Phosphorus-free based halogen-free flame-retardant resin composition, phosphorus-free based halogen-free flame-retardant insulated electric wire and phosphorus-free based halogen-free flame-retardant cable

Patent metadata

Field	Value
Publication number	US-9267079-B2
Application number	US-201313796425-A
Country	US
Kind code	B2
Filing date	Mar 12, 2013
Priority date	Mar 14, 2012
Publication date	Feb 23, 2016
Grant date	Feb 23, 2016

Abstract

A phosphorus-free based halogen-free flame-retardant resin composition includes a base polymer including a copolymer of ethylene and α-olefin having carbon number of 3 to 8 polymerized by a metallocene catalyst as a main component, and 5 to 30 weight % of an ethylene-vinyl acetate copolymer that has a melt flow rate of not less than 50 g/min and a vinyl acetate content of not less than 40%, a metal hydroxide blended with the base polymer in a ratio of 100 to 250 parts by weight relative to 100 parts by weight of the base polymer, and a mineral oil blended with the base polymer in a ratio of 1 to 20 parts by weight relative to 100 parts by weight of the base polymer.

First claim

What is claimed is:

1. A phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire, comprising:
a conductor; and
an insulation layer comprising a phosphorous-free based halogen-free flame-retardant composition coated around a periphery of the conductor, the phosphorous-free based halogen-free flame-retardant composition comprising:
a base polymer including a copolymer of ethylene and α-olefin having 3 to 8 carbon atoms polymerized by a metallocene catalyst as a main component, and not less than 5 weight % and not more than 30 weight % of an ethylene-vinyl acetate copolymer having a vinyl acetate content of not less than 40%;
a metal hydroxide mixed at 150 to 200 parts by weight per 100 parts by weight of the base polymer; and
a mineral oil blended with the base polymer in a ratio of 1 to 20 parts by weight per 100 parts by weight of the base polymer.

2. The phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire according to claim 1 , wherein the insulation layer is derived from crosslinking, and has an elongation rate of not less than 350% in tensile testing in compliance with JIS C3005.

3. The phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire according to claim 1 , further comprising:
a flame retardancy of being self-extinguished after not more than 1 minute in a vertical flame test according to EN60811-2-1.

4. The phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire according to claim 1 , further comprising:
a tensile strength of not less than 10 MPa when a tube obtained by extracting the conductor from the phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire is subjected to a tensile test according to JIS C3005.

5. The phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire according to claim 1 , wherein the mineral oil comprises one or not less than two process oils selected from the group consisting of a paraffin base oil, a naphthene base oil and an aroma based oil individually or in combination of thereof.

6. The phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire according to claim 1 , wherein the α-olefin having carbon number of 3 to 8 comprises propylene, 1-butene, 4-methyl-1-pentene, 1-hexene, or 1-octene.

7. A phosphorus-free based halogen-free flame-retardant cable, comprising:
an electrically-insulated electric wire comprising a conductor and an insulation layer provided around a periphery of the conductor; and
a sheath comprising a phosphorous-free based halogen-free flame-retardant composition coated around a periphery of the electrically-insulated electric wire the phosphorus-free based halogen-free flame-retardant resin composition comprising:
a base polymer including a copolymer of ethylene and α-olefin having 3 to 8 carbon atoms polymerized by a metallocene catalyst as a main component, and not less than 5 weight % and not more than 30 weight % of an ethylene-vinyl acetate copolymer having a vinyl acetate content of not less than 40%;
a metal hydroxide mixed at 150 to 200 parts by weight per 100 parts by weight of the base polymer; and
a mineral oil blended with the base polymer in a ratio of 1 to 20 parts by weight per 100 parts by weight of the base polymer.

8. The phosphorus-free based halogen-free flame-retardant cable according to claim 7 , wherein the insulation layer is derived from crosslinking, and has an elongation rate of not less than 350% in tensile testing in compliance with JIS C3005.

9. The phosphorus-free based halogen-free flame-retardant cable according to claim 7 , further comprising:
a flame retardancy of being self-extinguished after not more than 1 minute in a vertical flame test according to EN60811-2-1.

10. The phosphorus-free based halogen-free flame-retardant cable according to claim 7 , further comprising:
a tensile strength of not less than 10 MPa when a tube obtained by extracting the conductor from the phosphorus-free based halogen-free flame-retardant electrically-insulated electric wire is subjected to a tensile test according to JIS C3005.

11. The phosphorus-free based halogen-free flame-retardant cable according to claim 7 , wherein the mineral oil comprises one or not less than two process oils selected from the group consisting of a paraffin base oil, a naphthene base oil and an aroma based oil individually or in combination of thereof.

12. The phosphorus-free based halogen-free flame-retardant cable according to claim 7 , wherein the α-olefin having carbon number of 3 to 8 comprises propylene, 1-butene, 4-methyl-1-pentene, 1-hexene, or 1-octene.

13. The phosphorus-free based halogen-free flame-retardant cable according to claim 7 , further comprising:
a core comprising two phosphorus-free based halogen-free flame-retardant insulated electric wires according to claim 1 that are arranged in parallel and are pair-twisted together with an inclusion,
wherein the sheath layer covers an outer periphery of the core.

14. The phosphorus-free based halogen-free flame-retardant cable according to claim 13 , wherein the inclusion comprises polypropylene.

Assignees

• Hitachi Cable
• Hitachi Metals Ltd

Inventors

• Kimura Hitoshi
• Kajiyama Motoharu
• Suzuki Takuya

Classifications

• C09K21/14 Primary

  Macromolecular materials · CPC title