Nanocrystal titanium alloy and production method for same

Patent metadata

Field	Value
Publication number	US-9260773-B2
Application number	US-201013496750-A
Country	US
Kind code	B2
Filing date	Sep 22, 2010
Priority date	Sep 25, 2009
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

A titanium alloy has high strength and superior workability and is preferably used for various structural materials for automobiles, etc. The titanium alloy is obtained by the following production method. An alloy having a structure of α′ martensite phase is hot worked at conditions at which dynamic recrystallization occurs. The working is performed at a heating rate of 50 to 800° C./second at a strain rate of 0.01 to 10/second when the temperature is 700 to 800° C. or at a strain rate of 0.1 to 10/second when the temperature is more than 800° C. and less than 1000° C. so as to provide a strain of not less than 0.5. Thus, equiaxed crystals with an average grain size of less than 1000 nm are obtained.

First claim

The invention claimed is:

1. A titanium alloy having a composition that is classified as a titanium alloy of a near α titanium or an α+β titanium consisting of 4 to 9 mass % of Al, 2 to 10 mass % of V, and the balance of Ti and inevitable impurities, the titanium alloy consisting of a uniform fine structure in which equiaxed crystals with an average grain size of less than 1000 nm are uniformly dispersed,
wherein the equiaxed crystals have a β phase at more than 0% and not more than 1.0% by area ratio, which is measured by an Electron BackScattered Diffraction (EBSD) method using a phase map.

2. The titanium alloy according to claim 1 , wherein the titanium alloy has a structure deformed by working, and the uniform fine structure is not less than 80% by area ratio in a freely chosen cross section of the deformed structure.

3. The titanium alloy according to claim 1 , wherein the equiaxed crystals include crystal grains having less than 3° of an angle difference in crystal orientation within the crystal grain, which is measured by an Electron BackScattered Diffraction (EBSD) method using a GOS map, and an area ratio of the crystal grains is not less than 80%.

4. The titanium alloy according to claim 1 , wherein the average grain size is not more than 600 nm.

5. The titanium alloy according to claim 1 , wherein the titanium alloy has not less than 360 HV of hardness and not less than 1400 MPa of 0.2% bending yield strength.

6. A production method for the titanium alloy according to claim 1 , comprising:
preparing a titanium alloy consisting of 4 to 9 mass % of Al, 2 to 10 mass % of V, and the balance of Ti and inevitable impurities;
working the titanium alloy containing an α′ martensite phase so as to cause dynamic recrystallization.

7. The production method for the titanium alloy according to claim 6 , wherein the working is performed by heating the titanium alloy at a heating rate of 50 to 800° C./second and providing strain of not less than 0.5 at a strain rate of 0.01 to 10/second in a temperature range of 700 to 800° C. or at a strain rate of 0.1 to 10/second in a temperature range of more than 800° C. and less than 1000° C., the production method further comprising cooling the titanium alloy at a cooling rate of not less than 20° C./second after the working.

8. The production method for the titanium alloy according to claim 7 , wherein the titanium alloy is heated at a heating rate of 100° C./second from room temperature to a temperature that is lower than the working temperature by 100° C. and is then heated at a heating rate of 50° C./second.

9. The production method for the titanium alloy according to claim 7 , wherein the titanium alloy is worked at a working temperature of 700 to 800° C. at a strain rate of 0.01 to 10/second so as to have a strain of not less than 0.8.

Assignees

• Lee Sang-Hak
• Ono Yoshiki
• Ikai Kazuya
• Matsumoto Hiroaki
• Chiba Akihiko
• Nhk Spring Co Ltd
• Univ Tohoku

Inventors

• Lee Sang-Hak
• Ono Yoshiki
• Ikai Kazuya
• Matsumoto Hiroaki
• Chiba Akihiko

Classifications

• C22F1/183 Primary

  of titanium or alloys based thereon · CPC title

• C22C1/02

  by melting {(C22C1/1036 takes precedence)} · CPC title

• C22F1/00

  Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working (apparatus for mechanical working of metal B21, B23, B24) · CPC title

• C22C14/00

  Alloys based on titanium · CPC title