Electrostatic image developing toner, image forming apparatus, image forming method, and process cartridge

Patent metadata

Field	Value
Publication number	US-9268244-B2
Application number	US-201214113487-A
Country	US
Kind code	B2
Filing date	Apr 25, 2012
Priority date	Apr 26, 2011
Publication date	Feb 23, 2016
Grant date	Feb 23, 2016

Abstract

An electrostatic image developing toner including: toner base particles each including a binder resin and a colorant; and an external additive, wherein the toner base particles each have protrusions on a surface thereof, an average of lengths of long sides of the protrusions is 0.1 μm or more but less than 0.5 μm, a standard deviation of the lengths of the long sides of the protrusions is 0.2 or less, a coverage rate of the protrusions on the surface of each toner base particle is 10% to 90%, and the external additive includes an external additive (A) which is fine inorganic particles each containing silicone oil.

First claim

The invention claimed is:

1. An electrostatic image developing toner comprising:
toner base particles each comprising a binder resin and a colorant; and
an external additive in an amount of from 1.0% by mass to 5.0% by mass relative to the toner base particles;
wherein
the toner base particles each have protrusions on a surface thereof,
an average of lengths of long sides of the protrusions is 0.1 μm or more but less than 0.5 μm,
a standard deviation of the lengths of the long sides of the protrusions is 0.2 or less,
a coverage rate of the protrusions on the surface of each toner base particle is from 10% to 90%, and
the external additive comprises an external additive (A) which is fine inorganic particles each comprising silicone oil and wherein the external additive further comprises an external additive (B) comprising no silicone oil, and an amount of the external additive (B) is from 5.0% by mass or less relative to the toner base particles.

2. The toner according to claim 1 , wherein the protrusions comprise a resin, and the resin is obtained by polymerizing a monomer mixture comprising styrene.

3. The toner according to claim 2 , wherein a rate of a mass of the resin to a total mass of the toner is from 1% by mass to 20% by mass.

4. The toner according to claim 2 , wherein the toner base particles are obtained by a method comprising:
producing toner core particles; and
attaching or fusing, onto surfaces of the toner core particles, the resin, to thereby form the protrusions.

5. The toner according to claim 4 , wherein the toner core particles are obtained by granulation performed by emulsifying or dispersing, in an aqueous medium, an oil phase comprising at least the binder resin and the colorant.

6. The toner according to claim 4 , wherein the attaching or fusing comprises adding an aqueous dispersion liquid of fine resin particles to an aqueous medium comprising the toner core particles emulsified or dispersed therein, to attach or fuse the fine resin particles onto surfaces of the toner core particles.

7. An image forming apparatus comprising:
a latent image bearing member which bears a latent image thereon,
a charging unit configured to uniformly charge a surface of the latent image bearing member,
an exposing unit configured to expose the charged surface of the latent image bearing member to light based on image data to form a latent electrostatic image,
a developing unit configured to develop, with a toner, the latent electrostatic image formed on the surface of the latent image bearing member, to thereby form a visible image on the surface of the latent image bearing member,
a transfer unit configured to transfer, onto an image-receiving medium, the visible image formed on the surface of the latent image bearing member, and
a fixing unit configured to fix the transferred visible image on the image-receiving medium,
wherein the toner is an electrostatic image developing toner comprising:
toner base particles each comprising a binder resin and a colorant; and
an external additive in an amount of from 1.0% by mass to 5.0% by mass relative to the toner base particles,
wherein
the toner base particles each have protrusions on a surface thereof,
an average of lengths of long sides of the protrusions is 0.1 μm or more but less than 0.5 μm,
a standard deviation of the lengths of the long sides of the protrusions is 0.2 or less,
a coverage rate of the protrusions on the surface of each toner base particle is from 10% to 90%, and
the external additive comprises an external additive (A) which is fine inorganic particles each comprising silicone oil and wherein the external additive further comprises an external additive (B) comprising no silicone oil, and an amount of the external additive (B) is from 5.0% by mass or less relative to the toner base particles.

8. A process cartridge comprising:
a latent image bearing member which bears a latent image thereon, and
a developing unit configured to develop, with a toner, a latent electrostatic image formed on the surface of the latent image bearing member, to thereby form a visible image on the surface of the latent image bearing member,
wherein the process cartridge is mounted detachably to the main body of an image forming apparatus, and
wherein the toner is an electrostatic image developing toner comprising:
toner base particles each comprising a binder resin and a colorant; and
an external additive in an amount of from 1.0% by mass to 5.0% by mass relative to the toner base particles,
wherein
the toner base particles each have protrusions on a surface thereof,
an average of lengths of long sides of the protrusions is 0.1 μm or more but less than 0.5 μm,
a standard deviation of the lengths of the long sides of the protrusions is 0.2 or less,
a coverage rate of the protrusions on the surface of each toner base particle is from 10% to 90%, and
the external additive comprises an external additive (A) which is fine inorganic particles each comprising silicone oil and wherein the external additive further comprises an external additive (B) comprising no silicone oil, and an amount of the external additive (B) is from 5.0% by mass or less relative to the toner base particles.

9. The apparatus according to claim 7 , wherein the protrusions comprise a resin, and the resin is obtained by polymerizing a monomer mixture comprising styrene.

10. The apparatus according to claim 9 , wherein a rate of a mass of the resin to a total mass of the toner is from 1% by mass to 20% by mass.

11. The apparatus according to claim 7 , wherein the toner base particles are obtained by a method comprising:
producing toner core particles; and
attaching or fusing, onto surfaces of the toner core particles, the resin, to thereby form the protrusions.

12. The process cartridge according to claim 8 , wherein the external additive further comprises an external additive (B) comprising no silicone oil, and an amount of the external additive (B) is 5.0% by mass or less relative to the toner base particles.

13. The process cartridge according to claim 8 , wherein the protrusions comprise a resin, and the resin is obtained by polymerizing a monomer mixture comprising styrene.

14. The process cartridge according to claim 13 , wherein a rate of a mass of the resin to a total mass of the toner is from 1% by mass to 20% by mass.

15. The process cartridge according to claim 8 , wherein the toner base particles are obtained by a method comprising:
producing toner core particles; and
attaching or fusing, onto surfaces of the toner core particles, the resin, to thereby form the protrusions.

Assignees

• Fukao Tomohiro
• Kadota Takuya
• Mikuriya Yoshihiro
• Nozaki Tsuyoshi
• Ishikawa Yoshimichi
• Fuwa Kazuoki
• Miki Tomoharu
• Ricoh Co Ltd

Inventors

• Fukao Tomohiro
• Kadota Takuya
• Mikuriya Yoshihiro
• Nozaki Tsuyoshi
• Ishikawa Yoshimichi
• Fuwa Kazuoki
• Miki Tomoharu

Classifications

• G03G9/09392

  Preparation thereof · CPC title

• G03G9/0819

  characterised by the dimensions of the particles · CPC title

• G03G9/09716

  treated with organic compounds · CPC title

• G03G9/0806

  whereby chemical synthesis of at least one of the toner components takes place · CPC title

• G03G9/09321

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title