Manufacture of catalyst compositions and systems

Patent metadata

Field	Value
Publication number	US-9272271-B2
Application number	US-201414311219-A
Country	US
Kind code	B2
Filing date	Jun 20, 2014
Priority date	Sep 19, 2007
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

A method of producing a catalyst composition is provided, the method comprising mixing (i) a first component comprising a zeolite, and (ii) a second component comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic support, wherein the first component and the second component form an intimate mixture, and wherein the homogeneous solid mixture is produced by mixing a reactive solution comprising a precursor of the metal inorganic support and a templating agent with a precursor of the catalyst metal, and calcining the mixture to form the homogeneous solid mixture. The templating agent affects one or more of pore size, pore distribution, pore spacing, or pore dispersity of the metal inorganic support. The pores of the solid mixture produced after calcination may have an average diameter in a range of about 1 nanometer to about 15 nanometers.

First claim

The invention claimed is:

1. A method of producing a catalyst composition comprising mixing
(i) a first component comprising particles of a zeolite, and
(ii) a second component comprising particles comprised of a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic support,
wherein at least a portion of particles of the first component and at least a portion of the particles of the second component are in contact with one another to form an intimate mixture, and
wherein the homogeneous solid mixture is produced by mixing a reactive solution comprising a precursor of the metal inorganic support and a templating agent with a precursor of the catalyst metal, and calcining the mixture to form the homogeneous solid mixture.

2. The method of claim 1 wherein the particles of the second component have pores that have an average diameter of about 1 nanometer to about 15 nanometers.

3. The method of claim 1 wherein the homogeneous solid mixture is produced from a gel formed in the presence of a solvent, modifier, an inorganic halide, sulfate, nitrate, and/or sulfide salt precursor of the catalytic metal, an inorganic precursor of the metal inorganic network, and a templating agent, wherein the templating agent comprises an octylphenol ethoxylate having a structure [I]

wherein “n” is an integer having a value of about 8 to 20.

4. The method of claim 1 , wherein the catalytic metal comprises alkali metals, alkaline earth metals, transition metals, or a combination thereof.

5. The method of claim 1 , wherein the catalytic metal comprises silver, platinum, gold, palladium, iron, nickel, cobalt, gallium, indium, ruthenium, rhodium, osmium, iridium, or combinations of at least two of the foregoing metals.

6. The method of claim 1 , wherein the catalytic metal comprises silver.

7. The method of claim 6 , wherein the metal inorganic support comprises alumina.

8. The method of claim 1 , wherein the zeolite comprises zeolite Y, zeolite beta, mordenite, ferrierite, ZSM-5, ZSM-12, ZSM-22, ZSM-23, ZSM-34, ZSM-35, ZSM-38, ZSM-48; ZSM-50; ZSM-57, zeolite A, zeolite X or a combination comprising at least two of the foregoing.

9. The method of claim 1 , wherein the catalyst composition further comprises at least one promoting metal.

10. The method of claim 9 , wherein the at least one promoting metal is selected from the group consisting gallium, indium, gold, vanadium, zinc, tin, bismuth, cobalt, molybdenum, and tungsten.

Assignees

• Gen Electric

Inventors

• Lewis Larry Neil
• Whisenhunt Jr Donald Wayne
• Hancu Dan
• Mhadeshwar Ashish Balkrishna
• Winkler Benjamin Hale
• Norton Daniel George
• Siclovan Oltea Puica
• Yin Ming

Classifications

• B01J23/50

  Silver · CPC title

• B01D2255/20746

  Cobalt · CPC title

• B01J37/036

  to form a gel or a cogel · CPC title

• B01D2255/1023

  Palladium · CPC title

• B01J37/0203

  the impregnation liquid containing organic compounds · CPC title