Photovoltaic devices including doped semiconductor films

Patent metadata

Field	Value
Publication number	US-9263608-B2
Application number	US-26242408-A
Country	US
Kind code	B2
Filing date	Oct 31, 2008
Priority date	Nov 2, 2007
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

A photovoltaic cell can include a dopant in contact with a semiconductor layer.

First claim

What is claimed is:

1. A photovoltaic cell comprising:
a transparent conductive layer;
a first semiconductor window layer over the transparent conductive layer;
a dopant layer comprising a first dopant over the first semiconductor window layer;
a second semiconductor window layer over the first semiconductor window layer, wherein the dopant layer is between the first semiconductor window layer and the second semiconductor window layer, and wherein the second semiconductor window layer includes an oxidant and the first dopant; and
a semiconductor absorber layer over the second semiconductor window layer;
wherein the first and second semiconductor window layers comprise CdS; and
wherein the dopant layer containing the first dopant has a thickness between 4 and 15 Angstroms.

2. The photovoltaic cell of claim 1 , wherein the transparent conductive layer is positioned over a substrate.

3. The photovoltaic cell of claim 1 , wherein the oxidant comprises fluorine or oxygen.

4. The photovoltaic cell of claim 1 , wherein the first dopant includes an n-type dopant.

5. The photovoltaic cell of claim 1 , wherein the dopant layer comprising the first dopant is in direct contact with the first semiconductor window layer.

6. The photovoltaic cell of claim 1 , wherein the semiconductor absorber layer comprises CdTe.

7. The photovoltaic cell of claim 1 , further comprising a glass substrate, wherein the transparent conductive layer is over the glass substrate.

8. The photovoltaic cell of claim 1 , wherein the second semiconductor window layer includes the first dopant at a concentration greater than about 100 ppma.

9. The photovoltaic cell of claim 1 , wherein the semiconductor absorber layer includes a second dopant, wherein the first dopant is different from the second dopant.

10. The photovoltaic cell of claim 9 wherein the first dopant comprises a Group III species.

11. A photovoltaic cell comprising:
a transparent conductive layer;
a first semiconductor window layer over the transparent conductive layer;
a layer comprising a first dopant over the first semiconductor window layer;
a second semiconductor window layer over the first semiconductor window layer, wherein the layer comprising the first dopant is between the first semiconductor window layer and the second semiconductor window layer, and wherein the second semiconductor window layer includes an oxidant and the first dopant; and
a semiconductor absorber layer over and in direct contact with the second semiconductor window layer, wherein the semiconductor absorber layer comprises a second dopant;
wherein the first and second semiconductor window layers comprise CdS; and
wherein the layer comprising the first dopant has a thickness between 4 and 15 Angstroms.

12. The photovoltaic cell of claim 1 , further comprising a back metal electrode positioned over the semiconductor absorber layer.

13. The photovoltaic cell of claim 3 , wherein the oxidant comprises fluorine.

14. The photovoltaic cell of claim 11 , further comprising a back metal electrode positioned over the semiconductor absorber layer.

15. The photovoltaic cell of claim 11 , wherein the oxidant comprises fluorine.

16. A photovoltaic cell comprising:
a transparent conductive layer;
a first semiconductor window layer over the transparent conductive layer;
a dopant layer comprising a first dopant over and in direct contact with the first semiconductor window layer;
a second semiconductor window layer over and in direct contact with the dopant layer;
wherein the second semiconductor window layer is thicker than the first semiconductor window layer, and wherein the second semiconductor layer includes an oxidant and the first dopant; and
a semiconductor absorber layer over the second semiconductor window layer,
wherein the semiconductor absorber layer further comprises a second dopant;
wherein the first and second semiconductor window layers comprise CdS; and
wherein the dopant layer comprising the first dopant has a thickness between 4 and 15 Angstroms.

17. The photovoltaic cell of claim 11 , wherein the first dopant in the second semiconductor window layer is at a concentration greater than about 100 ppma.

18. The photovoltaic cell of claim 16 , wherein the oxidant comprises fluorine or oxygen.

19. The photovoltaic cell of claim 16 , wherein the first dopant has a concentration greater than 100 ppma in the second semiconductor window layer.

20. The photovoltaic cell of claim 1 , further comprising a capping layer between the transparent conductive layer and the first semiconductor window layer.

21. The photovoltaic cell of claim 11 , further comprising a capping layer between the transparent conductive layer and the first semiconductor window layer.

22. The photovoltaic cell of claim 16 , further comprising a capping layer between the transparent conductive layer and the first semiconductor window layer.

Assignees

• Powell Rick C
• Jayamaha Upali
• Abken Anke
• Gloeckler Markus
• Gupta Akhlesh
• Green Roger T
• Meyers Peter
• First Solar Inc

Inventors

• Powell Rick C
• Jayamaha Upali
• Abken Anke
• Gloeckler Markus
• Gupta Akhlesh
• Green Roger T
• Meyers Peter

Classifications

• Y02E10/543

  Solar cells from Group II-VI materials · CPC title

• Y02E10/544

  Solar cells from Group III-V materials · CPC title

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• H10F77/244 Primary

  made of transparent conductive layers, e.g. transparent conductive oxide [TCO] layers · CPC title

• H10F71/138

  Manufacture of transparent electrodes, e.g. transparent conductive oxides [TCO] or indium tin oxide [ITO] electrodes · CPC title