Near net shape manufacturing of rare earth permanent magnets

Patent metadata

Field	Value
Publication number	US-9272332-B2
Application number	US-201213628490-A
Country	US
Kind code	B2
Filing date	Sep 27, 2012
Priority date	Sep 29, 2011
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

A method of near net shaping a rare earth permanent magnet and a permanent magnet. The method includes introducing a magnetic material powder into a die, closing the die and shock compacting the powder in the die and sintering the compacted magnet powder to form the rare earth permanent magnet part. In one form, the magnetic material being subjected to compaction is a mixture made up of two or more different magnetic material powder precursors. Additional materials may be added to the mixture. One such additional material may be a lubricant to reduce the likelihood of cracking, while another may be a coating to provide oxidation protection of the mixture. Evacuation or inert environments may also be used either prior to or in conjunction with the sintering or related high-temperature part of the process.

First claim

What is claimed is:

1. A method of near net shape forming a rare earth permanent magnet, said method comprising:
introducing a plurality of magnetic material powders into a die;
mixing said plurality of powders to produce a blended powder;
shock compacting the blended powder in said die to produce a compacted powder;
adding a protective layer to the compacted powder to reduce oxidation of said compacted powder; and
sintering the compacted powder subsequent to adding the protective layer.

2. The method of claim 1 , wherein said protective layer is a ceramic-based slurry.

3. The method of claim 2 , wherein said slurry and said compacted powder are heated at a rate between 1° C./minute and 5° C./minute.

4. The method of claim 1 , further comprising subjecting said compacted powder to one of an evacuated atmosphere or an oxidatively inerted atmosphere.

5. The method of claim 1 , wherein the shock compacting is produced by an electrohydraulic process, an electromagnetic process, a spring releasing process, a piezoelectric process, an explosion process, an electric gun process or combinations thereof.

6. The method of claim 5 , wherein a layer of metal is disposed between said magnetic material powder and an explosive prior to said shock compacting by said explosion process.

7. The method of claim 1 , wherein a density of the compacted powder is at least about 90 percent of a theoretical density.

8. The method of claim 1 , wherein the rare earth permanent magnet has a non-stoichiometric composition.

9. The method of claim 1 , further comprising surface treating the rare earth permanent magnet.

10. The method of claim 1 , further comprising adjusting powder alignment of said blended powder in the presence of a magnetic field.

11. The method of claim 1 , further comprising cooling the sintered powder in said die.

12. The method of claim 1 , wherein sintering the compacted magnetic material powder comprises heating at a rate of about 1° C./min to about 5° C./min to a temperature within a range of about 900° C. to about 1200° C. for between about 1 to about 10 hr.

13. The method of claim 1 , wherein the shock compaction is performed at a temperature of about 20° C. to about 25° C.

14. The method of claim 1 , wherein the compacted magnetic material powder is sintered in a second die that is different from said die.

15. The method of claim 1 , wherein said at least one of said plurality of powders comprises at least one of dysprosium and terbium such that prior to said shock compacting, said at least one of dysprosium and terbium is present in said rare earth magnetic material powder in an amount of between about 1 weight percent and about 9 weight percent.

16. A method of shock compacting a rare earth permanent magnet, said method comprising:
introducing a mixture of a neodymium-iron-boron powder and a powder containing at least one of dysprosium and terbium into a die;
using a magnetic field to preferentially align at least one of said neodymium-iron-boron powder and said powder containing at least one of dysprosium and terbium;
shock compacting the powders to produce a compacted powder;
adding a protective layer to the compacted powder to reduce oxidation of said compacted powder; and
sintering the compacted powder.

17. The method of claim 16 , wherein said mixture further comprises a lubricant in a quantity of up to about 2 percent by weight.

18. The method of claim 17 , wherein said lubricant is inorganic-based that comprises at least one of boron nitride, molybdenum disulfide and tungsten disulfide.

19. The method of claim 17 , wherein said lubricant is organic-based that comprises at least one of zinc stearate and a paraffinic wax.

20. The method of claim 17 , further comprising a secondary operation selected from the group consisting of machining, repressing, coining, sizing, deburring, surface compressive peening, joining and tumbling.

Assignees

• Gm Global Tech Operations Inc

Inventors

• Becker Edward P
• Wang Yucong

Classifications

• H01F1/0577 Primary

  sintered · CPC title

• C22C38/001

  containing N · CPC title

• H01F41/0293

  diffusion of rare earth elements, e.g. Tb, Dy or Ho, into permanent magnets · CPC title

• B22F3/10

  Sintering only · CPC title

• H01F41/0266

  Moulding; Pressing (H01F41/0273 takes precedence; hard magnetic particles H01F1/06, H01F1/11) · CPC title