric acid absorber, antioxidant and copper inhibitor.

2. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of natural rosins.

3. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of modified rosins.

4. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of polyterpene resins.

5. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of synthetic petroleum resins.

6. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of coumarone resins.

7. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of phenolic resins.

8. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of xylene resins.

9. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of styrene resins.

10. The hot melt adhesive of claim 1 , wherein the at least one tackifier (C) is selected from the group consisting of isoprene resins.

Assignees

• Hoya Hiroshi
• Matsunaga Koji
• Hayakawa Yoji
• Yasui Hiroto
• Tokui Shin
• Mitsui Chemicals Inc

Inventors

• Hoya Hiroshi
• Matsunaga Koji
• Hayakawa Yoji
• Yasui Hiroto
• Tokui Shin

Classifications

• C09J123/142

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08L2666/06

  Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof · CPC title

• C08L2666/02

  Organic macromolecular compounds, natural resins, waxes or and bituminous materials · CPC title

• C08L23/12

  Polypropene · CPC title

• C08L23/142 Primary

  at least partially crystalline copolymers of propene with other olefins · CPC title