Process for the preparation of geopolymeric functional materials in a solid form

Patent metadata

Field	Value
Publication number	US-9266783-B2
Application number	US-201514599877-A
Country	US
Kind code	B2
Filing date	Jan 19, 2015
Priority date	Jan 20, 2014
Publication date	Feb 23, 2016
Grant date	Feb 23, 2016

Abstract

The present invention provides a process for the preparation of tailored precursor materials in a solid powder form, useful for geopolymeric system containing pentavalent silicon complexes in a solid powder form. The raw materials used are fly ash, sodium hydroxide, and rice husk with and without sodium silicate. The tailored precursors so obtained in solid powder need only water at site, instead of highly alkaline solution for obtaining the cementitious geopolymeric materials.

First claim

What is claimed is:

1. A tailored precursor material composition in solid form for geopolymer material comprising fly ash (59-91%), sodium hydroxide (11-15%), rice husk (0.8-11%) and optionally sodium silicate (0-29%).

2. The tailored precursor material composition as claimed in claim 1 , wherein said composition is incorporated into cement, mortar, on site in-situ concrete, or a geopolymer coating application.

3. The tailored precursor material composition as claimed in claim 1 , wherein the composition possesses compressive strength ranging between 2-50 MPa.

4. A process for the preparation of tailored precursor material composition in a solid powder form for geopolymeric material wherein the process comprises:
i. grinding of raw materials fly ash (59-91%), sodium hydroxide (11-15%), rice husk (0.8-11%) and optionally sodium silicate (0-29%) to get a powder having particle size in the range of 45 to 60 micron to get tailored precursor material;
ii. adding water to the precursor material of step (i) followed by casting the material in a standard mold, and curing the geopolymeric material to obtain a solid powdered form.

5. The process as claimed in claim 4 , wherein the raw materials are dry grinded together using ball mill or planetary mill, for a period ranging from 1-72 hours.

6. The process as claimed in claim 4 , wherein, the ratio of precursor material and water is 4 to 7.

7. The process as claimed in claim 4 , wherein, the curing of geopolymeric material is done using microwave oven for a duration of 10 seconds to 60 minutes with a power range of 5 to 1200 watt.

8. The process as claimed in claim 4 , wherein, the curing of geopolymeric material is done using hot air oven at a temperature ranging between 60-90° C. for a period of time 24 hr-7 days.

Assignees

• Council Scient Ind Res

Inventors

• Sitaram Amritphale Sudhir
• Manish Mudgal
• Kumar Chouhan Ramesh
• Deepti Mishra
• Navin Chandra

Classifications

• C04B40/0608

  Dry ready-made mixtures, e.g. mortars at which only water or a water solution has to be added before use · CPC title

• C04B18/24

  Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper {, cork} · CPC title

• C04B12/04

  Alkali metal or ammonium silicate cements {; Alkyl silicate cements; Silica sol cements; Soluble silicate cements (alkali metal silicates per se, their preparation C01B33/32; ammonium silicates per se, their preparation C01C1/00)} · CPC title

• C04B18/08

  Flue dust {, i.e. fly ash} · CPC title

• C04B28/006

  containing mineral polymers, e.g. geopolymers of the Davidovits type · CPC title