Coated glass substrate with heat treatable ultraviolet blocking characteristics

Patent metadata

Field	Value
Publication number	US-9272949-B2
Application number	US-80506910-A
Country	US
Kind code	B2
Filing date	Jul 9, 2010
Priority date	Jul 9, 2010
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

Certain example embodiments of this invention relate to the development of temperable UV blocking coatings having enhanced UV blocking efficiency and aesthetic appearance on stock sheets of glass substrates using large-scale wet coating manufacturing methods. A glass substrate is provided. A base coat is curtain coated on the glass substrate from a oxide precursor material including zinc, cerium, titanium, and silicon precursor materials. The base coat is cured. A top coat is roll coated, directly or indirectly, on the base coat, with the top coat being a sacrificial cross-linked organic polymer-based layer. The substrate is heat treated with the base coat and the top coat thereon. The base coat and the top coat are substantially uniform in thickness, and the heat treating removes substantially all of the top coat while causing substantially no cracking in the base coat.

First claim

What is claimed is:

1. A method of making a coated article, the method comprising:
providing a glass substrate;
curtain coating an ultraviolet (UV) radiation blocking base coat on the glass substrate, the base coat including oxides of zinc, cerium, titanium, and silicon, wherein the UV blocking base coat is formed from an oxide precursor consisting essentially of 55-85 mol % zinc, 5-50 mol % ceria and titania, and silane in an amount no more than 10 mol %;
curing the base coat;
roll coating a substantially uniformly thick top coat, directly or indirectly, on the base coat, the top coat being a sacrificial cross-linked organic polymer-based layer to be removed from the coated article; and
heat treating the substrate with the base coat and the top coat thereon,
wherein the thickness of the base coat and the top coat of the coated article each respectively has a thickness variation of no more than 15% of target coating thicknesses for each coat prior to the heat treating, and wherein
the top coat is removed from the coated article during and/or after the heat treating without leaving any residues on the base coat, resulting in a substantially crack-free base coat.

2. The method of claim 1 , wherein
the base coat is formed from an oxide precursor consisting essentially of 65-80 mol % zinc, 15-25 mol % ceria and titania, and silane in an amount no more than 5 mol %.

3. The method of claim 2 , wherein
ceria and titania are provided in substantially equal mol percents.

4. The method of claim 2 , wherein
the top coat is a UV curable resin.

5. The method of claim 2 , wherein
the top coat is a preformed polymer of or including PVB or PMMA.

6. The method of claim 2 , wherein
the top coat is a thermally curable polyimide.

7. The method of claim 2 , wherein
the base coat is cured at a temperature of 240-270 degrees C.

8. The method of claim 2 , wherein
the heat treating removes substantially all of the top coat from the base coat such that the base coat is substantially crack-free.

9. The method of claim 8 , wherein
the base coat and the top coat have respective thickness tolerances of no more than 10% prior to the heat treating.

10. The method of claim 8 , wherein
the base coat and the top coat have respective thickness tolerances of no more than 5% prior to the heat treating.

11. The method of claim 8 , further comprising cutting and edge seaming the glass substrate into a plurality of smaller substrates prior to the heat treating, and wherein
the heat treating is performed on at least some of the smaller substrates.

12. The method of claim 1 , wherein
the base coat is formed from an oxide precursor consisting essentially of 65-70 mol % zinc oxide, 30-35 mol % ceria and titania, remainder silane.

13. The method of claim 12 , wherein
ceria and titania are provided in substantially equal mol percents.

14. A method of making a coated article, the method comprising:
providing a glass substrate having located thereon (a) an infrared (IR) radiation blocking coating comprising a low-emissivity coating, (b) an ultraviolet (UV) radiation blocking base coat curtain coated from an oxide precursor material including zinc, cerium, titanium, and silicon, and (c) a substantially uniformly thick sacrificial cross-linked organic polymer-based top coat, to be removed from the coated article, roll coated on the base coat; and
heat treating the substrate with the base coat and the top coat thereon, the heat treating removing all of the top coat from the base coat without leaving any residues on the base coat such that the base coat is substantially crack-free;
wherein the base coat is formed from an oxide precursor consisting essentially of 40-80 mol % zinc, 5-50 mol % ceria and titania, and silane in an amount no more than 10 mol %, and
wherein the thickness of the base coat and the top coat of the coated article each respectively has a thickness variation of no more than 10% of target coating thicknesses for each coat prior to the heat treating.

15. The method of claim 14 , wherein
ceria and titania are provided in substantially equal mol percents.

16. The method of claim 15 , wherein
the oxide precursor consists essentially of 65-70 mol % zinc, 30-35 mol % ceria and titania, remainder silane.

17. The method of claim 14 , wherein
the top coat is a UV curable resin, a preformed polymer of or including PVB or PMMA, or a thermally curable polyimide.

18. The method of claim 17 , wherein
the base coat and the top coat have respective thickness tolerances of no more than 5% prior to the heat treating.

19. The method of claim 14 , further comprising cutting and edge seaming the glass substrate into a plurality of smaller substrates prior to the heat treating, and wherein
the heat treating is performed on at least some of the smaller substrates.

Assignees

• Varaprasad Desaraju V
• Orleans David B
• Wang Zhongming
• Guardian Industries

Inventors

• Varaprasad Desaraju V
• Orleans David B
• Wang Zhongming

Classifications

• C03C2217/74

  UV-absorbing coatings · CPC title

• C03C17/42 Primary

  at least one coating of an organic material and at least one non-metal coating · CPC title

• Y10T428/24612

  Composite web or sheet · CPC title

• C03C17/002

  for flat glass, e.g. float glass · CPC title

• C03C2218/355

  Temporary coating · CPC title