High density polyethylene composition and closure

Patent metadata

Field	Value
Publication number	US-9273199-B2
Application number	US-201313914460-A
Country	US
Kind code	B2
Filing date	Jun 10, 2013
Priority date	Jun 11, 2012
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

Disclosed is a high-density polyethylene (HDPE) composition that comprises at least a first high density polyethylene component having a density of 0.940-0.968 g/cm 3 and a melt index I 2.16 of 0.5-10.0 dg/min and a melt flow ratio (flow index I 21.6 at 190° C. divided by melt index I 2.16 at 190° C.) of at least 25. A second HDPE component may be included in the composition with melt index I 2.16 of greater than 10 dg/min and melt flow ratio of 30 or less. The disclosed compositions are suitable for use in living hinge closure applications.

First claim

What is claimed:

1. A composition for manufacturing a molded hinge component, comprising:
a mixture comprising a first high-density polyethylene (HDPE) and a second HDPE wherein the first HDPE is different from the second HDPE:
the first high-density polyethylene (HDPE) resin has:
a. a Melt Index (I 2.16 ) of about 0.5 dg/min to 10 dg/min,
b. a Density of about 0.940 g/cm 3 to 0.968 g/cm 3 , and
c. a Melt Flow Ratio (I 21.6 :I 2.16 ) greater than about 25; and

the second HDPE resin has a melt flow ratio less than about 30.

2. The composition of claim 1 , wherein the first HDPE resin has a melt flow ratio greater than about 50.

3. The composition of claim 2 ; wherein the second HDPE resin comprises from about 10 to 90% by weight of the composition for manufacturing a molded hinge component.

4. The composition of claim 2 , wherein the first HDPE resin is produced via a continuous reaction process either in-situ with one reactor, or in series with multiple reactors.

5. The composition of claim 2 , further comprising from about 0.1-80% by weight of any organic, or inorganic filler.

6. The composition of claim 5 wherein the filler is selected from the group consisting of glass spheres, calcium carbonate, post consumer recycle, glass fibers, talc, and combinations thereof.

7. The composition of claim 2 , further comprising one or more additives selected from the group consisting of polymer processing aids (ppa), slip components, nucleators, antistatic additives, and organic or inorganic performance enhancing additives or combination thereof.

8. The composition of claim 2 , further comprising a HHPA nucleator.

9. The composition of claim 2 , further comprising 1,2 Cyclohexanedicarboxylic Acid, or its salts.

10. The composition of claim 2 , further comprising a colorant.

11. The composition of claim 2 , wherein the overall composition is further characterized by having a viscosity measured at 200/s between about 100-250 Pa-s.

12. The composition of claim 2 , wherein the overall composition is further characterized by having a viscosity measured at 8,000/s between about 25-40 Pa-s.

13. The composition of claim 2 , wherein the overall composition is further characterized by having an Mz of greater than about 200,000 g/mol.

14. The composition of claim 2 , wherein overall composition is further characterized by having an Mw of less than about 65,000 g/mol.

15. The composition of claim 2 wherein the second HDPE is multimodal in terms of molecular weight distribution.

16. The composition of claim 1 , wherein the first HDPE resin has a Mz greater than about 200,000.

17. The composition of claim 1 , wherein the first HDPE resin comprises from about 10 to 90% by weight of the composition for manufacturing a molded hinge component.

18. The composition of claim 1 wherein the first HDPE is multimodal in terms of molecular weight distribution.

Assignees

• Domoy Brett Christopher
• Unger Barrett Albert
• Jablonka Mark T
• Dow Global Technologies Llc
• Conopco Inc

Inventors

• Domoy Brett Christopher
• Unger Barrett Albert
• Jablonka Mark T

Classifications

• C08L23/04

  Homopolymers or copolymers of ethene · CPC title

• C08F110/02

  Ethene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• Y10T403/45

  Flexibly connected rigid members · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title