Hydrogenolysis of ethyl acetate in alcohol separation processes

Patent metadata

Field	Value
Publication number	US-9272970-B2
Application number	US-201113178659-A
Country	US
Kind code	B2
Filing date	Jul 8, 2011
Priority date	Jul 9, 2010
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid and by reacting a portion of the crude ethanol product or one or more derivative streams containing ethyl acetate obtained therefrom in the presence of hydrogen, via hydrogenolyzis. The one or more derivative streams comprise ethyl acetate that are reacted via hydrogenolyzis to form additional ethanol that may be directly or indirectly fed to the separation zone or the hydrogenation reactor.

First claim

We claim:

1. A process for producing ethanol, comprising the steps of:
hydrogenating acetic acid in a first reactor in the presence of a catalyst to form a first crude ethanol product;
separating at least a portion of the first crude ethanol product in a first column into a first distillate comprising ethanol, water and ethyl acetate, and a first residue comprising acetic acid and a substantial portion of the water from the at least a portion of the first crude ethanol product;
removing water from the first distillate to form an ethanol mixture;
separating at least a portion of the ethanol mixture in a second column into a second distillate comprising ethyl acetate and a second residue comprising ethanol;
reacting in a second reactor at least a portion of the second distillate in the presence of hydrogen to form a second crude ethanol product;
flashing at least a portion of the second crude ethanol product to generate a vapor stream comprising hydrogen; and
introducing the vapor stream to the first reactor, wherein substantially all of the hydrogen introduced to the first reactor is obtained from the vapor stream, and
wherein all the hydrogen fed to the process is fed to the second reactor.

2. The process of claim 1 , wherein the second crude ethanol product comprises at least 5% more ethanol than the at least a portion of the second distillate.

3. The process of claim 1 , wherein the at least a portion of the second distillate comprises at least 5 wt. % ethyl acetate.

4. The process of claim 1 , wherein the second crude ethanol product comprises less ethyl acetate than the at least a portion of the second distillate.

5. The process of claim 1 , wherein the at least a portion of the second distillate is withdrawn from the second column as a vapor.

6. The process of claim 1 , wherein the at least a portion of the second distillate is condensed and withdrawn from the second column as a liquid.

7. The process of claim 1 , wherein the step of flashing at least a portion of the second crude ethanol product generates a vapor stream comprising hydrogen and a liquid stream; and further
introducing a portion of the liquid stream to the second column.

8. The process of claim 1 , wherein at least 95% of the water from the portion of the first distillate is removed.

Assignees

• Warner R Jay
• Horton Trinity
• Jevtic Radmila
• Johnston Victor J
• Lee David
• Orosco Adam
• Sarager Lincoln
• Celanese Int Corp

Inventors

• Warner R Jay
• Horton Trinity
• Jevtic Radmila
• Johnston Victor J
• Lee David
• Orosco Adam
• Sarager Lincoln

Classifications

• C07C29/141

  with hydrogen or hydrogen-containing gases · CPC title

• C07C29/149 Primary

  with hydrogen or hydrogen-containing gases · CPC title

• C07C67/08

  by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds · CPC title

• C07C29/90

  using hydrogen only · CPC title

• C07C29/88

  by treatment giving rise to a chemical modification of at least one compound (chemisorption C07C29/76) · CPC title