Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source
US-9212113-B2 · Dec 15, 2015 · US
US9266732B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9266732-B2 |
| Application number | US-201114116676-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 6, 2011 |
| Priority date | May 9, 2011 |
| Publication date | Feb 23, 2016 |
| Grant date | Feb 23, 2016 |
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The present invention relates to an apparatus for reforming a hydrocarbon using a micro-channel heater, which can utilize the combustion heat of a fuel as an energy source needed for reforming a hydrocarbon. A plurality of thin metal plates having micro-channels may be laminated in a multilayered structure so as to manufacture a small to medium compact hydrogen-producing apparatus. In particular, a reforming unit may be designed to have a multilayered structure so as to improve the capacity of a reformer up to a level desired by a user.
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The invention claimed is: 1. An apparatus for hydrocarbon reforming using a micro-channel heater comprising: an upper plate including a heat transfer gas supply pipe which is connected with a heat transfer gas supply source to supply a heat transfer gas, and a reformed gas discharge pipe for discharging a reformed gas; a lower plate including a raw gas supply pipe which is connected with a raw gas supply source to supply a raw gas, and a heat transfer gas discharge pipe for discharging the heat transfer gas; an upper heat transfer unit which is disposed under the upper plate and includes an upper heat transfer gas flow path which is connected with the heat transfer gas supply pipe to flow the heat transfer gas, and an upper reformed gas flow path which is formed in contact with the upper heat transfer gas flow path so as to allow heat transfer therebetween, and connected with the reformed gas discharge pipe; a lower heat transfer unit which is disposed on the lower plate and includes a lower heat transfer gas flow path which is connected with the heat transfer gas discharge pipe to flow the heat transfer gas, and a lower reformed gas flow path which is formed in contact with the lower heat transfer gas flow path so as to allow heat transfer therebetween, and connected with the raw gas supply pipe; and at least one reforming unit laminated between the upper heat transfer unit and the lower heat transfer unit, wherein the reforming unit, in order to be laminated in two or more layers, includes: a gas supply plate on which a gas supply channel for communicating only with the lower reformed gas flow path is installed; a reforming catalyst plate which is laminated on the gas supply plate and has a reforming catalyst mounted thereon; a gas transfer unit which is laminated on the reforming catalyst plate to transfer the reformed gas by the reforming catalyst to the upper reformed gas flow path; and a heating plate which is disposed under the gas supply plate or on the gas transfer unit and has a heating channel for communicating the upper heat transfer gas flow path with the lower heat transfer gas flow path, and wherein the gas supply plate, the reforming catalyst plate, the gas transfer unit, and the heating plate include first reforming through holes communicated with the upper reformed gas flow path, second reforming through holes communicated with the upper heat transfer gas flow path, third reforming through holes communicated with the lower reformed gas flow path, and fourth reforming through holes communicated with the lower heat transfer gas flow path, respectively. 2. The apparatus according to claim 1 , wherein the upper heat transfer unit comprises: at least one upper heat transfer plate which has an upper heat transfer channel communicated with the heat transfer gas supply pipe, and form the upper heat transfer gas flow path; and at least one upper reforming plate which has an upper reforming channel communicated with the reformed gas discharge pipe, and is alternately laminated with the upper heat transfer plate to form the upper reformed gas flow path, the upper heat transfer plate and the upper reforming plate include first to fourth upper through holes formed at a position corresponding to the first to fourth reforming through holes of the reforming unit, and an upper shielding plate having the first and second upper through holes formed therein and being disposed at the lowermost side of the upper heat transfer unit. 3. The apparatus according to claim 1 , wherein the lower heat transfer unit comprises: at least one lower heat transfer plate which has a lower heat transfer channel communicated with the heat transfer gas supply pipe, and form the lower heat transfer gas flow path; and at least one lower reforming plate which has a lower reforming channel communicated with the raw gas supply pipe, and is alternately laminated with the lower heat transfer plate to form the lower reformed gas flow path, the lower heat transfer plate and the lower reforming plate include first to fourth lower through holes formed at a position corresponding to the first to fourth reforming through holes of the reforming unit, and a lower shielding plate having the third and fourth lower through holes formed therein and being disposed at the uppermost side of the lower heat transfer unit. 4. The apparatus according to claim 1 , wherein the gas transfer unit comprises: a gas collection plate which is disposed on the reforming catalyst plate, and isolated from the first to fourth reforming through holes; and a gas transfer plate which is disposed on the gas collection plate, and includes a gas transfer channel communicated only with the first reforming through hole. 5. The apparatus according to claim 1 , wherein the gas transfer unit is a collection and transfer plate which is disposed on the reforming catalyst plate, and has porous collection holes isolated from the second to fourth reforming through holes, wherein the porous collection holes are communicated with the first reforming hole through a connecting channel. 6. The apparatus according to claim 1 , wherein a reforming catalyst retainer is disposed in the reforming catalyst plate under the reforming catalyst. 7. The apparatus according to claim 1 , wherein an O-ring is disposed in the reforming catalyst plate under the reforming catalyst. 8. The apparatus according to claim 5 , wherein a cross-sectional area of the porous collection hole is formed smaller than that of the reforming catalyst.
by combustion of fuel · CPC title
Fuel cells · CPC title
Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins · CPC title
the reforming step being a steam reforming step · CPC title
Comprising catalytically active material · CPC title
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