Reversible solid oxide fuel cell stack and method for preparing same

Patent metadata

Field	Value
Publication number	US-9263758-B2
Application number	US-6535706-A
Country	US
Kind code	B2
Filing date	Aug 31, 2006
Priority date	Aug 31, 2005
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

A reversible SOFC monolithic stack is provided which comprises: 1) a first component which comprises at least one porous metal containing layer ( 1 ) with a combined electrolyte and sealing layer on the porous metal containing layer ( 1 ); wherein the at least one porous metal containing layer ( 1 ) hosts an electrode; 2) a second component comprising at least one porous metal containing layer ( 1 ) with a combined interconnect and sealing layer on the porous metal containing layer; wherein the at least one porous metal containing layers hosts an electrode. Further provided is a method for preparing a reversible solid oxide fuel cell stack. The obtained solid oxide fuel cell stack has improved mechanical stability and high electrical performance, while the process for obtaining same is cost effective.

First claim

What is claimed is:

1. A method for preparing a reversible monolithic solid oxide fuel cell stack, comprising the steps of:
(a) providing a first component which comprises at least three porous metal containing layers, each layer having a different porosity than the other two layers, wherein the three porous metal containing layers form a porous, graded structure, and wherein the porosity of the first porous metal containing layer is from 20 to 70%, the porosity of the second porous metal containing layer is from 30 to 70%, and the porosity of the third porous metal containing layer is from 30 to 80%;
(b) applying an electrolyte layer on at least one porous metal containing layer of the first component;
(c) providing a second component comprising at least three porous metal containing layers, each layer having a different porosity than the other two layers, wherein the three porous metal containing layers form a porous, graded structure, and wherein the porosity of the first porous metal containing layer is from 20 to 70%, the porosity of the second porous metal containing layer is from 30 to 70%, and the porosity of the third porous metal containing layer is from 30 to 80%;
(d) applying an interconnect layer on the at least three porous metal containing layers of the second component;
(e) stacking at least two of said first component and said second component in an alternate order such that the electrolyte layer of the first component contacts the surface of the second component being opposite to the surface of the second component which is covered with the interconnect layer, wherein the at least two of said first component and second component are in an unsintered state;
(f) sintering the stack; and
(g) forming anodes and cathodes from the most dense of the at least three porous metal containing layers of the first and second components by impregnating the layers with electrode material,
wherein the at least three porous metal containing layers of the first and second component comprise a Fe 1-x-y Cr x Ma y alloy, wherein Ma is Ni, Ti, Ce, Mn, Mo, W, Co, La, Y or Al, and doped ceria or doped zirconia, and wherein the method comprises a single sintering step.

2. The method of claim 1 , wherein the sintering step is carried out at a temperature from about 900° C. to about 1500° C.

3. The method of claim 1 , wherein the material for forming the anode by impregnation is selected from (i) Ni; (ii) Ni—Fe alloy; (iii) doped ceria; (iv) doped zirconia, (v) Ma s Ti 1-x Mb x O 3-δ , wherein Ma is Ba, Sr, or Ca; Mb is V, Nb, Ta, Mo, W, Th, or U; and s ranges from 0 to 0.5; (vi) LnCr 1-x Mb x O 3-δ , wherein M is T, V, Mn, Nb, Mo, W, Th, or U; and (vii) mixtures thereof.

4. The method claim 1 , wherein the material for forming the cathode by impregnation is selected from (La 1-x Sr x )MnO 3-δ , (Ln 1-x Sr x )MnO 3-δ , (Ln 1-x Sr x )Fe 1-y Co y O 3-δ , (Y 1-x Ca x )Fe 1-y Co y O 3-δ , (Gd 1-x Sr x )Fe 1-y Co y O 3-δ , (Gd 1-x Ca x )Fe 1-y Co y O 3-6 , (Y,Ca)Fe 1-y Co y O 3-δ , doped ceria, doped zirconia, and mixtures thereof.

5. The method of claim 1 , wherein a barrier layer is applied to (i) at least one porous metal containing layer of the first component prior to applying the electrolyte layer thereon, (ii) at least one porous metal containing layer of the second component opposite to the interconnect layer, or (iii) both (i) and (ii).

6. The method of claim 1 , wherein the electrolyte layer is applied to the layer with the lowest porosity of the at least three layers.

7. The method of claim 1 , wherein the interconnect layer is applied to the layer with the highest porosity of the at least three layers.

8. The method of claim 1 , wherein the first component and second component are punched on two opposite sides prior to application of the electrolyte layer or the interconnect layer such that gas distribution holes are formed in the first and second components.

9. The method of claim 8 , wherein a sealing layer is deposited on the first and second components after the formation of the electrolyte layer or the interconnect layer thereon.

10. The method of claim 9 , wherein the two remaining sides of the first component and the second component are punched after the application of the sealing layer such that gas distribution holes are formed in the first and second components.

11. The method of claim 9 , wherein additional holes are punched in between the gas distribution holes already punched on the two opposite sides.

12. The method of claim 10 , wherein the sealing layer comprises an electrode layer or a contact layer.

13. A reversible solid oxide fuel cell stack, obtainable by the method of claim 1 .

14. The method of claim 2 , wherein the material for forming the anode by impregnation is selected from (i) Ni; (ii) Ni—Fe alloy; (iii) doped ceria; (iv) doped zirconia; (v) Ma s Ti 1-x Mb x O 3-δ , wherein Ma is Ba, Sr, or Ca; Mb is V, Nb, Ta, Mo, W, Th, or U; and s ranges from 0 to 0.5; (vi) LnCr 1-x M x O 3-δ , wherein M is V, Mn, Nb, Mo, W, Th, or U; and (vii) mixtures thereof.

15. The method of claim 14 , wherein the material for forming the cathode by impregnation is selected from (La 1-x Sr x )MnO 3-δ , (Ln 1-x Sr x )MnO 3-δ , (Ln 1-x Sr x )Fe 1-y Co y O 3-δ , (Y 1-x Ca x )Fe 1-y Co y O 3-δ , (Gd 1-x Sr x )Fe 1-y Co y O 3-δ , (Gd 1-x Ca x )Fe 1-y Co y O 3-δ , (Y,Ca)Fe 1-y Co y O 3-δ , doped ceria, doped zirconia, and mixtures thereof.

16. The method of claim 15 , wherein a barrier layer is applied to (i) at least one of the at least three porous metal containing layers of the first component prior to applying the electrolyte layer thereon, (ii) at least one of the at least three porous metal containing layer layers of the second component opposite to the interconnect layer, or (iii) both (i) and (ii).

17. The method of claim 16 , wherein the electrolyte layer is applied to the layer with the lowest porosity of the at least three layers.

18. The method of claim 17 , wherein the interconnect layer is applied to the layer with the highest porosity of the at least three layers.

19. The method of claim 16 , wherein the interconnect layer is applied to the layers with the highest porosity of the at least three layers.

20. The method of claim 16 , wherein the first component and the second component are punched on two opposite sides prior to application of the electrolyte layer or the interconnect layer such that gas distribution holes are formed in the first and second components.

21. The method of claim 17 , wherein the first component and the second component are punched on two opposite sides prior to application of the electrolyte layer of the interconnect layer such that gas distribution holes are formed in the first and second components.

22. The method of claim 18 , wherein the first component and the second component are punched on two opposite sides prior to application of the electrolyte layer or the interconnect layer such that gas distribution holes are formed in the first and second components.

23. The method of claim 11 , wherein the sealing layer comprises an electrode layer or a contact layer.

24. The method of claim 2 , wherein the material for forming the cathode by impregnation is selected from (La 1-x Sr x )MnO 3-δ , (Ln 1-x Sr x )MnO 3-δ , (Ln 1-x Sr x )Fe 1-y Co y O 3-δ , (Y 1-x Ca x )Fe 1-y Co y O 3-δ , (Gd 1-x Sr x )Fe 1-y Co y O 3-δ , (Gd 1-x Ca x )Fe 1-y Co y O 3-δ , (Y,Ca)Fe 1-y Co y O 3-δ , doped ceria, doped zirconia,

Assignees

• Larsen Peter Halvor
• Smith Anders
• Mogensen Mogens
• Linderoth Soeren
• Hendriksen Peter Vang
• Univ Denmark Tech Dtu

Inventors

• Larsen Peter Halvor
• Smith Anders
• Mogensen Mogens
• Linderoth Soeren
• Hendriksen Peter Vang

Classifications

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01M4/905

  specially used in fuel cell operating at high temperature, e.g. SOFC · CPC title

• H01M8/2435 Primary

  with monolithic core structure, e.g. honeycombs · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M4/9033

  Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites · CPC title