Coated article and/or device with optical out-coupling layer stack (OCLS) including vacuum deposited index match layer over scattering matrix, and/or associated methods

Patent metadata

Field	Value
Publication number	US-9263701-B2
Application number	US-201313826495-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Mar 14, 2013
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

Certain example embodiments relate to light emitting diode (e.g., OLED and/or PLED) inclusive devices, and/or methods of making the same. Certain example embodiments incorporate an optical out-coupling layer stack (OCLS) structure that includes a vacuum deposited index matching layer (imL) provided over an organo-metallic scattering matrix layer. The imL may be a silicon-inclusive layer and may include, for example, vacuum deposited SiOxNy. The OCLS including scattering micro-particles, the imL, and the anode may be designed such that the device extraction efficiency is significantly improved, e.g., by efficiently coupling the light generated in the organic layers of the devices and extracted through the glass substrate. In certain example embodiments, the refractive index of the ITO, SiOxNy index matching layer, OCLS scattering layer and the glass substrate may be provided in decreasing order.

First claim

What is claimed is:

1. A method of making a coated article, the method comprising:
wet applying a base scattering matrix layer, directly or indirectly, on a glass substrate, a precursor for the base scattering matrix layer including an organo-metallic chelate of a high index material and siloxane solvent;
curing the wet applied base scattering matrix layer;
vacuum coating a silicon-inclusive index matching layer, directly or indirectly, on the cured base scattering matrix layer; and
vacuum coating an anodic layer, directly or indirectly, on the index matching layer, wherein the cured base scattering matrix layer has a refractive index of 1.55-1.7, the index matching layer has a refractive index of 1.7-1.9, and the anodic layer has a refractive index of 1.9-2.1.

2. The method of claim 1 , wherein the glass substrate has a refractive index of less than 1.6.

3. The method of claim 1 , wherein the cured base scattering matrix layer is about 2-30 microns thick and has an average surface roughness (Ra) less than 4 nm.

4. The method of claim 3 , wherein the wet applying is practiced using a slot die coater.

5. The method of claim 4 , wherein the precursor from which the base scattering matrix layer is formed has a viscosity of 4-8 cp.

6. The method of claim 1 , wherein the base scattering matrix layer, when cured, comprises an isotropic layer matrix including an organo-metallic chelate hybrid matrix with scatterers dispersed therein.

7. The method of claim 6 , wherein the scatterers include titanium oxide, zirconium oxide, and/or hafnium oxide particles.

8. The method of claim 1 , wherein the curing is performed at a temperature less than 200 degrees C. for between a few minutes to a few hours.

9. The method of claim 1 , wherein the index matching layer comprises silicon oxynitride.

10. The method of claim 1 , wherein the anodic layer comprises indium tin oxide.

11. The method of claim 10 , further comprising annealing the substrate with the cured base scattering matrix layer, index matching layer, and anodic layer thereon, in order to increase transparency and reduce sheet resistance of the anodic layer.

12. The method of claim 1 , further comprising disposing a glue layer on the base scattering matrix layer, the index matching layer being disposed directly over and contacting the glue layer.

13. A method of making an electronic device, the method comprising:
providing a coated article made according to the method of claim 1 ;
patterning the anodic layer; and
disposing a hole transport layer, an emitting layer, and a reflective cathodic layer, in that order, on the patterned anodic layer, in making the electronic device.

14. The method of claim 13 , wherein the emitting layer is an electronic transport and emitting layer, and the electronic device is an COED-based device.

15. The method of claim 13 , wherein the electronic device is a PLED-based device.

Assignees

• Guardian Industries

Inventors

• Hatwar Tukaram K
• Den Boer Willem
• Veerasamy Vijayen S

Classifications

• H10K50/854

  comprising scattering means · CPC title

• G02B5/0242 Primary

  by means of dispersed particles · CPC title

• C09D7/00

  Features of coating compositions, not provided for in group C09D5/00 (driers C09F9/00); Processes for incorporating ingredients in coating compositions · CPC title

• H01L51/5275

  Electricity · mapped topic

• Y10T428/24893

  including particulate material · CPC title