Process for manufacturing porous carbon material

Patent metadata

Field	Value
Publication number	US-9266740-B2
Application number	US-201314389992-A
Country	US
Kind code	B2
Filing date	Mar 27, 2013
Priority date	Apr 2, 2012
Publication date	Feb 23, 2016
Grant date	Feb 23, 2016

Abstract

This manufacturing process has: a step of performing a heating treatment in a contact state of SiC with Cl 2 to form a porous carbon material; a step of reacting SiCl 4 formed along with the porous carbon material in the foregoing step, with Zn to extract Si; and a step of reacting Si extracted in the foregoing step, with C to form SiC, and the process further has: a step of reducing ZnCl 2 formed by reaction of SiCl 4 with Zn, to extract Zn and Cl 2 . These steps are repetitively carried out, SiC extracted by the step of forming SiC is used in the step of forming the porous carbon material, Cl 2 extracted by reduction of ZnCl 2 is used in the step of forming the porous carbon, and Zn extracted by reduction of ZnCl 2 is used in the reaction step of SiCl 4 with Zn.

First claim

What is claimed is:

1. A process for manufacturing a porous carbon material, comprising:
a porous carbon forming step of performing a heating treatment in a contact state of a metal carbide, which is a compound of a first metal and carbon, with chlorine gas, to form a porous carbon material;
a first metal reduction step of reacting a first metal chloride formed along with the porous carbon material in the porous carbon forming step, with a second metal, to extract the first metal; and
a metal carbide forming step of reacting the first metal extracted in the first metal reduction step, with carbon to form the metal carbide,
the process further comprising:
a second metal reduction step of reducing a second metal chloride formed along with the first metal in the first metal reduction step, to extract the second metal and chlorine gas, after the first metal reduction step.

2. The process for manufacturing the porous carbon material according to claim 1 , wherein the porous carbon forming step, the first metal reduction step, the metal carbide forming step, and the second metal reduction step are repetitively carried out, wherein the metal carbide extracted by the metal carbide forming step is used in the porous carbon forming step, wherein the chlorine gas extracted by the second metal reduction step is used in the porous carbon forming step, and wherein the second metal extracted by the second metal reduction step is used in the first metal reduction step.

3. The process for manufacturing the porous carbon material according to claim 1 , wherein the metal carbide used in the porous carbon forming step is a powdery or porous body.

4. The process for manufacturing the porous carbon material according to claim 1 , wherein the metal carbide includes at least one of Al 4 C 3 , B 4 C, CaC 2 , Cr 3 C 2 , Fe 3 C, SiC, ThC 2 , TiC, UC 2 , WC, and MoC.

5. The process for manufacturing the porous carbon material according to claim 1 , wherein the porous carbon forming step is carried out in such a manner that the metal carbide is placed in a mixed gas atmosphere of the chlorine gas and an inert gas, or in an atmosphere of the chlorine gas and that the mixed gas atmosphere or the chlorine gas atmosphere is heated at a temperature of not less than 500° C. and not more than 1500° C.

6. The process for manufacturing the porous carbon material according to claim 1 , wherein the porous carbon forming step is carried out in such a manner that the metal carbide is SiC, that the metal carbide is placed in a mixed gas atmosphere of the chlorine gas and an inert gas, or in an atmosphere of the chlorine gas, and that the mixed gas atmosphere or the chlorine gas atmosphere is heated at a temperature of not less than 900° C. and not more than 1300° C.

7. The process for manufacturing the porous carbon material according to claim 1 , wherein the porous carbon forming step is carried out in such a manner that the metal carbide is TiC, that the metal carbide is placed in a mixed gas atmosphere of the chlorine gas and an inert gas, or in an atmosphere of the chlorine gas, and that the mixed gas atmosphere or the chlorine gas atmosphere is heated at a temperature of not less than 600° C. and not more than 1000° C.

8. The process for manufacturing the porous carbon material according to claim 1 , wherein the second metal is any one of a Group 1 element, a Group 2 element, a Group 11 element, and a Group 12 element.

9. The process for manufacturing the porous carbon material according to claim 1 , wherein in the porous carbon forming step, the metal carbide is SiC and the second metal is Zn.

10. The process for manufacturing the porous carbon material according to claim 1 , wherein in the porous carbon forming step, the metal carbide is TiC and the second metal is Mg.

Assignees

• Sumitomo Electric Industries

Inventors

• Ishikawa Shinji
• Majima Masatoshi

Classifications

• C01B32/05 Primary

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C01B31/02

  Chemistry & Metallurgy · mapped topic

• C01B31/10 Primary

  Chemistry & Metallurgy · mapped topic